有机化学(第二版)-夏百根-黄乾明-主编-课后答案

第二章第二章烷烃作业参考答案烷烃作业参考答案 1 共有九种共有九种 CH3 CH2 CH2 CH2 CH2 CH2 CH3CH3 CH CH2 CH2 CH2 CH3 CH2 CH3 CH2 CH CH2 CH2 CH3 CH3 CH3 CH CH CH2 CH3 CH3CH3 CH3 CH CH2 CH CH3 CH3CH3 CH3 C CH2 CH2 CH3 CH3 CH3 CH3 CH2 C CH2 CH3 CH3 CH3 CH2 CH CH2 CH2 CH2 CH3 CH3 C CH3 CH3 CH CH3 CH3 2 1 3 甲基戊烷 2 2 5 二甲基 3 4 二乙基己烷 3 2 2 3 4 四甲基戊烷 4 2 甲基 5 乙基庚烷 5 2 甲基 3 环丁基丁烷 6 顺 1 甲基 3 乙基环戊烷 7 反 1 甲基 4 乙基环己烷 8 1 甲基 4 乙基 3 叔丁基 环己烷 3 1 2 CH3 CH CH2 CH2 CH3 CH3 CH3 C CH2CH3 CH3 CH3 3 4 CH3 CH CH CH CH CH3 CH3 CH3 CH2CH3 CH2CH3 CH3 H H C CH3 3 4 1 2 CH3CH2 C CH3 CH CH3 CH3 CH3 C CH CH CH3 CH3 CH3 CH3 CH3 CH C CH2 CH3 CH3 CH3 CH3 CH3 C CH2 CH CH3 CH3 CH3 CH3 5 1 错 改为 2 2 二甲基丁烷 2 错 改为 2 2 5 三甲基 4 乙基己烷 3 正确 4 错 改为 2 2 二甲基丁烷 6 1 改为 H H3CC2H5 CH3 H H CH3CH2CHCH2CH3 CH3 3 甲基戊烷 2 CH CH3 2 H3CCl CH3 HH CH3 CH2 C CH CH 2 CH3 Cl 2 3 二甲基 2 氯丁烷 7 C1 C2旋转 OH HH C2H5 H H OH HH H H C2H5 OH HH C2H5 H H OH HH H H C2H5 优势构象 C2 C3旋转 HH H H HH H CH3 CH2OH HH CH3 H H CH2OH HH H H CH3 CH2OHH3C CH2OH H 优势构象 8 1 2 3 CH2CH2CH3 CH2CH3 CH3 CH CH3 2 OH CH2CH3 H3C 9 1 2 3 4 10 A B CH3 CH2 CH2 CH2 CH3C CH3 CH CH2 CH3 CH3 CH3 C CH3 CH3 CH3 11 4 3 1 2 12 CH3CH2CH3 CH3 Br2 CH3 CH3CH2CH3 14 1 HI CH3 CH CH2CH3 I CH3 2 C2H5 CH3 H2SO4 CH3 CH2 C CH2CH2CH3 CH3 OSO3H CH3 CH2 C CH2CH2CH3 CH3 OH H2O 第三章第三章 烯烃烯烃 炔烃炔烃 二烯烃习题参考答案二烯烃习题参考答案 1 1 2 甲基 4 乙基 3 己烯 2 Z 3 甲基 2 戊烯 3 4 甲基 2 丙基 1 戊烯 4 Z 4 甲基 3 庚烯 5 2 2 二甲基 5 乙基 3 庚炔 6 E 3 甲基 2 溴 2 戊烯 7 2Z 4Z 3 5 二甲基 2 4 庚二烯 8 3E 2 4 二甲基 1 3 己二烯 2 1 2 3 4 CH3 2C C CH2CH3 CH3 C C ClCH3 H H3C CH2 C CH CH2 CH3CH2 CH CH2 CH CH2 5 6 C C H3C CH3 HCH2CH2CH3 C C H3C C C HH HCH3 H 3 1 CH3C C CH3 Br2 CH3C CH CH3 Br CCl4 CH3 CH3 Br 2 CH3 C CH CH3 CH3 Br2 H2O CH3 C CH3 CH CH3 OH Br CH3 C CH3 CH CH3 Br Br 3 CH3 C CH CH3 CH3 ICl CH3 C CH CH3 CH3 