一些污染物沉降参数参考值.docx

一些污染物沉降参数参考值来源:ANL/ER/TR-01/003，DOE/xx-nnnn。Deposition Parameterizations for the Industrial Source Complex (ISC3) Model，by M. L. Wesely, P. V. Doskey, and J. D. Shannon Environmental Research Division,Argonne National Laboratory9700 South Cass AvenueArgonne, Illinois 60439June 2002附录B:粒径分布资料这里列出为粒径分布不是很清楚且粒径在10um及以上的粒子质量占比较小（小于10%）的情况。这时在AERMOD中只需输入细粒子（2.5um以下）的质量百分比和全部粒子的质量中位径。为便于使用，这里只列出推荐值，不再列出各次试验具体值及来源（详细参见原版资料）。 粒子成份2.5m以下质量百分比 (%)中位径(m)备注锑，复合物601.0砷，复合物750.5石棉850.3铍，复合物(a) 80 (b) 0(a) 0.4 (b) 7.0(a)对应于燃烧 (b)对应于采矿镉，复合物700.6CCaN207.0氯复合物601.0铬复合物551.2钴复合物750.5焦炭炉排放物800.4氰化物（CN-）, 盐(不考虑HCN) 07.0铅复合物750.5锰复合物451.8汞复合物 (不含气态汞) 800.4精细矿物纤维1000.1镍复合物601.0磷(假定为磷酯盐)402.2多环有机物 (POM)800.4多环有机复合物，如: PCCD/Fs 900.1多环有机复合物，如: PAHs 930.1放射性物质（含氡）800.4硒复合物800.4 附录C:单个气态污染物和混合物的基本物化参数 在下表中查找污染物在空气中扩散率Da和水中扩散率Dw。如果找不到污染物，可参考分子结构相仿和分子量相近的物质。在下面的表中（NA）表示该项无数据。表 C.1. 单个气态污染物的基本物化参数， 298.2 K时. 序 化学名称 CAS No. 分子式 分子量 (g mol-1) 熔点 (C) 沸点 (C) 摩尔体积Le Bas 摩尔体积 (cm3 mol-1)空气扩散率 Da (cm2 s-1)水中扩散率 Dw x 105 (cm2 s-1)1Acetaldehyde75-07-0C2H4O44.05-123.020.147.251.80.12811.4502Acetamide60-35-5C2H5NO59.0781.0222.054.055.50.11531.4023Acetonitrile75-05-8C2H3N41.05-43.881.643.356.30.13421.3934Acetophenone98-86-2C8H8O120.1520.0202.0133.5140.40.072410.805452-Acetylamino- fluorene53-96-3C15H13NO223.28193.0NAa224.3248.00.054730.48076Acrolein107-02-8C3H4O56.06-87.752.663.166.60.10941.2797Acrylamide79-06-1C3H5NO71.0884.5192.669.980.80.10121.1518Acrylic acid79-10-7C3H4O272.0612.3141.069.283.20.10141.1329Acrylonitrile107-13-1C3H3N53.06-83.577.359.271.10.11331.23510Allyl chloride107-05-1C3H5Cl76.53-134.545.180.387.50.094631.099114-Aminobiphenyl92-67-1C12H11N169.2353.5302.0184.2198.80.060970.603212Aniline62-53-3C6H7N93.13-6.0184.197.8110.20.085040.953313o-Anisidine90-04-0C7H9NO123.166.2224.0124.4143.40.074490.792814Benzene71-43-2C6H678.115.580.091.096.00.089621.04015Benzidine92-87-5C12H12N2184.24120401.0191.0213.00.059620.564416Benzotrichloride98-07-7C7H5Cl3195.48-5.0221.0167.6180.90.062990.656817Benzyl chloride100-44-7C7H7Cl126.59-45.0179.0130.2124.30.072840.879118Biphenyl92-52-4C12H10154.2169.0256.1177.3199.60.062470.600919Bis(chloromethyl) ether542-88-1C2H4Cl2O114.96-41.5106.089.2102.70.086360.997420Bis(2-ethylhexyl) phthalate117-81-7C24H38O4390.57-55.0384.0475.5524.80.037240.100221Bromoform75-25-2CHBr3252.758.0149.183.999.50.083571.017221,3-Butadiene106-99-0C4H654.09-108.9-4.477.581.40.10131.14623Caprolactan105-60-2C6H11NO113.16NANA113.2133.90.078230.833624Captan133-06-2C9H8Cl3NO2S300.59172.5NA227.6262.50.053550.450125Carbaryl63-25-2C12H11NO2201.22145.0NA196.4220.80.058530.544526Carbon disulfide75-15-0CS276.14-111.546.061.766.00.10531.28527Carbon tetrachloride56-23-5CCl4153.82-23.076.899.9113.20.080240.936628Carbonyl