美利肯透明聚丙烯课件

1、最新一代聚丙烯透明剂谢春平博士，美利肯化工内容简介 OutlineMillad 3988i, Millad NX8000产品概述 Product SummaryMillad NX8000介绍 What is Millad NX8000?Millad NX8000个例经济分析 Millad NX8000 Commercial Case Study总结 Conclusion十多年来，Millad 3988一直是透明聚丙烯市场的百尺竿头Millad 3988,the Industry Benchmark for Clear PolypropyleneMillad NX8000 更进一步Millad

2、NX8000 is for the Ultimate in Clear PolypropyleneMillad NX8000 的产品定位position in the market Millad NX8000 是透明聚丙烯领域的重大突破。其所能达到的透明度增加了许多商机。Millad NX8000 gives a new clarity standard for cPP, a breakthrough in PP transparency, permitting attractive opportunities in market value growth through the develo

3、pment of new clear resins 通过取代别的透明塑料来加速聚丙烯的增长Accelerating PP growth through material replacement of clear polymers 在已存在的应用通过提高顾客对更为透明产品的兴趣来增长Reinvigorating and growing polypropylene in existing applications through improved consumer interest and acceptanceWhat is Millad NX8000?Millad NX8000是一全新分子结构的

4、透明剂 Millad NX8000 is a new-to-the-world clarifier based on a new type chemistry that significantly expands the performance of PP clarification Millad NX8000使得透明聚丙烯看起来近似聚苯乙烯和聚碳酸酯因而使材料取代成为可能 Millad NX8000 allows polypropylene to approach the look and clarity of high clarity plastics like polystyrene a

5、nd polycarbonate creating material substitution opportunities 商业级树脂在全球各地都有开发 Commercial grades are in development in each region of the worldHaze Continuum for Selected Plastic MaterialsMillad NX8000 使聚丙烯更接近透明工程塑料 Millad NX8000 allows PP to close the haze gap on “water white” polymers5PMMAPETPSPCGla

6、ssClarified (NX8000) PP(RACO & HOMO)3.5-7.0Clarified PP (1G) RACO20-30Clarified (3G) PP (HOMO)15-20Clarified (3G) PP (RACO) 10-15Clarified (3G) mPP (HOMO)13-16Clarified (3G) mPP (RACO) 9-11Unclarified PP(HOMO) 50-70Unclarified PP (RACO) 40-50Unclarified HDPE 80+“Water White”Clarity (13)Evolutionary

7、Improvements in Polypropylene ClarityNote: 1.25 mm plaquesHaze, %40806020103150Millad NX8000 的价值何在？What is the Value?提高透明度 Improved clarity增宽加工窗口 Broad processing window缩短成型周期 Improved cycle timeMillad NX8000 的价值何在？What is the Value?提高透明度 Improved clarity增宽加工窗口 Broad processing window缩短成型周期 Improved

8、 cycle time透明聚丙烯在注塑产品的应用Markets for Injection Molded Clear PP 新一代聚丙烯透明剂有何不同？Millad NX8000将 Millad 3988i 的雾度降低几乎一半 Millad NX8000 gives half the haze as Millad 3988i at any thickness.Millad NX8000 把不同厚度产品的雾度都几乎降低了一半 Millad NX8000 delivers significantly improved haze at all thickness in IM (50%) under

9、commercial conditions Millad NX8000 显著地增宽了加工区间从而使得雾度在各种操作条件下都接近一致 Millad NX8000 has a significantly broadened processing window - allowing for consistently superior clarity across all polypropylene melt flows and processing conditions要点 Points to noteNote: DOEs conducted in 12 MFI RCP; Millad 3988i

10、at 2000 ppm; Millad NX8000 at 4000 ppm雾度 HazeFor the Ultimate in Clear PolypropyleneFor the Ultimate in Clear PolypropyleneMillad NX8000 的价值何在？What is the Value?提高透明度 Improved clarity增宽加工窗口 Broad processing window缩短成型周期 Improved cycle timeParameter LowHighMixingLow Intensity (L)High Intensity (H)Ext

11、rusionSingle Screw (S)Twin Screw (T)Extrusion Temp.190C (L)230C (H)IM Barrel Temp.190C (L)230C (H)IM Injection Rate2.4cc/s (L)30cc/s (H)新一代聚丙烯透明剂有何不同？ What is Next Generation Millad?Millad NX8000在各种条件下都能得到好的雾度 A broad processing window giving excellent haze under all processing conditions.Note: DOEs

12、 conducted in 12 MFI RCP; Millad NX8000 at 4000 ppmMillad NX8000 的价值何在？What is the Value?提高透明度 Improved clarity增宽加工窗口 Broad processing window缩短成型周期 Improved cycle timeMillad NX8000结晶温度更高，成型周期更短,产能提高 5-10%Millad NX8000 has a higher Tc and shorter T1/2. When coupled with the broader processing window,

13、 productivity enhancements (generally 5 10%) are possible without reducing other quality requirements.Note: Expts conducted in 12 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 ppmTc DataT1/2 DataMillad NX8000 的价值何在？What is the Value? 提高挤出吹塑产品的透明度EBM - Improved clarity拓宽挤出吹塑的加工窗口EBM - Impr