Cl I 4 CH3 C CH CH3 CH3 HBr CH3 C CH CH3 CH3 HBr 5 CH3 C CH CH3 CH3 H2SO4 CH3 C CH2 CH3 CH3 OSO3H H2OCH3 C CH2 CH3 CH3 OH 6 CH3 C CH CH3 CH3 KMnO4 H CH3 C O CH3 CH3COOH 7 CH3 C CH CH3 CH3 O3 C H3C H3C O OO CHCH3 H2O Zn CH3 C O CH3 CH3CHO 4 1 CH3CH2C CH HBr 2mol CH3CH2CCH3 Br Br H2O Hg2 H CH3CH2C O CH3 KMnO4 H CH3CH2COOH CO2 H2O CH3CH2C CH2 Ag NH3 2 CN 2 H3C HBr H3C Br 3 CH3 C CH CH3 CH3 NaCl H2O HBr CH3 C CH2 CH3 CH3 Br CH3 C CH CH3 CH3 Cl CH3 C CH2 CH3 CH3 OH 4 CH3 CH CH2 Cl2 CH2 CH CH2 Cl CH2 CH CH CH2 CH2Cl 5 CH2 CH CH CH2 HCl 1mol CH3 CH CH CH2Cl KMnO4 H 1 O3 2 H2O Zn CO2 H2O C O H H O C C O H H CH2 CHCHO CHO 5 1 CH3 CH2 CH3CH2 CH CH3CH C CH3 a bc KMnO4 H b ca Ag NH3 2 c b 2 CH3 CH2 a CH2 CH CH2 CH2CH3b C C CH2 CH2CH3cCH2 CH CH CH CH3d ab c d KMnO4 H Ag NH3 2 c b d S db CH HCCH HC CH CH C C O O O CH3 6 1 CH3C CH3 CH3 CH3 CH CH2 CH3 CH3 CH CH2 CH3 2 CH2 CHCH2 CH3CHCH3 CH3CH2CH2 CH3 3 CH2 H3C CH2 CH2 O2N 7 用浓 H2SO4 8 1 2 3 C CH CH3 H3C H3C CH3CHCH2CH CH2 CH2CH3 CH3 9 3 4 具有 共轭体系 2 具有缺电子的 p 共轭体系 3 具有多电子的 p 共轭体系 1 4 具有 共轭体系 10 A CH3 B CH3 CH2 CH CH3 CH3 C CH3CH2CH CH2 C CH3CH2CH CH2 A CH3 HBr B CH3 CH2 CH CH3 Br HBr 11 A CH3CH CHCH CH3 2 B CH3CH2CH C CH3 2 C CH3CH2CH2CH CH3 2 12 CH3CH CH2C CHA B CH3 C CH2 CH CH2 CH3CH3 13 Cl2 Cl Br2 CH2CH CH2 BrBrCl 1 CH2 CH CH3 CH2 CH CH2 Cl2 Cl HBr H2O2 CH2CH2CH2 BrCl 2 CH2 CH CH3 CH2 CH CH2 3 CH3C CH H2O H2SO4 HgSO4 CH3 C CH3 O 14 O 1 2 H2C 3 COOH 4 O O O 15 CH3 C CH H3C CH2CH2C CHCH3 CH3 第四章第四章芳香烃作业参考答案芳香烃作业参考答案 1 1 邻硝基甲苯 2 3 羟基苯磺酸 3 3 甲基 4 氯苯甲酸 4 1 4 二甲基萘 5 4 甲基 3 苯基 1 戊烯 6 6 氯 2 萘酚 2 1 2 3 4 5 COOH NO2 CH CH2 Cl SO3H CH3 Cl NO2 CH3 CH CH3 2 CH2CH3 6 H3CO Cl COOH 3 1 COOH Cl2 Fe COOH Cl 2 CH3 Cl HNO3 H2SO4 CH3 Cl CH3 Cl O2N NO2 3 CH CH3 2Cl2 C CH3 2 Cl 4 OCH3 CH3CO 2O AlCl3 