sulfide463-58-1COS60.07-138.8-50.044.948.70.12341.49329Catechol120-80-9C6H6O2110.11105.0245.0103.2110.80.081590.949930Chloramben133-90-4C7H5Cl2NO2206.03200.0NA163.3180.30.063510.658731cis-Chlordane5103-71-9C10H6Cl8409.78108NA286.0332.50.047560.325632trans-Chlordane5103-74-2C10H6Cl8409.78104NA286.0332.50.047560.325633Chloroacetic acid79-11-8C2H3O2Cl94.5063.0189.372.089.30.096311.086342-Chloroacetophenone532-27-4C8H7OCl154.6056.5247.0152.2161.30.066860.723335Chlorobenzene108-90-7C6H5Cl112.56-45.2131.7109.7116.90.079330.916736Chlorobenzilate510-15-6C16H14Cl2O3325.1937.0157.0 (0.07 mm Hg)310.5337.20.046130.318437Chloroform67-66-3CHCl3119.38-63.661.181.292.30.089441.06538Chloromethyl methyl ether107-30-2C2H5OCl80.51-103.559.570.581.80.099101.14339Chloroprene126-99-8C4H5Cl88.54-130.059.496.2102.30.086150.999640o-Cresol95-48-7C7H8O108.1429.8191.0117.6125.60.077320.872741m-Cresol108-39-4C7H8O108.1411.8202.2117.6125.60.077320.872742p-Cresol106-44-5C7H8O108.1435.5201.9117.6125.60.077320.872743o-Cresyl acetate533-18-6C9H10O2150.18NA208.0160.1177.20.065520.668544Cumene98-82-8C9H12120.20-96.0152.4152.5162.60.068300.718645Diazomethane334-88-3CH2N242.04-145.0-23.029.653.40.15351.42946Dibenzofuran132-64-9C12H8O168.286.5287.0160.5176.70.064890.6702471,2-Dibromo-3-chloropropane96-12-8C3H5ClBr2236.34NA196.0124.1141.50.071100.8005482,4-Dichloro-phenoxyacetic acid94-75-7C8H6O3Cl2221.04140.5160.0 (0.4 mm Hg)183.1209.80.060080.5727491,1-Dichloro-2,2-bis(p-chlorophenyl)ethylene72-55-9C14H8Cl4318.0389.0NA288.5305.20.047820.370150Dibutyl phthalate84-74-2C16H22O4278.35-35.0340.0311.4347.20.046390.3034511,4-Dichlorobenzene106-46-7C6H4Cl2147.0052.7174.0128.3137.80.072360.8164523,3-Dichlorobenzidine84-68-4C12H10N2Cl2253.13165.0NA228.4265.00.053900.444853Dichloroethyl ether111-44-4C4H8Cl2O143.01-51.9178.5130.2147.90.072060.774254trans-1,3-Dichloropropene10061-02-6C3H4Cl2110.97NA112.098.9108.40.083010.963355Dichlorvos62-73-7C4H7Cl2O4P220.98NA140.0 (20 mm Hg)169.1193.10.062270.619456Diethanolamine111-42-2C4H11NO2105.1428.0268.8105.8126.70.081140.867257Diethyl sulfate64-67-5C4H10SO4154.19-24.0208.0134.0155.00.070730.746558Diethylene glycol monobutyl ether112-34-5C8H18O3162.23-68.0231.0187.1213.30.060730.5635593,3-Dimethoxybenzidine119-90-4C14H16N2O2244.30137.0NA244.3279.40.052340.4166604-Dimethylamino- azobenzene60-11-7C14H15N3225.30117.0NA234.3275.90.053250.423361N,N-Dimethylaniline121-69-7C8H11N121.182.4194.1138.9156.10.071110.7423623,3-Dimethylbenzidine119-93-7C14H16N2212.30131.5NA232.0257.40.054040.460563Dimethylcarbamyl chloride79-44-7C3H6NOCl107.54-33.0167.093.2110.60.085380.950864N,N-Dimethylformamide68-12-2C3H7NO73.10-60.4153.074.589.70.098201.083651,1-Dimethylhydrazine57-14-7C2H8N260.10-58.063.959.490.40.11081.07866Dimethyl