亚硫酸钠化学品安全技术说明书.doc

亚硫酸钠Sulfurous acid sodium第一部分：化学品名称First part:Chemicals name化学品中文名称： 亚硫酸钠Chemicals Chinese name: Sulfurous acid sodium化学品英文名称： sodium sulfiteChemicals English name: sodium sulfite中文名称2：Chinese name 2:英文名称2：English name 2:技术说明书编码： 1331 Technique manual coding: 1331 分子式： Na2SO3Molecular formula: Na2SO3分子量： 126.04 Molecular weight: 126.04 第二部分：成分/组成信息Second part:Composition/constitute an information有害物成分 含量 CAS No. Harmful thing composition content CAS No. 亚硫酸钠 Sulfurous acid sodium 第三部分：危险性概述Third part:Does the risk outline危险性类别：Risk category:侵入途径：Invade path:健康危害： 对眼睛、皮肤、粘膜有刺激作用。Healthy harm: To eyes, skin, glue a film have already stimulated a function. 环境危害： 对环境有危害，对水体可造成污染。 The environment endangers: Have harm to the environment, can result in a pollution to water body. 燃爆危险： 本品不燃，具刺激性。 The Ran explodes dangerous: This article is non-combustible, have stimulative. 第四部分：急救措施Four-part cent:Give first aid measure皮肤接触： 脱去污染的衣着，用大量流动清水冲洗。 The skin gets in touch with: Take off polluting clothes, flush with a great deal of fluxion clear water. 眼睛接触： 提起眼睑，用流动清水或生理盐水冲洗。Eyes get in touch with: Bring up eyelids, use to flow clear water or physiology brine to flush.就医。 Cure. 吸入： 脱离现场至空气新鲜处。Inhalation: Escape from the spot to the air fresh place.如呼吸困难，给输氧。It is like dyspnea, give to lose oxygen.就医。 Cure. 食入： 饮足量温水，催吐。The food goes into: Drink amount of foot Wen Shui, urge to vomit.就医。 Cure. 第五部分：消防措施Fifth part:Fire fight measure 危险特性： 未有特殊的燃烧爆炸特性。Dangerous characteristic: Have never there been special combustion explosion characteristic.受高热分解产生有毒的硫化物烟气。 Be subjected to sulphide of the hot decomposition creation poison smoke spirit. 有害燃烧产物： 硫化物。 Harmful combustion outcome: Sulphide. 灭火方法： 消防人员必须穿全身防火防毒服，在上风向灭火。Extinguish fire a method: The fire fighter has to wear whole body fire prevention the anti-virus take, at up the direction of wind extinguish fire.灭火时尽可能将容器从火场移至空旷处。 Move from fire field to open spaces place of container possibly while extinguishing fire. 第六部分：泄漏应急处理Sixth part:Does the leakiness meet an emergency a processing应急处理： 隔离泄漏污染区，限制出入。Meet an emergency a processing: The insulation leaks to pollute area, restriction discrepancy.建议应急处理人员戴防尘面具（全面罩），穿防毒服。The suggestion meets an emergency to handle a personnel to wear a dust palliative mask(cover completely) and wears an anti-virus to take.避免扬尘，小心扫起，置于袋中转移至安全场所。Avoid a Yang dust, carefully start to sweep, Be placed to in the bag to transfer into safe place.也可以用大量水冲洗，洗水稀释后放入废水系统。Can also flush with a great deal of water, put into waste water system after washing water dilution.若大量泄漏，用塑料布、帆布覆盖。If in great quantities leak, use a plastics cloth, canvas overlay.收集回收或运至废物处理场所处置。 Collections recall or carry into a discard processing place handle. 第七部分：操作处置与储存Seventh part:Operate treatment and storage操作注意事项： 密闭操作，加强通风。Operate a regulation: Closeness operation strengthens airiness.操作人员必须经过专门培训，严格遵守操作规程。Operating the personnel has to pass by specialized training, strictly obey operate regulations.建议操作人员佩戴自吸过滤式防尘口罩，戴化学安全防护眼镜，穿防毒物渗透工作服，戴橡胶手套。Suggest to operate a personnel to wear from absorb the percolation type dust palliative mouth-muffle, wear chemistry safe protection glasses, wear an anti-virus thing to permeate smock, wear rubber gloves.避免产生粉尘。Avoid producing dust.避免与酸类接触。Avoid contacting the acids.搬运时轻装轻卸，防止包装破损。The casual wear lightly unloads while transporting and preventfrom a packing breakage.配备泄漏应急处理设备。The equipment leakiness meets an emergency to handle an equipments.倒空的容器可能残留有害物。 Pouring the empty container may remain a harmful thing. 储存注意事项： 储存于阴凉、通风的库房。Store a regulation: Store on cool and well ventilated database building.远离火种、热源。Keep off a material for new fire, hot source.应与酸类等分开存放，切忌混储。Should wait with acids to separately deposit, slice to hate to mix to keep.不宜久存。Should not be long to save.储区应备有合适的材料收容泄漏物。 Keeping the area should have suitable material to accept to permit to leak a thing. 