OCH3 C CH3 O OCH3 C CH3 O 5 C CH3 3 CH2CH2CH3 KMNO4 H C CH3 3 COOH 6 CH2CH CH2 CH2CH3 KMNO4 H COOH COOH 7 CH3CH2CH2CH2Cl AlCl3 CH CH2CH3 CH3 8 CH2CH3 HNO3 H2SO4 CH2CH3 NO2 KMNO4 H COOH NO2 Br2 Fe COOH NO2 Br 4 1 OH CH3 Cl NO2 2 CH3 CH3 CH3 COOH CH3 COOH COOH COOH 5 1 KMnO4 H Br2 H2O a b c b a c CH3 CH3 a bc c a 2 Br2 Ag NH3 2 a b c b c a CH2CH3CH CH2C CH a bc CCl4 C b 6 1 2 3 4 5 OH Cl CH3 Cl CH3 COOH NHCOCH3 NO2 CH3 SO3H 6 7 8 9 OCH3 COOH OH CH3 COOH NO2 OH NO2 7 1 AlCl3 CH3Br CH3 KMNO4 H COOH HNO3 H2SO4 COOH NO2 2 AlCl3 CH3Br CH3 Cl2 Fe CH3 Cl Cl2 CH2Cl Cl 3 CH3CO 2O AlCl3 C CH3 O Br2 Fe C CH3 O Br 4 AlCl3 CH3Cl2 CH2Cl Fe CH2 CH3Cl 5 AlCl3 CH3 CH3Cl Br2 Fe CH3 Br KMnO4 H COOH Br HNO3 H2SO4 COOH Br NO2 6 AlCl3 CH3 CH3Cl AlCl3 CH3Cl CH3 CH3 HNO3 H2SO4 CH3 CH3 NO2 KMnO4 H COOH COOH NO2 8 有芳香性的是 2 4 5 8 9 CH3 CH2CH3 10 C CH CH3 A H2 Ni CH2CH3 CH3 B K2Cr2O7 H COOH COOH H2O C C O O O C D 第五章旋光异构作业参考答案第五章旋光异构作业参考答案 2 对 6 7 错 1 2 3 4 5 8 3 有旋光性的为 1 2 4 5 4 1 2 3 4 HBr CH2Br CH3 ClH BrH CH3 CH3 1 2 3 4 HBr BrH COOH COOH 1 2 3 4 H3CH C C2H5 C H H H3C 注 旋光异构体的数目略 5 1 R 氟氯溴甲烷 2 S 3 羟基 2 戊酮 3 2R 3S 2 3 4 三羟基丁醛 4 R 2 氨基 2 苯基乙酸 5 2R 3R 3 氯 2 丁醇 6 COOH H Br H Br COOH BrH BrH COOH COOH 1 2 3 4 2R 3S 2 3 2S 3R2 3 6 1 都是 S 所以是相同的 2 分别为 2R 3S 和 2S 3R 所以是对映体关系 3 分别为 2R 3S 和 2R 3R 所以是非对映体关系 4 一个为 R 另一个为 S 所以是对映 体关系 7 A CH3CH2 C CH CH2 OH CH3 B OH CH3 CH3CH2 C CH2 CH3 8 CH3 CH2 CH CH CH2 CH3 A H2SO4 H2O CH3 CH2 CH CH2 CH2 CH3 OH B KMnO4 OH CH3 CH2 CH CH CH2 CH3 OHOH C HOH HOH C2H5 C2H5 C 第六章第六章 卤代烃习题参考答案卤代烃习题参考答案 1 1 2 甲基 1 氯丙烷 伯卤代烷 2 2 甲基 2 溴丁烷 叔卤代烷 3 2 2 二甲基 4 溴戊烷 仲卤代烷 4 Z 2 甲基 1 溴 2 戊烯 烯丙基型 5 Z 顺 3 甲基 2 氯 2 戊烯 乙烯型 6 3 甲基 4 溴 1 丁烯 隔离型卤代烃 7 对 氯甲苯 乙烯型 8 1 苯基 1 溴丙烷 烯丙基型 2 1 2 3 4 CH3 CH CH CH3 CH3 BrBr CH3 C C CH2 CH3 Cl CH3Cl CH3 CH