phthalate131-11-3C10H10O4194.195.5283.7188.2206.40.059810.581967Dimethyl sulfate77-78-1C2H6SO4126.13-27.076.0 (15 mm Hg)93.0110.60.084110.9508684,6-Dinitro-o-cresol534-52-1C7H6N2O5198.1486.5NA146.5172.40.066810.6844692,4-Dinitrophenol51-28-5C6H4N2O5184.11115.5sublimes126.0150.20.071710.7650702,4-Dinitrotoluene121-14-2C7H6N2O4182.1471.0300.0 decomposes140.4165.00.068450.7098711,4-Dioxane123-91-1C4H8O288.1111.8101.576.093.60.095021.056721,2-Diphenylhydrazine122-66-7C12H12N2184.24131.0NA191.0216.00.059620.556573Epichlorohydrin13403-37-7C3H5ClO92.53-26.0117.068.188.90.098741.089741,2-Epoxybutane106-88-7C4H8O72.11-150.063.369.990.20.10101.08075Ethyl acrylate140-88-5C5H8O2100.12-71.299.4110.2123.40.080170.8833 76Ethylbenzene100-41-4C8H10106.17-94.9136.1132.0140.40.073690.805277Ethyl carbamate51-79-6C3H7NO289.0949.0185.080.6100.60.092641.01078Ethyl chloride75-00-3C2H5Cl64.52-138.712.364.472.70.10611.22079Ethylene dibromide106-93-4C2H4Br2187.879.9131.684.898.40.084671.02480Ethylene dichloride107-06-2C2H4Cl298.96-35.583.583.093.60.090401.05681Ethylene glycol107-21-1C2H6O262.07-13.0197.357.966.60.11131.27982Ethylene glycol monobutyl ether111-76-2C6H14O2118.18-74.8168.4140.0159.00.071040.731583Ethyleneimine151-56-4C2H5N43.07-77.956.0 47.963.70.12791.30984Ethylene oxide75-21-8C2H4O44.05-111.710.628.945.80.15341.53585Ethylene thiourea96-45-7C3H6N2S102.16131.0NA93.5118.30.085740.909286Ethylidene dichloride75-34-3C2H4Cl298.96-96.957.483.093.60.090401.05687Formaldehyde50-00-0CH2O30.03-92.0-19.126.629.60.17201.84588Heptachlor76-44-8C8H5Cl7373.3095.5NA230.9274.60.052740.425889Hexachlorobenzene118-74-1C6Cl6284.78231.8325.0203.1221.40.056570.542890Hexachlorobutadiene87-68-3C4Cl6260.76-21.0215.0189.6206.80.058610.580891()1,2,3,4,5,6-Hexachlorocyclohexane60291-32-9C6H6Cl6290.83159.5288.0217.0243.60.054820.490392()1,2,3,4,5,6-Hexachlorocyclohexane 58-89-9C6H6Cl6290.83112.5323.4217.0243.60.054820.490393Hexachloro- cyclopentadiene77-47-4C5Cl6272.77-9239.0187.2210.10.058820.571994Hexachloroethane67-72-1C2Cl6236.74187.0 (tripl. pt.)NA157.8177.20.063970.668595Hexamethylene diisocyanate822-06-0C8H12N2O2168.20NA255.0176.2208.80.062230.575496Hexamethyl- phosphoramide680-31-9C6H18N3OP179.207.0232.5179.6225.30.061420.533297Hexane110-54-3C6H1486.18-95.368.7127.7140.60.076600.804398Hydrazine302-01-2N2H432.051.0113.618.335.80.19221.70999Hydroquinone123-31-9C6H6O2110.11172.3287.0103.2110.80.081590.9497100Isophorone78-59-1C9H14O138.21-8.1215.2163.3177.40.065410.6679 101Maleic anhydride108-31-6C4H2O398.0652.820268.379.80.097961.159102Methanol67-56-1CH4O32.04-97.664.631.337.00.15981.686103Methoxychlor72-43-5C16H15O2Cl3345.6687.0 327.7358.10.044850.2877104Methyl bromide74-83-9CH3Br94.94-93.73.544.752.90.11531.435105Methyl