【《钙钛矿结构反铁电材料研究文献综述》1800字】

钙钛矿结构反铁电材料研究文献综述1.1钙钛矿结构在多种材料结构中均存在反铁电体，但钙钛矿结构是反铁电材料中最具有代表性的一类ADDINEN.CITE<EndNote><Cite><Author>Subbarao</Author><Year>1973</Year><RecNum>83</RecNum><DisplayText><styleface="superscript">[7]</style></DisplayText><record><rec-number>83</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623416565">83</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Subbarao</author><author>E.,C.</author></authors></contributors><titles><title>Ferroelectricandantiferroelectricmaterials</title><secondary-title>Ferroelectrics</secondary-title></titles><periodical><full-title>Ferroelectrics</full-title></periodical><pages>267-280</pages><volume>5</volume><number>1</number><dates><year>1973</year></dates><urls></urls></record></Cite></EndNote>[7]。钙钛矿结构存在于许多常见的反铁电材料中，如PbZrO3ADDINEN.CITE<EndNote><Cite><Author>Samara</Author><Year>1969</Year><RecNum>78</RecNum><DisplayText><styleface="superscript">[8]</style></DisplayText><record><rec-number>78</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623416565">78</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Samara,G.A.</author></authors></contributors><titles><title>Anewpressure-inducedphaseinPbHfO3</title><secondary-title>PhysicsLettersA</secondary-title></titles><periodical><full-title>PhysicsLettersA</full-title></periodical><pages>446-447</pages><volume>30</volume><number>8</number><dates><year>1969</year></dates><urls></urls></record></Cite></EndNote>[8]ADDINEN.CITE<EndNote><Cite><Author>deBretteville</Author><Year>1954</Year><RecNum>80</RecNum><DisplayText><styleface="superscript">[9]</style></DisplayText><record><rec-number>80</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623416565">80</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>deBretteville</author><author>A.,P.</author></authors></contributors><titles><title>ThresholdFieldandFreeEnergyfortheAntiferroelectric-FerroelectricPhaseTransitioninLeadZirconate</title><secondary-title>PhysicalReview</secondary-title></titles><periodical><full-title>PhysicalReview</full-title></periodical><pages>1125-1128</pages><volume>94</volume><number>5</number><dates><year>1954</year></dates><urls></urls></record></Cite></EndNote>[9]、PbHfO3ADDINEN.CITE<EndNote><Cite><Author>Samara</Author><Year>1969</Year><RecNum>78</RecNum><DisplayText><styleface="superscript">[8]</style></DisplayText><record><rec-number>78</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623416565">78</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Samara,G.A.</author></authors></contributors><titles><title>Anewpressure-inducedphaseinPbHfO3</title><secondary-title>PhysicsLettersA</secondary-title></titles><periodical><full-title>PhysicsLettersA</full-title></periodical><pages>446-447</pages><volume>30</volume><number>8</number><dates><year>1969</year></dates><urls></urls></record></Cite></EndNote>[8]ADDINEN.CITE<EndNote><Cite><Author>Shirane</Author><Year>1953</Year><RecNum>79</RecNum><DisplayText><styleface="superscript">[10]</style></DisplayText><record><rec-number>79</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623416565">79</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Shirane,G.</author><author>Pepinsky,R.</author></authors></contributors><titles><title>PhaseTransitionsinAntiferroelectricPbHfO3</title><secondary-title>PhysRev</secondary-title></titles><periodical><full-title>PhysRev</full-title></periodical><pages>812-815</pages><volume>91</volume><number>4</number><dates><year>1953</year></dates><urls></urls></record></Cite></EndNote>[10](简称PH)、以及NaNbO3ADDINEN.CITE<EndNote><Cite><Author>Zhelnova</Author><Year>1987</Year><RecNum>77</RecNum><DisplayText><styleface="superscript">[11]</style></DisplayText><record><rec-number>77</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623416565">77</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Zhelnova,O.A.