CH CH2 Cl CH CH CH2 Br 5 6 7 8 C C H3C Cl CH3 H C C Cl H H C C H Cl H CH3 Cl CH2Br 3 1 CH3 Cl CH2Cl ClCl CH3a bc d a b c d AgNO3 b a c d KMnO4 H d c 2 CH3 CH CH CH3 CH3Cl CH2 CHCl CH2 CH C CH3 Cl CH3 a b c a b c AgNO3 c a b 3 CH2 CH CH CH3 Cl CH2 CH CH CH3 I AgNO3 CH2 CH CH CH3 I CH2 CH CH CH3 Cl 4 1 CH2 CH CH2CH3 CH3Br CH3 CH CH CH3 CH3Br CH3 C CH2CH3 CH3 Br 2 CH2 CH2 CH2CH3 Br CH3 C CH3 CH3 Br CH3 CH2 CH CH3 Br 3 CH2 CH2 CH2CH3 Br CH2 CH2 CH2CH3 I CH2 CH2 CH2CH3 Cl 4 CH3 C CH2CH3 CH3 Br CH3 CH CH CH3 CH3Br CH2 CH CH2CH3 CH3Br 5 1 CH3 CH CH CH3 CH3Cl NaOH CH3 C CH CH3 CH3 Br2CH3 C CH CH3 CH3Br Br NaOH CH2 C CH CH2 CH3 2 ClCH2Cl NaCN ClCH2CN H2O H ClCH2COOH 3 CH2Br Mg CH2MgBr 1 CO2 2 H2O CH2COOH 4 CH CH3 Br NaOH CH CH2 HBr CH2 CH2 Br CH3ONa CH2 CH2 OCH3 5 CH3 Br NaOH CH3 KMnO4 H CH3 C CH2 CH2 CH2 C OH OO 6 1 CH2 CH2 Br2 Br CH2 CH2 Br NaCN NC CH2 CH2 CN H2O H HOOC CH2CH2 COOH 2 CH3 CH2 CH CH3 Br NaOH CH3 CH CH CH3 KMnO4 H CH3COOH 3 CH2 CH2 HCl CH3 CH2Cl Na CH3 CH2 CH2CH3 4 CH3 CH2CH2 Cl NaOH CH3 CH CH2 HCl CH3 CH CH3 Cl NH3 CH3 CH CH3 NH3 5 CH2 CH CH3 CH3Br NaOH CH2 C CH3 CH3 HBr CH3 C CH3 CH3 Br NaCN CH3 C CH3 CH3 CN H2O H CH3 C CH3 CH3 COOH 6 CH3 C CH2 CH3 HBr CH3 CH CH2Br CH3 NaCN CH3 CH CH2CN CH3 H2O H CH3 CH CH2COOH CH3 7 CH3 CH CH CH3 CH3Br NaOH CH3 C CH CH3 CH3 HBr A B CH3 C CH2 CH3 CH3 Br NaOH C CH3 C CH CH3 CH3 KMnO4 H CH3 C O CH3 CH3COOH 8 A CH3CHCH CH2 Br B CH3CH CHCH2Br Br Br C CH2 CH CH CH2 第七章第七章 醇醇 酚酚 醚习题参考答案醚习题参考答案 1 1 4 基 2 己醇 2 2 甲基 2 丙烯基 3 戊烯 1 醇 3 2 4 己二醇 4 3 环己烯 1 醇 5 4 苯基 2 戊醇 6 E 5 甲基 4 庚烯 3 醇 7 4 甲基苯酚 8 对甲氧基苯甲醇 9 苯乙醚 10 1 2 环氧丁烷 2 1 2 3 4 5 CH3 C OH CH3 CH3 H3CO CH2OH OH CH3H3C OH CH2OH 6 COOH OH 3 1 CH3 3C OH HBr CH3 3C Br H2O 2 OH HCl ZnCl2 Cl 3 CH3 CH O CH3 CH3 HI CH3 CH OH CH3 CH3I 4 