chloride74-87-3CH3Cl50.49-97.7-24.043.850.50.12841.467106Methyl chloroform71-55-6C2H3Cl3133.41-30.474.0101.7114.50.080590.9293107Methyl ethyl ketone78-93-3C4H8O72.11-86.779.688.296.20.091801.039108Methylhydrazine60-34-4CH6N246.07-52.487.538.859.50.13671.355109Methyl iodide74-88-4CH3I141.94-66.442.552.662.90.10471.317110Methyl isobutyl ketone108-10-1C6H12O100.16-84.0116.5129.2140.60.074860.8043111Methyl isocyanate624-83-9C2H3NO57.05-45.039.549.463.70.12001.309112Methyl methacrylate80-62-6C5H8O2100.12-48.0100.5110.2121.80.080170.8913113Methyl tert-butyl ether1634-04-4C5H12O88.15-108.655.2113.3129.40.080430.85441144,4-Methylenebis (2-chloroaniline)101-14-4C13H12N2Cl2267.16NANA248.9277.00.051660.4212115Methylene chloride75-09-2CH2Cl284.93-95.140.062.571.40.10331.2321164,4-Methylenediphenyl diisocyanate101-68-8C15H10N2O2250.26NANA246.3275.00.052080.42501174,4-Methylenedianiline101-77-9C13H14N2198.2792.5398211.5235.20.056640.5095118Naphthalene91-20-3C10H8128.1880.2217.9140.9147.60.070290.7754119Nitrobenzene98-95-3C6H5NO2123.115.7210.8105.4124.50.079970.87781204-Nitrobiphenyl92-93-3C12H9NO2199.21114340.0191.8208.00.059200.57761214-Nitrophenol100-02-7C6H5NO3139.11113.8279.0111.5126.80.077220.86971222-Nitropropane79-46-9C3H7NO289.09-91.3120.280.697.40.092641.031123N-Nitroso-N-methylurea684-93-5C2H5N3O2103.08123.5 decomposesNA69.2101.90.096911.002124N-Nitrosodimethylamine62-75-9C2H6N2O74.08NA154.060.987.70.10631.098125N-Nitrosomorpholine59-89-2C4H8N2O2116.1229.0225.085.1135.70.087970.8256 126Parathion56-38-2C10H14NO5PS291.266.1375.0253.9288.00.050970.4005127Pentachloro- nitrobenzene82-68-8C6Cl5NO2295.34144.0328.0 decomposes198.9223.90.057020.5366128Pentachlorophenol87-86-5C6Cl5OH266.34174.0310.0 decomposes190.5204.20.058430.5879129Phenol108-95-2C6H5OH94.1140.9181.897.199.70.078441.016130p-Phenylenediamine106-50-3C6H8N2108.14146.0267.0104.7124.40.075980.8783131Phosgene75-44-5COCl298.92-127.98.064.071.40.10041.232132Phosphine7803-51-2H3P34.00-133.0-87.829.836.70.16041.716133Phthalic anhydride85-44-9C8H4O3148.12130.8295.0118.2132.50.074920.84001341,3-Propane sultone1120-71-4C3H6SO3122.1432.0180.0 (30 mm Hg)84.5105.60.087790.9797135 -Propiolactone57-57-8C3H4O272.06-33.4162.050.969.10.11441.254136Propionaldehyde123-38-6C3H6O58.08-80.048.067.774.00.10571.209137Propoxur114-26-1C11H15NO3209.2587.0decomposes214.1248.30.056130.48001381,2-Dichloropropane26198-63-0C3H6Cl2112.99-100.496.4103.6115.80.081240.9223139Propylene oxide75-56-9C3H6O58.08-111.935.049.470.50.11971.2411401,2-Propylenimine75-55-8C3H7N57.10NA67.050.176.30.11941.188141Quinoline91-22-5C9H7N129.16-14.8237.1127.2144.70.073450.7872142Quinone106-51-4C6H4O2108.10115.7sublimes98.6103.40.083340.9929143Styrene100-42-5C8H8104.15-31.0145.0127.4133.00.075000.8377144Styrene