</author><author>Fesenko,O.E.</author></authors></contributors><titles><title>PhasetransitionsandtwinninginNaNbO3crystals</title><secondary-title>Ferroelectrics</secondary-title></titles><periodical><full-title>Ferroelectrics</full-title></periodical><pages>469-475</pages><volume>75</volume><number>1</number><dates><year>1987</year></dates><urls></urls></record></Cite></EndNote>[11]ADDINEN.CITE<EndNote><Cite><Author>Shen</Author><Year>1998</Year><RecNum>76</RecNum><DisplayText><styleface="superscript">[12]</style></DisplayText><record><rec-number>76</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623416565">76</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Shen,Z.X.</author><author>Wang,X.B.</author><author>Kuok,M.H.</author><author>Tang,S.H.</author></authors></contributors><titles><title>Ramanscatteringinvestigationsoftheantiferroelectric–ferroelectricphasetransitionofNaNbO3</title><secondary-title>JournalofRamanSpectroscopy</secondary-title></titles><periodical><full-title>JournalofRamanspectroscopy</full-title></periodical><pages>379-384</pages><volume>29</volume><number>5</number><dates><year>1998</year></dates><urls></urls></record></Cite></EndNote>[12]等在室温下都呈现反铁电性。典型的钙钛矿结构的化学通式可表示为ABO3。图1.2为钙钛矿结构的示意图。在典型钙钛矿材料中，A位离子占据晶胞的顶点，配位数为12；B位的离子占据体心，配位数为6；O2-离子在晶胞内构成氧八面体。理想钙钛矿结构中，A位的离子半径RA，B位离子半径RB与O2-离子半径RO之间满足如下关系ADDINEN.CITE<EndNote><Cite><Author>Wang</Author><Year>2007</Year><RecNum>88</RecNum><DisplayText><styleface="superscript">[13]</style></DisplayText><record><rec-number>88</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623417252">88</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Wang,J.</author></authors></contributors><titles><title>HandbookofElectronicandPhotonicMaterials</title></titles><dates><year>2007</year></dates><urls></urls></record></Cite></EndNote>[13]：RA然而，当各离子半径稍有偏差时，仍然可以保证钙钛矿结构稳定存在。针对这一现象，人们提出了容忍因子(简称t)的概念。式(1-2)所示为t的表达式ADDINEN.CITE<EndNote><Cite><Author>Wang</Author><Year>2007</Year><RecNum>88</RecNum><DisplayText><styleface="superscript">[13]</style></DisplayText><record><rec-number>88</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623417252">88</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Wang,J.</author></authors></contributors><titles><title>HandbookofElectronicandPhotonicMaterials</title></titles><dates><year>2007</year></dates><urls></urls></record></Cite></EndNote>[13]：t=在式(1-2)中，当RA、RB、RO的大小使得t满足在一定范围内变化t∈[0.85，1.05]时，材料的钙钛矿结构均可稳定存在，从而达到改变材料原有的能带宽带、自发极化状态和电荷分布的目的，从而实现对材料的改性。掺杂后形成的(A1，A2，A3，…，Am)(B1，B2，B3，…，Bm)O3结构也称为复合钙钛矿结构。图1.2钙钛矿结构示意图ADDINEN.CITE<EndNote><Cite><Author>Wang</Author><Year>2007</Year><RecNum>88</RecNum><DisplayText><styleface="superscript">[13]</style></DisplayText><record><rec-number>88</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623417252">88</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Wang,J.</author></authors></contributors><titles><title>HandbookofElectronicandPhotonicMaterials</title></titles><dates><year>2007</year></dates><urls></urls></record></Cite></EndNote>[13]1.2复合钙钛矿结构反铁电材料钙钛矿结构的PbZrO3是首个被发现的典型反铁电材料ADDINEN.CITE<EndNote><Cite><Author>Sawaguchi</Author><Year>1951</Year><RecNum>100</RecNum><DisplayText><styleface="superscript">[14]</style></DisplayText><record><rec-number>100</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623417734">100</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Sawaguchi,E.</author><author>Maniwa,H.</author><author>Hoshino,S.