CH3 CH CH2 CH CH3 CH3 OH K2Cr2O7 H CH3 CH CH2 C CH3 CH3 O 5 CH3CH2CH2CH2 OH SOCl2 CH3CH2CH2CH2 Cl 6 CH3 CH CH CH3 CH3OHH2SO4 170C O CH3 C CH CH3 CH3 KMnO4 H CH3 C O CH3 CH3COOH 7 OH C2H5 H2SO4 C2H5 1 O3 2 Zn H2O CH3CH2 C CH2CH2CH2CHO O 8 O CH 3CH2CH2CH2OH CH2 CH2 OH OCH2CH2CH2CH3 9 H3COH Br2 H3COH Br Br 10 OH NaOH ONa CH3Br OCH3 HI OH CH3I 4 1 1 4 丁二醇 正辛醇 3 己醇 2 甲基 2 戊醇 正己烷 2 碳酸 邻甲苯酚 水 苯甲醇 苯甲醚 2 4 二硝基苯酚 邻硝基苯酚 苯酚 邻甲苯酚 3 5 1 CH3CH2OCH2CH3CH2 CH2CH2CH3 Br CH2 CH2CH2CH3 OH CH2 CH2CH CH2 OH a b c d a b c d AgNO3 b a c d a c d Br2 d a Na 2 a b c d Ag NH3 2 d a b c K2Cr2O7 H a b c 3 CH2 CH CH2 OH OHOH OH OH Cu OH 2 CH2 CH CH2 OH OHOH OH OH FeCl3 OH OH 6 分子间的氢键 1 4 分子内的氢键 2 3 7 1 NaCN CH3CH2CH2CH2CN H3O CH3CH2CH2CH2COOH 2 CH3CH2 CH2 CH2OH H2SO4 170OC CH3CH2 CH CH2 H2SO4 H2O CH3CH2 CH CH3 OH Cu CH3CH2 C CH3 O 3 CH3CH2 CH2 CH2OH HBr CH3CH2 CH2 CH2Br CH3CH2 CH2 CH2OH H2SO4 170OC CH3CH2 CH CH2 H2SO4 H2O CH3CH2 CH CH3 OH H2SO4 170OC CH3CH CH CH3 Br2 CH3CH CH CH3 BrBr NaOH C2H5OH CH2 CH CH CH2 4 CH3CH2 CH2 CH2OH H2SO4 170OC CH3CH2 CH CH2 H2SO4 H2O CH3CH2 CH CH3 OH H2SO4 170OC CH3CH CH CH3 O3 H2O Zn CH3CHO 8 1 CH3 CH2 CH2OH H2SO4 170OC CH3 CH CH2 H2SO4 H2O CH3 CH CH3 OH K2Cr2O4 H CH3COCH3 2 OH Na ONa CH3CH2I OC2H5 3 CH3CH2 CH2 CH2OH H2SO4 170OC CH3CH2 CH CH2 HCl CH3CH2 CH CH3 Cl NaCN CH3CH2 CH CH3 CN 4 CH3 OH H2SO4 170OC CH3 KMnO4 H CH3 C CH2CH2CH2COOH O 9 OCH3 A HI OH CH3I BC OH NaOH ONa B CH3I C AgNO3 CH3ONO2 AgI 10 CH3CH2 CH2 CH2OH HCl CH3CH2 CH2 CH2Cl ZnCl2 A B CH3CH2 CH CH2 H2SO4 170OC NaOH C KMnO4 H CH3CH2COOH CO2H2O HCl ZnCl2 CH3CH2 CH CH3 Cl E 第八章第八章 醛 酮 醌习题参考答案醛 酮 醌习题参考答案 1 1 2 甲基丙醛 2 4 甲基 2 羟基苯甲醛 3 5 甲基 2 己烯醛 4 3 甲基 2 丁酮 5 2 4 己二酮 6 2 甲基 4 戊酮 1 醛 7 2 甲基 1 4 环己二酮 8 水合甲醛 2 1 2 3 CH3 CH2 CH CH2 CHO CH3 CH3 CH CH2 C CH3 