oxide96-09-3C8H8O120.15-35.6194.1115.2138.00.077180.81551452,3,7,8-Tetrachlorodibenzo-p-dioxin1746-01-6C12H4O2Cl4321.98305.0446.5241.4267.80.051960.43921461,1,2,2-Tetrachloroethane79-34-5C2H2Cl4167.85-43.8146.5120.4135.40.073610.8270147Tetrachloroethylene127-18-4C2Cl4165.83-22.3121.3115.8128.00.074920.8610148Toluene108-88-3C7H892.14-94.9110.6111.5118.00.080540.9097149Toluene-2,4-diamine95-80-7C7H10N2122.1799.0292.0125.2146.60.076630.77801502,4-Toluene diisocyanate584-84-9C9H6N2O2174.1620.5251160.0186.40.064810.6395151o-Toluidine95-53-4C7H9N107.16-16.3200.3118.3132.40.077200.8405152Toxaphene8001-35-2C10H10Cl8413.8065-90NA313.5358.80.045520.28671531,2,4-Trichlorobenzene120-82-1C6H3Cl3181.4517.0213.5147.0158.70.067100.73261541,1,2-Trichloroethane79-00-5C2H3Cl3133.41-36.6113.8101.7114.50.080590.9293155Trichloroethylene79-01-6C2HCl3131.39-84.787.297.1107.10.082290.97091562,4,5-Trichlorophenol95-95-4C6H3Cl3O197.4569.0247.0153.1166.10.065540.70601572,4,6-Trichlorophenol88-06-2C6H3Cl3O197.4569.0246.0153.1166.10.065540.7060158Triethylamine121-44-8C6H15N101.19-114.789.0134.6156.30.073460.7415159Trifluralin1582-09-8C13H16F3N3O4335.2849.0140.0 (4.2 mm Hg)307.5339.10.046290.31551602,2,4-Trimethylpentane540-84-1C8H18114.23-107.399.2168.8185.00.065610.6438161Vinyl acetate108-05-4C4H6O286.09-93.272.589.7101.20.089021.006162Vinyl bromide593-60-2C2H3Br106.96-137.815.860.667.70.10181.268163Vinyl chloride75-01-4C2H3Cl62.50-153.7-13.359.765.30.10991.292164Vinylidene chloride75-35-4C2H2Cl296.94-122.531.678.486.20.092761.109165o-Xylene95-47-6C8H10106.17-25.2144.5132.0140.40.073690.8052166m-Xylene108-38-3C8H10106.17-47.8139.1132.0140.40.073690.8052167p-Xylene106-42-3C8H10106.1713.2138.3132.0140.40.073690.8052表 C.2. 单苯基聚氯乙烯（PCB）属物质的基本物化参数， 298.2 K时. 序 化学名称 CAS No. 分子式 分子量 (g mol-1) 熔点 (C) 沸点 (C) 摩尔体积Le Bas 摩尔体积 (cm3 mol-1)空气扩散率 Da (cm2 s-1)水中扩散率 Dw x 105 (cm2 s-1)12-Monochloro2051-60-7C12H9Cl188.6634.0274196.0205.50.058830.584323-Monochloro2051-61-8C12H9Cl188.6625.1284196.0205.50.058830.584334-Monochloro2051-62-9C12H9Cl188.6677.9291196.0205.50.058830.584342,2-Dichloro13029-08-8C12H8Cl2223.1061.0NAa214.7226.40.055850.530552,3-Dichloro16605-91-7C12H8Cl2223.10NANA214.7226.40.055850.530562,3-Dichloro25569-80-6C12H8Cl2223.10NANA214.7226.40.055850.530572,4-Dichloro33284-50-3C12H8Cl2223.1024.4NA214.7226.40.055850.530582,4-Dichloro34883-43-7C12H8Cl2223.1043.0NA214.7226.40.055850.530592,5-Dichloro34883-39-1C12H8Cl2223.1025.1NA214.7226.40.055850.5305102,6-Dichloro33146-45-1C12H8Cl2223.1034.9NA214.7226.40.055850.5305113,3-Dichloro2050-67-1C12H8Cl2223.1029.0322214.7226.40.055850.5305123,4-Dichloro2974-92-7C12H8Cl2223.1049.0NA214.7226.40.055850.5305133,4-Dichloro2974-90-5C12H8Cl2223.10NANA214.72