14、oved processing window透明聚丙烯在挤出注塑产品的应用Markets for Extrusion Blow Molded Clear PPMillad NX8000 使挤出注塑瓶的外形大为改观从而加宽了透明聚丙烯在挤出注塑领域的应用 Millad NX8000 yields new PP aesthetics in EBM bottles permitting a broader application of cPP in EBM applications.Millad NX8000 在雾度和光泽度都有显著提高 Millad NX8000 gives superior pe

15、rformance in haze and gloss at high loadings.Millad NX8000显著提高挤出注塑产品的外观Millad NX8000 consistently gives improved aesthetics in EBM要点 Points to noteDecreasing loadingNote: Expts conducted in 2 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 ppm, 500 mL Shampoo bottle雾度 Haze内部光泽度 Inside Gloss

16、硬度略有提高，抗冲击不受影响 There is a modest improvement in stiffness without loss in impact resistance硬度在低温操作条件下有所提高，抗冲击不受影响 Stiffness is higher at cooler operating temperatures without the loss in impact resistanceMillad NX8000具有典型无规共聚的硬度/抗冲击平衡Millad NX8000 has typical stiffness/impact balance for RCP. 要点 Poi

17、nts to noteDecreasing loadingNote: Expts conducted in 12 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 ppmFlexural ModulusGardner Impact优异的重复加工稳定性,宜于回收利用 Excellent multi-pass additive stability indicates regrind stabilityMillad NX8000在氧化裂解中具有优良的稳定性Millad NX8000 has excellent regrind and v

18、isc-breaking stability 要点 Points to noteDecreasing loadingNote: Expts conducted in 12 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 ppmNormal 12 MFICR to 35 MFIAttributeMillad NX8000Millad 3988iMillad NX8000，其他性质类似Millad 3988i All other attributes are like Millad 3988i.雾度 Haze大约降低50% 50%

19、reduction in haze业界标准Industry Standard气味 Taste & Odor基本一致 Similar业界标准 Industry Standard操作温区 Processing190 250 C210 C注册情况 Regulatory 全球许可申请中In progress全球许可 Globally approved提取物Extraction低 Low低 Low硬度Stiffness基本一致 Similar业界标准 Standard抗冲击Impact基本一致 Similar业界标准 Standard发黄问题Yellowing没问题 No issues没问题 No is

20、suesFor the Ultimate in Clear PolypropyleneNX8000 商业化个案研究：更高的透明度在食品包装的价值The Value of Clarity in Food Storage Containers 应用： 食品包装 Application: Food Storage Containers 加工：注塑 Process: Injection Molding 区域：北美 Region: North America 追求高清晰度的动力何在？ Drivers for higher clarity: (1) 增加销售 Increase sales 市场研究表明顾客

21、希望更为透明的食品包装 Market research demonstrates that consumers prefer higher clarity in food storage containers (2) 提高利润率 Improve margins市场研究表明顾客愿意为更透明的食品包装付出多一些 结果证明了这一点 Market research suggests that consumers will pay more for higher clarity in food storage containers. It has been proved by market.食品包装盒转

22、换:高清晰度导致高利润率 Food Storage Conversion: Improve Clarity to Improve MarginsProduct LineSizeClear Base Weight (kg)Clear PP Cost / kg resinClear PP Material Cost / PartSales Price at RetailerServin Saver2.1 cups (500 mL)0.05$1.870.093$1.99Easy Find Lids2 cups (473 mL)0.05$2.170.109$2.19 成本增加了2美分 Higher c

23、larity adds less than $0.02 / part in cost (assume a $300/ton upcharge for NX8000) 零售价增加了20美分 Retail price is $0.20 / part higher for the Easy Find Lids商业应用举例：食品容器：高端顾客对更高透明度的追求包装材料：取代高成本塑料如聚碳酸酯，聚氯乙烯，聚苯乙烯，共聚聚酯 (PETG)等 婴儿奶瓶：取代聚碳酸酯 成本及内分泌腺的安全考虑 挤吹塑料瓶：化妆品容器等For the Ultimate in Clear Polypropylene塑料类型价格

24、(美元/吨)Price USD/t密度(吨/米3)Density (t/m3)价格(美元/米3)Price USD/m3均聚聚丙烯 Homo PP$14500.91305高密度聚乙烯 HDPE$14500.941363共聚聚丙烯-NX8000 $16500.91485聚苯乙烯 Polystyrene $16001.041664聚氯乙烯 PVC - Rigid$16001.2-1.41920-2240聚碳酸酯 Polycarbonate$25001.23000Millad NX8000 材料取代的经济分析 Millad NX8000 Economics Inter-material substi

25、tutionSource: IDES, data for Oct 07材料取代商机Material Substitution Opportunities聚苯乙烯类 Styrenics (including SAN, SBC)CD盒，杯子，包装等 CD cases, appliances, cups, packaging取代动力 Drivers成本，抗冲击，持久性 Cost (copolymers), impact, sustainability聚酯 Polyesters包装，杯子，瓶子 Packaging, cups, bottles取代动力 Drivers 成本， 手感 Cost (PETG), hand/feel聚碳酸酯 Polycarbonate婴儿奶瓶，水瓶，家具，日常用具Infant feeding bottles, water packaging, furniture, housewares, appliances取代动力 Drivers 成本及内分泌腺的安全考虑 Cost, BPA endocrine disru