河南省郑州市荥阳市实验高中高三化学上学期10月月考试卷（含解析）.doc

2015-2016学年河南省郑州市荥阳市实验高中高三（上）月考化学试卷（10月份）一、选择题（每题3分，共48分）1如图为雾霾的主要成分示意图下列说法不正确的是( )a重金属离子可导致蛋白质变性b苯是最简单的芳香烃c向空气中大量排放so2和nxoy都能引起酸雨和光化学烟雾d汽车尾气的大量排放是造成雾霾天气的人为因素之一2下列说法不正确的是( )a油脂是高级脂肪酸的甘油酯b油脂与氢气发生加成反应，可以得到硬化油c油脂在酸性条件或碱性条件下，可以发生皂化反应d日常使用的花生油、豆油、动物油都是油脂，它们可以溶解一些脂溶性维生素3通过对实验现象的观察、分析推理得出正确的结论是化学学习的方法之一对下列实验事实的解释不正确的是( )现象解释或结论aso2使酸性高锰酸钾溶液退色so2表现还原性b浓hno3在光照条件下变黄浓hno3不稳定，生成有色产物能溶于浓硝酸c某溶液中加入浓naoh溶液加热，放出气体能使湿润的红色石蕊试纸变蓝该溶液中一定含有nh4+d铝片放入浓硫酸中，无明显变化说明铝与冷的浓硫酸不发生化学反应aabbccdd4用na表示阿伏加德罗常数的值，下列说法正确的是( )a11.2 l氧气中所含有的原子数为nab7.8g的na2o2中含有的阴离子的数目为0.2nac0.10mol fe 粉与足量水蒸气反应生成的h2分子数为0.10nad54g al分别与足量的稀硫酸及氢氧化钠溶液反应失去的电子数都是6na5在t时，向x g kno3不饱和溶液中加入a g kno3或蒸发掉b g水，恢复到t，溶液均达到饱和，据此，下列推论不正确的是( )a在t时，kno3的溶解度为gb若原溶液中溶质的质量分数为，则x=2bc在t时，所配的kno3溶液中溶质的质量分数为w%d若将原溶液蒸发掉2b g水，恢复到原温度析出2a g kno36下列离子方程式正确的是( )a0.01mol/l nh4al（so4）2溶液与0.02mol/l ba（oh）2溶液等体积混合nh4+al3+2so42+2ba2+4oh2baso4+al（oh）3+nh3h2obfecl2酸性溶液放在空气中变质：2fe2+4h+o22fe3+2h2oc用ch3cooh溶解caco3：caco3+2h+ca2+h2o+co2d电解mgcl2水溶液的离子方程式：2cl+2h2oh2+cl2+2oh7已知金刚石的燃烧热为395kj/mol，下表是部分化学键的键能数据下列选项中正确的是( )化学键cco=oc=o键能（kj/mol）348498xax=794.5bx=1142.5c1mol金刚石的能量一定比1mol co2能量高d金刚石燃烧的热化学方程式为 2c（s）+o2（g）=2co（g）h=790 kj/mol8如图为两个原电池装置图，由此判断下列说法错误的是( )a当两电池转移相同电子时，生成和消耗ni的物质的量相同b两装置工作时，盐桥中的阴离子向负极移动，阳离子向正极移动c由此可判断能够发生2cr3+3ni=3ni2+2cr和ni2+sn=sn2+ni的反应d由此可判断cr、ni、sn三种金属的还原性强弱顺序为：crnisn9二氯化二硫（s2cl2）是广泛用于橡胶工业的硫化剂，其分子结构如图所示常温下，s2cl2是一种橙黄色液体，遇水易水解，并产生能使品红褪色的气体，化学方程式为：2s2cl2+2h2o=so2+3s+4hcl下列说法中错误的是( )as2cl2的结构式为clssclb反应中so2是还原产物，s是氧化产物cs2cl2为含有极性键和非极性键的分子d反应中，生成1molso2，转移电子为3mol10硫酸锶（srso4）在水中的沉淀溶解平衡曲线如下下列说法正确的是( )a温度一定时，ksp（srso4）随c（so42）的增大而减小b三个不同温度中，313k时ksp（srso4）最大c283k时，图中a点对应的溶液是不饱和溶液d283k下的srso4饱和溶液升温到363k后变为不饱和溶液11如图是草酸溶液中h2c2o4、hc2o4三种微粒的分布分数（某微粒物质的量浓度与三种微粒物质的量被度和的比值）与ph的关系图，下到有关说法不正确的是( )aph=5的溶液中c（c2o42）c（hc2o4）bnahc2o4溶液中：c（oh）+c（c2o42）=c（h+）+c（h2c2o4）c向nahc2o4溶液中加强酸至ph与a点对应时，溶液中2c（na+）=c（hc2o4）+c（h2c2o4）d为