ch10取代羧酸

1、 CH2COOHXCH2COOHOHCH2COOHNH2CH3CCOOHO CH2CH2COOHBrC H3C H2C C O O HB rB r ClCH2CH2CH2COOHCOOHBrCH3CHCOOHOHCOOHOHCOOHOHOH HOOCCHCH2COOHOHCHOCH2CO O HCO O HCH2CO O HHOOCCHCHCOOHOHOHHCCOOHOCH3CCH2COOHOCH3(CH2)7CCOOHO CH2COOHNH2HOOCCH2CH2CHCOOHNH2COOHNH2CH2 CHCOOHNH2 CH3CH2CHCOOHClCH3CHCH2COOHClCH2CH2CH

2、2COOHClClCH2COOHCH3COOHCl2CHCOOHCl3CCOOH ClCH2COOHFCH2COOHBrCH2COOHICH2COOH COOHCOOHOHCOOHNH2COOHOCH3 COOHCOOHClCOOHICOOHBr COOHCOOHCNCOOHNO2 COOHOHCOOHOHCOOH COOHNO2COOHNO2COOHNO2 CCOOHCCCOOHCCCOOHCClClCl HBr+RCHCOOHBrPBr3+RCH2COOHBr2RCHCOOHKIKCl(Br)+Cl(Br)IRCHCOOH +RCH=CHCOOHHXRCHCH2COOHX+RCHCH2CO

3、OHOHHBrRCHCH2COOHBr + HClCH3CHCOOHClH2OCH3CHCOOHOH+ NaClCH2CHCOOHHClCH2=CHCOOH+NaOH+ H2O CH2CH2CH2COOHClH2ONa2CO3H+CH2CH2CH2COOHOH-OOCH2CH2CH2CH2COOHClH2ONa2CO3H+CH2CH2CH2CH2COOHOH-OO C6H5COCH3+ ClCH2COOC2H5C2H5ONaor NaNH2C6H5CCH3CHCOOC2H5O C6H5CCH3CHCOOC2H5OOH- / H2OC6H5CCH3CHCOO-O+C2H5OHC6H5CCH3CH

4、COO-O+HH+C6H5CCH3CHCOO-OH+-CO2,C6H5CCH3CHOH重排C6H5CHCH3CHO BrCH2COOC2H5+ ZnetherBrZnCH2COOC2H5BrZnCH2COOC2H5C6H5CHO +C6H5CHOZnBrCH2COOC2H5H2OC6H5CHOZnBrCH2COOC2H5H+C6H5CHOHCH2COOC2H5+ZnOHBr H2O+CH2COOHClCH2COOHOH+ HCl H2O+RCHOHCNRCCNOHHH+RCCOOHOHHH2O+ HCNRCCNOHRH+RCCOOHOHRRCRO100CHCNOHconc HClCHCOOHO

5、HRCH=CH2HClORCHCH2OH ClKCNRCHCH2CNOHH2OH+RCHCH2COOHOH HOCH2COOHOHCCOOHOOHOOCCOOHCH3CHCOOHOHOCH3CCOOHOCH3CHCH2COOHOHOCH3CCH2COOHORCCOOHO-CO2RCHORCCH2COOHO-CO2RCCH3O CHROHCOOHCHCOHOHOR+OOROOR+ 2H2OOOROORH2OH+ or OH-2 RCH COOHOHRCHCH2CO O HO HRCH=CHCO O H COOHOHOO+ H2O+ H2OOHCOOHOOCOONaOHOONaOH / H2O ONa+CO2120140405709kPaOHCOONaH+OHCOOHOK+CO2加热，加压COOKOHCOOHOHH+ OH+CO2OHCOOH200220+CO2200COOHHOOHOHHOOHOH H2NCOOHRCHCOOHCH3HHOCOOHRHH2NL乳酸 L氨基酸 H2NHC COOHRHClH3NHC COOHRH2NHC COO-Na+RNaOHH3NHC COOR RCHCOOHHOCOCRHNHHNH+NHNHOO CH2CH2COOH