</author></authors></contributors><titles><title>AntiferroelectricStructureofLeadZirconate</title><secondary-title>PhysicalReview</secondary-title></titles><periodical><full-title>PhysicalReview</full-title></periodical><pages>1078-1078</pages><volume>83</volume><number>5</number><dates><year>1951</year></dates><urls></urls></record></Cite></EndNote>[14]。而常温下PbHfO3(以下简称PH)和PbZrO3结构相同：在PH结构中，Pb2+离子占据A位，Hf4+离子占据B位，室温下为正交相。Pb2+离子在a-b平面内反向平行的排列ADDINEN.CITE<EndNote><Cite><Author>Hao</Author><Year>2014</Year><RecNum>110</RecNum><DisplayText><styleface="superscript">[4,14]</style></DisplayText><record><rec-number>110</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623417734">110</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Hao,X.</author><author>Zhai,J.</author><author>Ling,B.K.</author><author>Xu,Z.</author></authors></contributors><titles><title>Acomprehensivereviewontheprogressofleadzirconate-basedantiferroelectricmaterials</title><secondary-title>ProgressinMaterialsScience</secondary-title></titles><periodical><full-title>ProgressinMaterialsScience</full-title></periodical><pages>1-57</pages><volume>63</volume><number>8</number><dates><year>2014</year></dates><urls></urls></record></Cite><Cite><Author>Sawaguchi</Author><Year>1951</Year><RecNum>100</RecNum><record><rec-number>100</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623417734">100</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Sawaguchi,E.</author><author>Maniwa,H.</author><author>Hoshino,S.</author></authors></contributors><titles><title>AntiferroelectricStructureofLeadZirconate</title><secondary-title>PhysicalReview</secondary-title></titles><periodical><full-title>PhysicalReview</full-title></periodical><pages>1078-1078</pages><volume>83</volume><number>5</number><dates><year>1951</year></dates><urls></urls></record></Cite></EndNote>[4,14]是PH铁电性的来源。图1.4中矩形框所在的区域代表一个晶胞的垂直于c轴的平面，Pb2+离子沿着[001]方向偏移，相邻晶胞中离子水平位移基本一致，方向相反，从而产生反向偶极矩，偶极矩大小相等，极性相反，因此PH材料在宏观上不显电性。正交相PH具有非常稳定的反铁电性，在矫顽电场强度到达EA-F前，样品往往已经被击穿，因此PH在室温下难以诱导出双电滞回线。然而通过化学掺杂引入其他离子形成复合钙钛矿结构可以显著影响PH电性能，并且会引入其他中间相变。近些年，Ayyub和Dai等人ADDINEN.CITE<EndNote><Cite><Author>Jona</Author><Year>1957</Year><RecNum>98</RecNum><DisplayText><styleface="superscript">[15]</style></DisplayText><record><rec-number>98</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623417734">98</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Jona,F.</author><author>Shirane,G.</author><author>Mazzi,F.</author><author>Pepinsky,R.</author></authors></contributors><titles><title>X-RayandNeutronDiffractionStudyofAntiferroelectricLeadZirconate,PbZrO3</title><secondary-title>PhysRev</secondary-title></titles><periodical><full-title>PhysRev</full-title></periodical><pages>849-856</pages><volume>105</volume><number>3</number><dates><year>1957</year></dates><urls></urls></record></Cite></EndNote>[15]发现PbZrO3中存在极弱的铁电效应。该研究提出：PZ的反铁电性体现于它晶胞的垂直于c轴的平面，而它的铁电性则处于晶胞的[001]方向ADDINEN.CITE<EndNote><Cite><Author>Asada</Author><Year>2004</Year><RecNum>97</RecNum><DisplayText><styleface="superscript">[16]</style></DisplayText><record><rec-number>97</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623417734">97</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Asada,T.</author><author>Koyama,Y.</author></authors></contributors><titles><title>Coexistenceofferroelectricityandantiferroelectricityinleadzirconatetitanate</title><secondary-title>PhysicalReviewB</secondary-title></titles><periodical><full-title>PhysicalReviewB</full-title></periodical><pages>2516-2528</pages><volume>70</volume><number>10</number><dates><year>2004</year></dates><urls></urls></record></Cite></EndNote>[16]。