HSETrainingChemicalOperation危险化学品作业培训

HSETrainingChemicalOperationHSE2|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyContentsofthetraining

培训内容MSDS物质平安数据表FireandExplosivePrevention火灾和爆炸的预防ChemicalExposureandPrevention化学品接触和预防PhysicalHazardandPrevention物理危害和预防3|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyHazardsintheworkplace

工作场所的危害4|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyHazardsinWorkPlace

工作场所的危害TypeofHazard危险类型Classificationandcodeforthehazardousandharmfulfactorsinproductionprocess?生产过程危险和有害因素分类代码?〔GB/T13861-1992〕Chemicalhazard化学危险Physicalhazard物理危险Biologicalhazard生物危险Psychologic&physiologicalhazard心理、生理性Behaviourhazard行为性危险Others其他5|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyGBCodesofChemicManagement

化学品管理的相关标准常用危险化学品的分类及标志(GB13690-92)危险货物分类和品名编号(GB6944—86)危险货物品名表〔GB12268-90〕剧毒物品分级、分类与品名编号(GA57-93)剧毒物品品名表〔GB58-93〕危险货物包装标志〔GB190-90〕包装储运图示标志〔GB6944-86〕化学品平安技术说明书编写规定(GB16483-2000)化学品平安标签编写规定(GB15258-1999)作业场所化学品平安标签编写规定(GB报批稿)工作场所职业有害因素接触限值〔GBZ2-2002〕常用化学危险品贮存通那么〔GB15603-1995〕6|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyChemicalinthesite

化学品的来源CommercialSubstances商业物质ExistingPharmaSubstances制药部存在的物质SubstancesprocuredfromSuppliers供给商提供的物质Rawmaterials原料Auxiliarymaterials辅料Intermediates中间体Existingdrugsubstancesandintermediates已存的药物和中间体Drugsubstancesandintermediatesindevelopment开发中的药物和中间体7|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyMaterialhazardcommunication-MSDS

物质危害信息-MSDSMaterialSafetyDataSheet——化学品平安说明书,化学品平安信息卡，或者物质平安数据表，简称MSDSTheMaterialSafetyDataSheet(MSDS)isadetailedinformationbulletinpreparedbythemanufacturerorimporterofachemicalthatdescribesthematerialinformation.MSDS是由生产商和化学品进口商提供的描述物质信息的数据表。InformationonanMSDSaidsintheselectionofsafeproductsandhelpsprepareemployersandemployeestorespondeffectivelytodailyexposuresituationsaswellastoemergencysituations.MSDS信息有助于选择平安的产品和帮助雇主和员工有效应对化学品的接触以及应急响应。?化学品平安技术说明书〔CSDS〕编写规定范围?(GB16483-2000)8|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyMSDSstructure

MSDS结构1化学品及企业标识〔chemicalproductandcompanyidentification〕

主要标明化学品名称、生产企业名称、地址、、、应急、和电子邮件地址等信息。2成分/组成信息〔composition/informationoningredients)

标明该化学品是纯化学品还是混合物。纯化学品，应给出其化学品名称或商品名和通用名。混合物，应给出危害性组分的浓度或浓度范围。无论是纯化学品还是混合物，如果其中包含有害性组分，那么应给出化学文摘索引登记号〔CAS号〕。3危险性概述〔hazardssummarizing)

简要概述本化学品最重要的危害和效应，主要包括：危害类别、侵入途径、健康危害、环境危害、燃爆危险等信息。4急救措施〔first-aidmeasures)

指作业人员意外的受到伤害时，所需采取的现场自救或互救的简要处理方法，包括：眼睛接触、皮肤接触、吸入、食入的急救措施。9|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyMSDSstructure

MSDS结构5消防措施〔fire-fightingmeasures)

主要表示化学品的物理和化学特殊危险性，适合灭火介质，不适宜的灭火介质以及消防人员个体防护等方面的信息，包括：

危险特性、灭火介质和方法，灭火本卷须知等。6泄露应急处理〔accidentalreleasemeasures)

指化学品泄露后现场可采用的简单有效的应急措施、本卷须知和消除方法，包括：应急行动、应急人员防护、环保措施、消除方法等内容。7操作处置与储存〔handlingandstorage)

主要是指化学品操作处置和平安储存方面的信息资料，包括：操作处置作业中的平安本卷须知、平安储存条件和本卷须知。8接触控制/个体防护〔exposurecontrols/personalprotection)

在生产、操作处置、搬运和使用化学品的作业过程中，为保护作业人员免受化学品危害而采取的防护方法和手段。包括：

最高容许浓度、工程控制、呼吸系统防护、眼睛防护、身体防护、手防护、其他防护要求。10|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyMSDSstructure

MSDS结构9理化特性〔physicalandchemicalproperties〕

主要描述化学品的外观及理化性质等方面的信息，包括：

外观与性状、ph值、沸点、熔点、相对密度〔水=1〕、相对蒸气密度〔空气=1〕、饱和蒸气压、燃烧热、临界温度、临界压力、辛醇/水分配系数、闪点、引燃温度、爆炸极限、溶解性、主要用途和其他一些特殊理化性质。10稳定性和反响性〔stabilityandreactivity)