CH3 O BrC CH3 O 4 5 6 CH N OH CH3 C CH3 N NH NNH C NH2 O 3 1 CH3 CH CH2CH3 OH Cu CH3 C CH2CH3 O HCN CH3 C CH2 CH3 OH CN H2O H CH3 C CH2 CH3 OH COOH 2 CH3 C CH2CH2CH3 O H2N NH O2N NO2 CH3 C NNH O2N NO2 H3CH2CH2C 3 CH3CH2CH2CHO CH3CH2MgBr CH3CH2CH2CH CH2CH3 OMgBr H2O H CH3CH2CH2CH CH2CH3 OH 4 CH3 3CCHO OH CH3 3CCOO CH3 3CCH2OH 5 CHO HCHO OH CH2OH HCOO 6 CH CH H2O HgSO4 H2SO4 CH3CHO I2 NaOH CI3CHO NaOH CHI3 HCOO 7 CH3 3C C CH3 O I2 NaOH CH3 3C C O O CHI3 8 CH3CHO HO CH2 CH2HO H CH3CH O O 9 2CH3CH2CHO OH CH3CH2CH CH CHO CH3 OH CH3CH2CH C CHO CH3 10 C CH3 CH3MgBr O 1 2 H2O H C CH3 OH CH3 4 1 c a d b 2 a b d c 5 1 CH2 CH2 H2O H2SO4 CH3CH2OH Cu CH3CHO OH CH3 CH CH CHO H2 Ni CH3 CH2CH2CH2OH 2 CH3C H O HCN OH CH3 CH CN OH H2O H CH 3 CH COOH OH 3 CH3CH CH2 HBr CH3 CH2 CH2Br H2O2 Mg CH3 CH2 CH2MgBr HCHO CH3 CH2 CH2 CH2 OMgBr H2O CH3CH2CH2CH2OH 4 CH3CHO OH CH3CHCH2CHO OH HO CH2 CH2HO HCl CH3CHCH2CH OH O CH2 CH2O KMnO4 H CH3CCH2CH O O CH2 CH2O H H2O CH3CCH2CHO O 5 CH3CHCH3 OH HBr CH3 CH CH3 Br Mg CH3 CH CH3 MgBr CH3CHCH3 OH Cu CH3CCH3 O CH3 CH CH3 MgBr H2OCH3 C CH CH3 H3C CH3 OH 6 CH3CH2 C X O AlCl3 C CH2CH2CH3 O H2N NH2 NaOH HOCH2CH2 2O CH2CH2CH2CH3 7 CH3CH2OH HBr CH3CH2Br Na CH3CH2CH2CH3 Cl2 CH3CH2CHCH3 Cl NaOH H2O CH3CH2CHCH3 OH 1 CH3CH2MgBr Cu CH3CH2CCH3 O 2 H2O CH3CH2C CH2CH3 CH3 OH 8 CH3CH CH2 HBr CH3 CH2 CH2Br H2O2 NaOH H2O CH3CH2CH2OH Cu CH3 CH2CHO OH CH3 CH2 CH C CHO CH3 LiAlH4 CH3 CH2 CH C CH2OH CH3 6 1 HCHOCH3CHO CH3 C CH3 O C CH2 CH3 O ab c d a b c d a b C d b a I2 NaOH H c d 2 CH3CH2CH2CH2CHOCH3C CH2CH2CH3 O CH3CH2 C CH2CH3 O CH3CHCH2CH2CH3 OH a b c d a b c d b I2 NaOH b d a c d a C 3 CHO C CH3 O CHOHO abc a b c FeCl3 c a b I2 NaOH b a 4 CH3 CH2CHO CH3C CH3 O C CH3 O a b c a b I2 NaOH b C a c b c NaHSO3 7 CH3 CH2 