第八部分：接触控制/个体防护 Eighth part:Get in touch with a control/individual protection职业接触限值 The occupation gets in touch with a limit value中国MAC(mg/m3)： 未制定标准 MAC China:(mg/m 3) Dont draw up standard前苏联MAC(mg/m3)： 0.2 The former Soviet Union MAC:(mg/m 3) 0.2TLVTN： 未制定标准 TLVTN: Dont draw up standardTLVWN： 未制定标准 TLVWN: Dont draw up standard监测方法：Monitor a method:工程控制： 生产过程密闭，加强通风。 The engineering controls: Production line closeness strengthens airiness. 呼吸系统防护： 空气中粉尘浓度超标时，必须佩戴自吸过滤式防尘口罩。Breathe a system protection: When the dust density is over-standard in the air, have to wear from absorb the percolation type dust palliative mouth-muffle.紧急事态抢救或撤离时，应该佩戴空气呼吸器。 Urgent circumstances salvage or withdraw, should wear an air breather. 眼睛防护： 戴化学安全防护眼镜。 Eyes protection: Wear chemistry safe protection glasses. 身体防护： 穿防毒物渗透工作服。 Body protection: Wear an anti-virus thing to permeate smock. 手防护： 戴橡胶手套。 Hand protection: Wear rubber gloves. 其他防护： 及时换洗工作服。Other protections: Change to wash smock in time.保持良好的卫生习惯。Keep a good hygiene habit. 第九部分：理化特性Ninth part:Physics and chemistry characteristic主要成分： 纯品 Main composition: Pure article外观与性状： 无色、单斜晶体或粉末。 External appearance and sex-like in shape: Have no color, single inclined crystal or powder. pH：PH:熔点()： 150(失水分解) Melting point:() 150沸点()： 无资料(lose a humidity solution)Boiling point:() Have no data相对密度(水=1)： 2.63 Opposite density:(water=1) 2.63 相对蒸气密度(空气=1)： 无资料 Opposite fume density:(air=1) Have no data饱和蒸气压(kPa)： 无资料The saturated fume presses(kPa): Have no data燃烧热(kJ/mol)： 无意义 Is burnable hot(kJ/mol): Is nonsense临界温度()： 无意义 Critical temperature:() Is nonsense临界压力(MPa)： 无意义 Critical pressure(MPa): Is nonsense辛醇/水分配系数的对数值： 无资料 Xin Chun/humidity goes together with the logarithms value of coefficient: Have no data闪点()： 无意义The Shan orders:() Is nonsense引燃温度()： 无意义Emblaze temperature:() Is nonsense爆炸上限%(V/V)： 无意义Explode an upper limit%(V/V): Is nonsense 爆炸下限%(V/V)： 无意义The limit (V/V)in explosion%: Is nonsense溶解性： 易溶于水，不溶于乙醇等。 Fuse sex: Easily being dissolved to water isnt dissolved to ether etc. 主要用途： 用于制亚硫酸纤维素酯、硫代硫酸钠、有机化学药品、漂白织物等, 还用作还原剂、防腐剂、去氯剂等。 Main use: Used for making the sodium sulfate, organic chemistry drugs of the sulfurous acid cellulose ester, sulphur generation and bleach fabric etc., also used to a revivification, antiseptic and go to a chlorine etc. 其它理化性质：Other physics and chemistry properties:第十部分：稳定性和反应活性Tenth part:Stability and reaction activity 稳定性：Stability禁配物： 强酸、铝、镁。 Forbid to go together with a thing: Is strong sour, aluminum, magnesium. 避免接触的条件：Avoid a contiguous condition: 聚合危害：Come together harm: 分解产物：Resolve an outcome:第十一部分：毒理学资料 11th part:Does the poison reason learn data 急性毒性： LD50：无资料Impatient toxicity: LD50:Have no data: 亚急性和慢性毒性：Second impatient and chronic toxicity:刺激性：Stimulative:致敏性：To the quick致突变性：To mutating sex:致畸性：To the Ji:致癌性：Cancer-causing:第十二部分：生态学资料 12th part:Ecology data生态毒理毒性：The ecosystem poison manages a toxicity:生物降解性：The living creature declines to solve sex:非生物降解性：The non- living creature declines to solve sex:生物富集或生物积累性：The living creature is rich to gather or the living creature backlog:其它有害作用： 该物质对环境有危害，应特别注意对水体的污染。 Other harmful function: The material has harm to the environment, in response to the pollution of special attention to water body. 第十三部分：废弃处置13th part:Abandon treatment 废弃物性质：Wastes property:废弃处置方法： 处置前应参阅国家和地方有关法规。 Abandon a treatment method: Should read a nation to have relation with place before handling laws.中和后，用安全掩埋法处置。 After moderating, bury method treatment with the safety. 废弃注意事项：Abandon a regulation:第十四部分：运输信息14th part:Transport an information 危险货物编号： 无资料Dangerous cargo serial number: Have no dataUN编号： 无资料 UN serial number: Have no data包装标志：Packing mark:包装类别： Z01 Pack a category: Z01包装方法： 无资料。 Pack a method: Have no data. 运输注意事项： 起运时包装要完整，装载应稳妥。Transport a regulation: While rising luck the packing has to be complete and load should steady.运输过程中要确保容器不泄漏、不倒塌、不坠落、不损坏。Transport to want to ensure that the container doesnt leak, dont tumble down, dont sink into in the process, not damage.严禁与酸类、食用化学品等混装混运。Strictly f