正交相PH在室温下的反铁电性非常稳定，在矫顽电场强度到达EA-F前，样品往往已经被击穿，因此PH在室温下难以诱导出双电滞回线ADDINEN.CITE<EndNote><Cite><Author>Sawaguchi</Author><Year>1951</Year><RecNum>100</RecNum><DisplayText><styleface="superscript">[14]</style></DisplayText><record><rec-number>100</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623417734">100</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Sawaguchi,E.</author><author>Maniwa,H.</author><author>Hoshino,S.</author></authors></contributors><titles><title>AntiferroelectricStructureofLeadZirconate</title><secondary-title>PhysicalReview</secondary-title></titles><periodical><full-title>PhysicalReview</full-title></periodical><pages>1078-1078</pages><volume>83</volume><number>5</number><dates><year>1951</year></dates><urls></urls></record></Cite></EndNote>[14]。因此，要推进PH在反铁电材料方面应用，降低EA-F是关键。许多研究者在掺入不同元素对反铁电钙钛矿体系的影响做出了深远的贡献，其中对(Pb，La)(Zr，Sn，Ti)O3和Pb(Zr，Sn，Ti)NbO3复合钙钛矿体系的研究是目前学界研究的主流方向：Shirane等人ADDINEN.CITE<EndNote><Cite><Author>Shirane</Author><Year>1952</Year><RecNum>96</RecNum><DisplayText><styleface="superscript">[17]</style></DisplayText><record><rec-number>96</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623417734">96</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Shirane,G.</author></authors></contributors><titles><title>FerroelectricityandAntiferroelectricityinCeramicPbZrO3ContainingBaorSr</title><secondary-title>PhysicalReview</secondary-title></titles><periodical><full-title>PhysicalReview</full-title></periodical><pages>219-227</pages><volume>86</volume><number>2</number><dates><year>1952</year></dates><urls></urls></record></Cite></EndNote>[17]用Ba2+离子和Sr2+离子分别取代部分A位的Pb2+离子，发现掺杂离子的引入可以对反铁电相的稳定性造成直接影响。此后，学界分别对La3+离子ADDINEN.CITE<EndNote><Cite><Author>Berlincourt</Author><Year>1964</Year><RecNum>95</RecNum><DisplayText><styleface="superscript">[18]</style></DisplayText><record><rec-number>95</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623417734">95</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Berlincourt,D.</author><author>Krueger,Hha</author><author>Jaffe,B.</author></authors></contributors><titles><title>Stabilityofphasesinmodifiedleadzirconatewithvariationinpressure,electricfield,temperatureandcomposition</title><secondary-title>JournalofPhysics&ChemistryofSolids</secondary-title></titles><periodical><full-title>JournalofPhysics&ChemistryofSolids</full-title></periodical><pages>659-674</pages><volume>25</volume><number>7</number><dates><year>1964</year></dates><urls></urls></record></Cite></EndNote>[18]、Ca2+离子ADDINEN.CITE<EndNote><Cite><Author>Krainik</Author><Year>1958</Year><RecNum>94</RecNum><DisplayText><styleface="superscript">[19]</style></DisplayText><record><rec-number>94</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623417734">94</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Krainik,N.N.</author></authors></contributors><titles><title>PHASETRANSITIONSINSOMESOLIDSOLUTIONSCONTAININGLEADZIRCONATE</title><secondary-title>Zhur.tekh.fiz</secondary-title></titles><periodical><full-title>Zhur.tekh.fiz</full-title></periodical><dates><year>1958</year></dates><urls></urls></record></Cite></EndNote>[19]取代A位离子，利用Nb5+离子ADDINEN.CITE<EndNote><Cite><Author>Krainik</Author><Year>1958</Year><RecNum>94</RecNum><DisplayText><styleface="superscript">[19]</style></DisplayText><record><rec-number>94</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623417734">94</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Krainik,N.N.