使溶液中c（hc2o4）尽可能多一些，溶液的ph最好控制在2.7左右12分子式为c10h12o2的有机物，满足以下两个条件：苯环上有两个取代基，能与nahco3反应生成气体则满足条件的该有机物的同分异构体有( )a9b10c12d1513在450、5.05107pa时，如果把1体积n2和3体积h2的混合物通入一个装有催化剂的密闭容器中反应达到平衡时，得到含nh352%（体积分数）的混合气体在同温同压下向密闭容器中通入2体积n2和6体积h2，达到平衡时nh3的体积分数为( )a大于52%b等于52%c小于52%d不能确定14已知反应2no2（g）+o3（g）n2o5（g）+o2（g），若反应在恒容密闭容器中进行，下列由该反应相关图象作出判断正确的是( )a升高温度，平衡常数减小b03内，反应速率为v（no2）=0.2moll1ct1时仅加入催化剂，平衡正向移动d达平衡时，仅改变x，则x为c（o2）15下列实验现象预测正确的是( )a实验：振荡后静置，上层溶液颜色保持不变b实验：酸性kmno4溶液中出现气泡，且颜色逐渐褪去c实验：微热稀hno3片刻，溶液中有气泡产生，广口瓶内始终保持无色d实验：继续煮沸溶液至红褐色，停止加热，当光束通过体系时可产生丁达尔效应16高铁电池是一种新型可充电电池，与普通高能电池相比，该电池能长时间保持稳定的放电电压高铁电池的总反应为：3zn+2k2feo4+8h2o3zn（oh）2+2fe（oh）3+4koh 下列叙述不正确的是( )a放电时负极反应为：3zn6e+6oh3zn（oh）2b充电时阳极反应为：fe（oh）33e+5ohfeo42+4h2oc放电时每转移3 mol电子，正极有1 mol k2feo4被还原d充电时阴极溶液的碱性减弱二、填空题（52分）17亚硝酸钠易溶于水，有碱味，有氧化性，也有还原性nano2大量用于染料工业和有机合成工业中，也可用作水泥施工的抗冻剂然而由于nano2有毒性，将含该物质的废水直接排放会引起水体严重污染，所以这种废水必须处理后才能排放处理方法之一如下：_nano2+_ki+_no+_i2+_k2so4+_na2so4+_（1）请完成该化学方程式并配平（2）在上述反应中，若要生成50.8g i2，则电子转移了_个（3）现有25.00ml的ki溶液，用酸化的10.00ml 0.000mol/l的kio3溶液处理（5i+io3+6h+=3i2+3h2o）将生成的i2全部除去后，再加入过量的ki溶液，使之与剩余的kio3反应，然后将溶液调节至中性，析出的单质碘用0.1000mol/l的na2s2o3溶液滴定（2s2o32+i2=s4o6+2i），用去该溶液的体积为21.00ml求剩余的kio3为_ mol，原ki溶液的物质的量浓度是_mol/l18（16分）甲烷是天然气的主要成分，是生产生活中应用非常广泛的一种化学物质（1）一定条件下，用甲烷可以消除氮氧化物（nox）的污染已知：ch4（g）+4no（g）2n2（g）+co2（g）+2h2o（g）h1ch4（g）+4no2（g）4no（g）+co2（g）+2h2o（g）h2现有一份在相同条件下对h2的相对密度为17的no与no2的混合气体，用16g甲烷气体催化还原该混合气体，恰好生成氮气、二氧化碳气体和水蒸气，共放出1042.8kj热量该混合气体中no和no2的物质的量之比为_已知上述热化学方程式中h1=1160kj/mol，则h2=_在一定条件下no气体可以分解为no2气体和n2气体，写出该反应的热化学方程式：_（2）以甲烷为燃料的新型电池，其成本大大低于以氢气为燃料的传统燃料电池，目前得到广泛地研究，如图是目前研究较多的一类固体氧化物燃料电池工作原理示意图回答下列问题：b极为电池_极，电极反应式为_若用该燃料电池作电源，用石墨作电极电解100ml 1mol/l的硫酸铜溶液，当两极收集到的气体体积相等时理论上消耗的甲烷的体积为_（标准状况下），实际上消耗的甲烷体积（折算到标准状况）比理论上大，可能原因为_19黄铁矿（主要成分为fes2）是我国大多数硫酸厂制取硫酸的主要原料某化学学习小组对某黄铁矿石进行如下实验探究实验一测定硫元素的含量、将m1 g该黄铁矿样品放入如图所示装置（夹持和加热装置省略）的石英管中，从a处不断地缓缓通入空气，高温灼烧石英管中的黄铁矿样品至反应完全石英管中发生反应的化学方程式为：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