危险品DangerousGoodsBriefing.ppt

Jun 2009,危險品簡介 Dangerous Goods Briefing,2,內容 Contents,3,認識危險品條例 Introduction of Dangerous Goods Regulation,危險品簡介 Dangerous Goods Briefing,危險品條例 Dangerous Goods Regulation (DGR),帶有潛在危險的付運貨物均被列為危險品, 但透過適當的處理程序仍可以空運運送. 為確保能安全運送, 國際民航組織 (ICAO) 辦佈了 Technical Instruction (TI) 作為安全付運指引. 國際航空運輸協會 (IATA) 的危險品條例 (DGR) 經國際民航組織 (ICAO) 認可, 並加入相關之運作及程序指引. Dangerous goods are commodities that possess potentially dangerous features. These features will not make their transportation by air dangerous, provided that suitable precautions are taken. There are internationally agreed rules to ensure the safe transportation of dangerous goods by air. These are published by the International Civil Aviation Organization (ICAO) as the Technical Instructions (TI) for the Safe Transport of Dangerous Goods by Air. The IATA DGR are recognized by ICAO as the field document for the transport of dangerous goods by air. The DGR is complied with ICAO Technical Instructions and in some cases are more restrictive, by taking account of industry practices or operational considerations.,4,內容 Contents,5,危險品分類 Classification,危險品簡介 Dangerous Goods Briefing,九個類別的危險品 9 Classes of Dangerous Goods 第 1 類 爆炸品 Class 1 Explosives 第 2 類 氣體 Class 2 Gases 第 3 類 易燃液體 Class 3 Flammable Liquid 第 4 類 易燃固體 Class 4 Flammable Solid 第 5 類 氧化劑及有機過氧化物 Class 5 Oxidizing Substances and Organic Peroxides 第 6 類 毒性及傳染性物質 Class 6 Toxic and Infectious Substances 第 7 類 放射性物質 Class 7 Radioactive Material 第 8 類 腐蝕性物品 Class 8 Corrosives 第 9 類 雜項危險物品 Class 9 Miscellaneous Dangerous Goods 危險品的類別是以個位數字表達. 如, 第 9 類. Classes are expressed by single digit numbers. For example, “Class 9”,6,危险品分类,爆炸品类： 雷管 传爆助爆管 导爆索 导火索 火帽 引信 炸药 烟火制品（礼花鞭炮、摔、拉炮等） 点火绳 发令纸,7,危险品分类,压缩气体和液化气体类： 甲烷 乙烷（压缩、液化的） 丙烷 丁烷 打火机（可限量携带） 微型煤气炉用贮气罐 气体杀虫剂,8,危险品分类,易燃液体类： 汽油、酒精、去光水、引擎开导液、鸡眼水、染皮鞋水、打字蜡纸改正液、强力胶、汽车门窗胶、橡胶水、脱漆剂、环氧树脂、油漆、皮革光亮剂、显影液、印刷油墨、煤油、樟脑油、松节油、松香水、擦铜水、钮扣磨光剂、油画上光油、刹车油、防冻水、柴油；,9,危险品分类,易燃固体类： 红磷 硫磺 火补胶 自燃物品类： 黄磷 油布 遇湿易燃物品类： 金属钠 镁铝粉,10,危险品分类,氧化剂和有机过氧化物类： 过氧化氢（双氧水） 硝酸铵 氯酸钾,11,危险品分类,毒害品类： 氰化物 砷 赛力散 灭鼠安（含各类鼠药） 敌百虫等杀虫剂 来草松等灭草剂,12,危险品分类,放射性物品类： 夜光粉 发光剂 放射性同位素,13,危险品分类,腐蚀品类： 硝酸 硫酸 盐酸 苛性纳,14,危險品分類 Classification,危險品簡介 Dangerous Goods Briefing,項目 Divisions 部份類別再細分為項目以表達該物品的特有的危險性. 只有第 1, 2, 4, 5, 6 類再細分為項目. 項目以兩位數子表達. 第一位數字代表類別, 第二位數字代表該類別細分的項目.如, 氧化劑屬於第五類的第一項, 亦即 5.1 項。 類別及項目編號順序並非相應的危險等級, 只為方便使用. (如第 1 類不一定比第 2 類危險品危險) Classes are further divided into “Divisions” to identify a particular risk within the class. Only Dangerous Goods in Classes 1, 2, 4, 5 and 6 are with divisions. Division are expressed by 2 digit numbers. The first digit identifies the Class number and the second identifies the variation within that class. For example, oxidizer is Class 5, Division 1 which should read as “Division 5.1” The order in which the classes are numbered is for convenience and does not imply a relative degree of danger. (ie. Class 1 is not necessarily more dangerous than Class 2 or 3),15,危險品分類 Classification,危險品簡介 Dangerous Goods Briefing,第 1 類 爆炸品 Class 1 Explosive (Division 1.1 1.6),16,危險品分類 Classification,危險品簡介 Dangerous Goods Briefing,第 1 類 爆炸品 Class 1 Explosive (Division 1.1 1.6),17,危險品分類 Classification,危險品簡介 Dangerous Goods Briefing,第 2 類 氣體 Class 2 Gases (Division 2.1 2.3),18,危險品分類 Classification,危險品簡介 Dangerous Goods Briefing,第 3 類 易燃液體 