</author></authors></contributors><titles><title>PHASETRANSITIONSINSOMESOLIDSOLUTIONSCONTAININGLEADZIRCONATE</title><secondary-title>Zhur.tekh.fiz</secondary-title></titles><periodical><full-title>Zhur.tekh.fiz</full-title></periodical><dates><year>1958</year></dates><urls></urls></record></Cite></EndNote>[19]、Ti4+离子、Sn4+离子ADDINEN.CITE<EndNote><Cite><Author>Marutake</Author><Year>2007</Year><RecNum>114</RecNum><DisplayText><styleface="superscript">[20]</style></DisplayText><record><rec-number>114</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623418226">114</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Marutake,M.</author><author>Ikeda,T.</author></authors></contributors><titles><title>ElasticPropertiesofLeadZirconate</title><secondary-title>JournalofthePhysicalSocietyofJapan</secondary-title></titles><periodical><full-title>JournalofthePhysicalSocietyofJapan</full-title></periodical><pages>424-428</pages><volume>10</volume><number>6</number><dates><year>2007</year></dates><urls></urls></record></Cite></EndNote>[20]取代B位离子进行了研究，均得出了一部分成果，但具体的影响方向在学界仍有争议。PH也是一种具有复合钙钛矿结构的材料，其容忍因子t同样满足前文所描述的规律。对于组分为Pb(Hf1-xSnx)O3的PH反铁电体系，其A位、B位的平均离子半径满足(1-3)和(1-4)式ADDINEN.CITE<EndNote><Cite><Author>Hao</Author><Year>2007</Year><RecNum>91</RecNum><DisplayText><styleface="superscript">[21,22]</style></DisplayText><record><rec-number>91</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623417734">91</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Hao,X.</author><author>Zhai,J.</author></authors></contributors><titles><title>Composition-dependentelectricalpropertiesof(Pb,La)(Zr,Sn,Ti)O3antiferroelectricthinfilmsgrownonplatinum-bufferedsiliconsubstrates</title><secondary-title>JournalofPhysicsDAppliedPhysics</secondary-title></titles><periodical><full-title>JournalofPhysicsDAppliedPhysics</full-title></periodical><pages>7447</pages><volume>40</volume><number>23</number><dates><year>2007</year></dates><urls></urls></record></Cite><Cite><Author>Ming</Author><Year>2001</Year><RecNum>90</RecNum><record><rec-number>90</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623417734">90</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Ming,C.</author><author>Xi,Y.</author><author>Zhang,L.</author></authors></contributors><titles><title>Preparationof(Pb,La)(Zr,Sn,Ti)O3antiferroelectricceramicsusingcolloidalprocessingandthefieldinducedstrainproperties</title><secondary-title>JournaloftheEuropeanCeramicSociety</secondary-title></titles><periodical><full-title>JournaloftheEuropeanCeramicSociety</full-title></periodical><pages>1159-1164</pages><volume>21</volume><number>9</number><dates><year>2001</year></dates><urls></urls></record></Cite></EndNote>[21,22]RA容忍因子t会随着组分比例的不同发生相应改变。大量实验分析与数据统计结果发现：对于复合钙钛矿体系而言，当t<1时，反铁电相更加稳定；当t>1时，一般为铁电相。在PH体系中，反铁电相与铁电相的竞争直接受组分影响，不同的组分会向体系内引入不同的相变行为。图1.SEQ图\*ARABIC\s02PH的晶格结构示意图：箭头代表Pb2+离子在(001)面内的偏移ADDINEN.CITE<EndNote><Cite><Author>Hao</Author><Year>2014</Year><RecNum>110</RecNum><DisplayText><styleface="superscript">[4]</style></DisplayText><record><rec-number>110</rec-number><foreign-keys><keyapp="EN"db-id="a9wprfpauxfsd3etxp6x22w4pfr2t9t5xttv"timestamp="1623417734">110</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Hao,X.</author><author>Zhai,J.</author><author>Ling,B.K.</author><author>Xu,Z.</author></authors></contributors><titles><title>Acomprehensivereviewontheprogressofleadzirconate-basedantiferroelectricmaterials</title><secondary-title>ProgressinMaterialsScience</secondary-title></titles><periodical><full-title>ProgressinMaterialsScience</full-title></periodical><pages>1-57</pages><volume>63</volume><number>8</number><dates><year>2014</year></dates><urls></urls></record></Cite></EndNote>[4]参考文献[1] LIF,ZHANGS,LIZ,etal.弛豫铁电单晶的研究进展——压电效应的起源研究[J].物理学进展,2012.[2] LIJ,FEIL,ZHANGS.DecodingtheFingerprintofFerroelectricLoops:ComprehensionoftheMaterialPropertiesandStructures[J].JOURNALOF