有机化学综合练习二(完成反应式).doc

有机化学综合练习二完成反应式（写出主要产物或注明反应条件）1CH3-C CH + 2HCl CHO 2 + 3. CH3 + HBr HgSO4H2SO4 4 CH3-CH C CH + H2O CH3 -C-CH3O 5 + (CH3CO)2O 6. CH3OCH2CH3 + HI 浓 H2SO4CH3 OH7.CH3-CHCH-CH2-CH2CH3 -NH2 8 + (CH3CO)2CO CH3-CHCCH3 HBrCH39.过氧化物CH3-CH=C-CH2-CH3 + HBrCH310. 光 11CH3-CH=CH2 + Cl2 稀OH 12 CH3-CH2-CHO H2NNH2 H2O , NaOH高沸点溶剂，加热O13CH3-CHCH2CCH3 Zn-Hg/浓HClO14 C-CH2-CH2CH3 KOH乙醇CH3Br CH3-CH-CH-CH2CH3 15. -NO2-NH216 NaBH4O17CH2=CH-CH2CH2-CCH3 -COOH 18 + SOCl2 KMnO4,H+N-CH319 浓HNO3O20 CH3-CHC-CH2-CH3CH3-CHCH2-CH2-CH3BrBrO. 21 22 CH=CH-CHO -CH=CH-CH2OH O23CH3CCH2COOH KMnO424 CH(CH3)2 SCH3COONO2乙酐 -1025 H2SO4N26 CH3 CH3 27. ClKMnO428CH3 C(CH3)3 CH2COOHCH2COOH29 O二氧六环 030. + Br2 -CH3光 31 + Cl2 -N2+Cl- + -OH-N=N- -OH32. 浓NaOHCHO + HCHO33. ClClO 34. CH3-CH-CH2-C-CH3 CH3-CH-CH2-CH2-CH3 CHO + H2N-NH-35. O36. CH3CCH2COOHNKMnO4/H+CH337. KOH-乙醇，CH3Br38. O2,V2O539. O40. C H2 CHCH2CCH2CH3 C H2 CHCH2CH2CH2CH3 参考答案CHOClClCH3CCH31 2、CH3CH3-CHCCH3OBrCH3CHCH2CH33、 4、 NH-C-CH3O5、无水三氯化铝 6、CH3I + CH3CH2OH CH3 CH3-C=CH-CH2-CH2CH37 8、 CH3-CH2CCH3 CH3BrCH3-CH-CH-CH2-CH3 CH3Br9、 10、 CH3CH2CHCHCHOOH CH311. ClCH2-CH=CH2 12. CH2-CH2-CH2-CH313. CH3-CHCH2CH2CH3 14. CH3-C=CH-CH2-CH3CH31516. Fe + HCl-COClOH17. CH2=CH-CH2CH2-CHCH3 18. CH2CH2COOHCH2CH2COOHN-COOH19. 20. Zn-Hg/浓HCl20. 22. LiAlH4 或NaBH4-COOHO23CH3CCH3 24、 -SO3HNSNO225. 26. HOOC- C(CH3)327. KOH/乙醇 28、OBrCH2-CCH2-COOO29. 30. CH2Cl 31. 32. 弱碱性 COOH + CH3OH33. 34. Zn-Hg/浓HCl, 加热