Class 3 Flammable liquids,19,危險品分類 Classification,危險品簡介 Dangerous Goods Briefing,第 4 類 易燃固體 Class 4 Flammable Solid (Division 4.1 4.3),20,危險品分類 Classification,危險品簡介 Dangerous Goods Briefing,第 5 類 氧化劑及有機過氧化物 Class 5 Oxidizing Substances and Organic Peroxides (Division 5.1 5.2),21,危險品分類 Classification,危險品簡介 Dangerous Goods Briefing,第 6 類 毒性及傳染性物質 Class 6 Toxic and Infectious substances (Division 6.1 6.2),22,危險品分類 Classification,危險品簡介 Dangerous Goods Briefing,第 7 類 放射性物質 Class 7 Radioactive materials,23,危險品分類 Classification,危險品簡介 Dangerous Goods Briefing,第 7 類 放射性物質 Class 7 Radioactive materials,24,危險品分類 Classification,危險品簡介 Dangerous Goods Briefing,第 8 類 腐蝕性物品 Class 8 Corrosives,25,危險品分類 Classification,危險品簡介 Dangerous Goods Briefing,第 9 類 雜項危險物品 Class 9 Miscellaneous dangerous goods,Handling Label 處理標籤,26,內容 Contents,27,危險品辨認 Identification,危險品簡介 Dangerous Goods Briefing,運輸專用名稱 Proper Shipping Name 各危險都被編上由聯合國專家委員會訂立的運輸專用名稱及聯合國編號. 如沒有聯合國編號則須採用 8000 系列的編號. 危險品列表 (IATA DGR Subsection 4.2) 包含超過三千種經常於空運運載的物質. 此列表亦會顯示運輸專用名稱, 聯合國編號, 最高可接受於空運客機或貨機運載的危險品數量. 例 : Flammable solid, organic, n.o.s 的聯合國編號為UN1325 Dangerous goods are identified by proper shipping name and UN numbers. These names and numbers are assigned under the UN classification system to specific articles or substance. In cases where a UN number has not yet been assigned, an identification (ID) number in the 8000 series is assigned. Subsection 4.2 contains over 3,000 articles and substance with dangerous properties which are mostly likely to be shipped by air. This section also indicated the proper shipping name, UN number and maximum quantities of each products permitted per package on Passenger and/or Cargo Aircraft Only. The list is not intended to be all inclusive, therefore it contains several names of a general nature, known as n.o.s (not otherwise specified) names or entries, under which unlisted items may be transported. Example UN number for Flammable solid, organic, n.o.s. is UN1325,28,危險品辨認 Identification,危險品簡介 Dangerous Goods Briefing,危險品列表 Example of Subsection 4.2,29,內容 Contents,30,危險品標記及標籤 Marking & Labelling,危險品簡介 Dangerous Goods Briefing,例子 Example,31,危險品標記及標籤 Marking & Labelling,危險品簡介 Dangerous Goods Briefing,u n,聯合國規格標記 UN Specification Marking ( Ref Table 6.0.C ),32,危險品標記及標籤 Marking & Labelling,危險品簡介 Dangerous Goods Briefing,處理標籤 Handling Labels 提供正確處理及裝載危險品包裝的資料 Certain Dangerous Goods require special handling labels in addition to the hazard label, because they need to be handled or loaded in a particular manner.,33,危險品標記及標籤 Marking & Labelling,危險品簡介 Dangerous Goods Briefing,處理標籤 Handling Labels,34,危險品標記及標籤 Marking & Labelling,危險品簡介 Dangerous Goods Briefing,處理標籤 Handling Labels,35,危險品標記及標籤 Marking & Labelling,危險品簡介 Dangerous Goods Briefing,其他標記 Additional Markings,36,內容 Contents,37,寄送空氣危險品, 寄貨人除了一般空氣寄貨文件 (如空運提單, 發票, 裝箱單) 外, 必須填報危險品申報單 (DGD). 寄貨人有責任根據根據國際航空運輸協會 (IATA) 的危險品條例 (DGR) 填報所須資料. All cargo must be accompanied with relevant documents when carrying by air transportation. It includes the airway bill ( AWB ) or Air Consignment Note and the accompanied customers documents like the Invoice, Packing List. In addition, the Shippers Declaration For Dangerous Goods ( DGD ) must be accompanied with most of the dangerous goods. The shipper is responsible for the completion of a DGD in the IATA format for shipment containing dangerous goods as defined in, or classified according to the DGR.,寄貨人申報及其他相關文件 Shippers Declaration & Other Relevant Documents,危險品簡介 Dangerous Goods Briefing,相關文件 Relevant Documents,38,此危險品申報單可以黑或紅色字體印在白紙上. 