C CH CH3 CH3 O H2NOH CH3 CH2 C CH CH3 CH3 NOH H2 Ni CH3 CH2 CH CH CH3 CH3 OH H2SO4 CH3 CH2 CH C CH3 CH3 1 O3 2 Zn H2O CH3 CH2CHO O C CH3 CH3 Ag NH3 2 CH3 CH2COONH3 Ag I2 NaOH CH3COONa CHI3 8 CH3 C CH2 CH2 CH C CH3 CH3 O A KMnO4 H CH3 C CH2 CH2COOH O CH3 C CH3 O BC CH3 C CH2 CH2COOH O B I2 NaOH NaOOC CH2CH2 COONa CHI3 A CH3 C C CH2CH2CHO CH3 CH3 9 CH2 C CH3 OCH3 O LiAlH4 CH2 CH CH3 OCH3 OH AB HI CH2 C CH3 OH O CH3I C Zn Hg HCl CH2 CH2 CH3 OCH3 D CH2 C CH3 OCH3 O A H2NOH CH2 C CH3 OCH3 N OH A CH2 C CH3 OCH3 O A I2 NaOH CH2 C ONa OCH3 O CHI3 CH2 CH CH3 OCH3 OH B I2 NaOH CH2 C ONa OCH3 O CHI3 第九章 羧酸 羧酸衍生物及其衍生物作业参考答案 1 1 4 甲基 3 氯戊酸 2 E 2 羟基 3 戊烯酸 3 4 甲基 1 3 苯二甲酸 4 4 甲氧基苯乙酰氯 5 苯甲酸苯甲酯 6 乙基 丁内酰胺 7 2 甲基顺丁烯二酸酐 8 2R 3S 3 甲基 2 羟基丁二酸单甲酯 9 10 11 CH COOH CH COOH HO HO CH3 C CH2 C OC2H5 O O HOOC C CH2 COOH O 12 C C O O NH 2 1 H C COOH O a COOH COOH HCOOHCH3COOH b c d a b c d KMnO4 H a b c d Ag NH3 2 Ag a c b 2 4 a c 2 COOH COOH OH a bc CH CH COOH a b c FeCl3 c a b a b KMnO4 H 3 a bc CH3 C COOH O CH3 C CH3 O CH3CH2COOH a b c I2 NaOH c a b b a 4 O CH3 CH2 C CH2 CH3 O CH3 C CH2CH2CH3 O CH3 C CH2 C CH3 O O abc d a b c d I2 NaOH c d a b FeCl3 d c NaHSO3 a B 3 1 丁烯二酸 丁二酸 丁酸 2 2 氟丙酸 2 羟基丙酸 丙酸 2 甲基丙酸 3 乙二酸 氯乙酸 苯甲酸 乙酸 丙酸 4 1 2 CH CHCH2OH CH2CH2OH CH2CH2COOH CH2CH2OH 3 C OMgBr O H2SO4 H2O C OH O CH3OHCO2 C OCH3 O 注 注 4 以下答案在下页 以下答案在下页 第十章第十章 含氮和含磷化合物作业参考答案含氮和含磷化合物作业参考答案 1 1 1 硝基丙烷 2 对硝基甲苯 3 乙异丙基胺 4 N 甲基苯胺 5 1 4 丁二胺 6 溴化对甲基重氮苯 7 2 4 二硝基苯肼 8 丁二酰亚胺 9 7 氯 1 萘胺 10 N 亚硝基二乙胺 2 1 2 3 CH3 CH CH CH2CH3 CH3NO2 CH3CH2CH2CH2 3N ONNH2 4 5 6 CH2 CH2 NH2NH2 N CH CH3 2 CH3 H3C C2H5 OH N CH3 CH3 HOH2CH2C CH3 OH 7 8 9 N CH3 CH3 H3C C O CH2CH2 CH3 OH O NH2 O2NNH CH2CH3 10 CH2NH2 3 1 5 4 1 2 3 2 4 1 5 3 2 4 1 CH3CH2NH3Cl 2 N CH CH3 2 C2H5 C2H5 C2H5 Br AgOH N