兩旁印上紅色斜紋. This form may be printed in black and red on white paper or in red only. The diagonal hatchings printed vertically in the left and right margins must be printed in red.,寄貨人申報及其他相關文件 Shippers Declaration & Other Relevant Documents,危險品簡介 Dangerous Goods Briefing,寄貨人及收貨人資料 Shipper and Consignee Info.,運載詳情 Transportation Details,危險品資料及數量 Nature and Quantity of Dangerous Goods,其他資料 Additional Handling Info.,寄貨人及其簽署 Name / Title of Signatory,危險品申報單 DGD ( 斑馬紙 ),39,寄貨人申報及其他相關文件 Shippers Declaration & Other Relevant Documents,危險品簡介 Dangerous Goods Briefing,此句句子 : Dangerous Goods as per attached shippers declaration or Dangerous Goods as per attached DGD,危險品一般敘述 (不需運輸專用名稱) The description of the dangerous goods should be a general description of the rating or customs requirement. It does not need to be the proper shipping name,危險品空運提單 AWB When shipment containing Dangerous Goods 危險品空運提單必須包括: The completion of Air Waybills for shipment containing dangerous goods have very specific requirements.,40,寄貨人申報及其他相關文件 Shippers Declaration & Other Relevant Documents,提供化學品的基本資料包括, 確認危險品類別, 發生事故時之處理方法, 儲存方式. The purpose of MSDS is to provide the basic data of a chemical which can help us in determined the class / division of dangerous goods in different mode of the transportation. In addition, it is very useful when some of the incident and accident happened related with this chemical. It can provide appropriate emergency response for the medical. It also included the handling, storage and disposal requirement of this chemical.,危險品簡介 Dangerous Goods Briefing,化學品安全技術說明 Materials Safety Data Sheets ( MSDS ),41,寄貨人申報及其他相關文件 Shippers Declaration & Other Relevant Documents,危險品簡介 Dangerous Goods Briefing,化學品安全技術說明 Materials Safety Data Sheets ( MSDS ) 大部份化學品須有安全技術說明, 用以說明 Most of the chemicals do have the MSDS. It helps to 分別危險品類別 Identify hazard 急救方法及程序 First Aid measures and procedure 消防方法 Fire Fighting Measures 危險品處理及儲存 Handling and Storage 物理及化學特性 Physical and chemical properties 運載詳情 Transportation Information 如上圖 Example - Potassium Cyanide, Rhodorsil Crosslinking Agent NO 1,42,內容 Contents,43,“Not Restricted“ Battery Shipment,Dry Battery shipped as “Not restricted” cargo Documentation requirements: Non-DG Dry battery Declaration MSDS / PSDS or Laboratory Test Report or Certificate for Transport of Air Cargo. (For proving the dry battery are not restricted under Special Provision A123),危險品簡介 Dangerous Goods Briefing,44,Proper Shipping Name & UN number Packing and Marking Packing Instruction PI965 PI970 The watt-hour rating must be marked on the outside of the battery case (for Lithium Ion ),“Not Restricted“ Battery Shipment,Lithium Battery shipped as “Not restricted” cargo,危險品簡介 Dangerous Goods Briefing,45,“Not Restricted“ Battery Shipment,Lithium Battery shipped as “Not restricted” cargo,危險品簡介 Dangerous Goods Briefing,Lithium-ion Cells / Batteries shipped as Not Restricted Cargo 1. Must comply with Part 1 of PI965 PI967 accordingly. 2. For cells, the Watt-hour rating should not be more than 20Wh. 3. F