主要表达化学品的稳定性和反响活性方面的信息，包括：稳定性、禁配物、应防止接触的条件、聚合危害、分解产物。11毒理学资料〔toxicologicalinformation〕

提供化学品的毒理学信息，包括：不同接触方式的急性毒性〔LC50、LD50〕、刺激性、致敏性、亚急性和慢性毒性，致突变性、致畸性、致癌性等。12生态学资料〔ecologicalinformation〕

主要陈述化学品的环境生态效应、行为和转归，包括：生物效应〔如LD50、LD50〕、生物降解性、生物富集、环境迁移及其他有害的环境影响等。

11|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyMSDSstructure

MSDS结构13废弃处置〔disposal〕

是指对被化学品污染的包装和无使用价值的化学品的平安处理方法，包括废弃处置方法和本卷须知。14运输信息〔transportinformation)

主要是指国内、国际化学品包装、运输的要求及运输规定的分类和编号，包括：危险货物编号、包装类别、包装标志、包装方法、UN编号及运输本卷须知等。15法规信息〔regulatoryinformation〕

主要是化学品管理方面的法律条款和标准。16其他信息〔otherinformation〕

主要提供其他对平安有重要意义的信息，包括：参考文献、填表时间、填表部门、数据审核单位等。12|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyExample

例如KSO

13|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyFireandExplosivePrevention火灾和爆炸的预防14|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyFormationofexplosiveatmosphere

爆炸气氛的形成Ignitionsource15|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyPreventionoftheformationofExplosiveAtmosphere

防止爆炸气体形成Substitutionofflammableorcombustiblesubstances替代易燃或可燃物质ClosedHandling密闭操作Ventilation通风Evacuation减压操作Inerting惰化16|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyClassificationofExArea

防爆区域划分17|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyClassificationofExArea

防爆区域划分18|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyClassificationofExArea

防爆区域划分19|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyIgnitionSources

点火源OpenFlames火焰ElectricalEquipment电气设备MechanicalSparks机械火花HotSurfaces高温外表StaticElectricity静电ChemicalReactions化学反响20|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyStaticelectricity

静电Threeconditionsmustbemetbeforeanexplosioncausedbystaticelectricitycantakeplace:1.Anexplosivemixturemustbepresent.2.Anelectricfieldmusthavebeenproducedduetotheelectrostaticchargethathadbeengeneratedandaccumulatedinaliquidorsolid.3.Anelectricfieldmustbelargeenoughtocauseasparkofsufficientenergytoignitethemixture.21|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyCharacterizationofdifferenttypesofstaticdischarges

SubtitleSparkDischarge:BrushDischarge:PointDischargeLightning–likeDischarge22|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyExamplesofelectrostaticinduction:

Subtitleanon–conductivesolventflowingoutofametalpipe.Theliquidischargedbyaseparationeffectandexcesschargesleaktotheground.23|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyExamplesofelectrostaticinduction:

Subtitlepowderpouringoutofaplasticbag.Thepowderandbagarechargedbyaseparationeffectandthechargesdissipateslowly.24|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyExamplesofelectrostaticinduction:

Subtitlethetransferofnon-conduc­tiveliquidorpowderinglassorplasticpipe.Thereisaseparationeffectinthewallzone,andthepipe,flangesandcon­tentsarecharged.Chargeleakageisslow.Ifplasticflangesareused,theflangesdonothavetobegrounded.Metalflangesonlines>2in.(5cm)shouldbegrounded.25|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyExamplesofelectrostaticinduction:

Subtitleliquidbeingatomizedthroughametalnozzle.Thereisasepa­rationeffectwhenthedropletsareformed.Theliquiddropletsandnozzlearecharged,andtheexcesschargeonthemetalnozzleisdissipatedbytheground­ingconductor.26|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyTheFivePrinciplesforProtectionAgainstStaticHazards

Subtitle1.Groundallconductorsa.Equipmentb.Interconnectbuildingstructureswithconductorsc.Groundisolatedmetalparts,e.g.,flanges,metalsheetingd.Placemetaldrumsonconductivefloorsorground2.Groundpersonnela.Installconductivefloorcoveringsb.Wearconductivefootwear27|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyTheFivePrinciplesforProtectionAgainstStaticHazards

Subtitle3.Preventandreducechargingbyusingconductivematerialsa.Ifpossible,useaqueousorpolarsolventsb.Avoidhighlyinsulatingplasticcon­tainersc.Useconductivedrivebeltsd.Useconductivepipese.Useconductivefiltermaterialsfordustsifflammablevaporislikely4.Keepvelocitieslowa.Limitvelocityofliquidsandgasescontainingdustandliquidparticlesb.Avoidturbulenceinchargeableliquids28|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyTheFivePrinciplesforProtectionAgainstStaticHazards

Subtitle5.Avoidexplosiblemixturesandaerosolsa.Removegases,vaporsanddustsbysuctionatthesourceb.Workwithflammableliquidsatleast5°C(9°F)belowtheirflashpointc.Considerchargingflammableliquidstovesselsbysuctionanddischargingbyblowingoutwithnitrogen.29|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyMitigationofexplosioneffects

降低爆炸效果Explosionpressureresistantconstruction防爆建筑Explosionreliefventing泄爆放空ExplosionSuppression抑爆装置ExplosionIsolation爆炸隔离SafetyCompartments平安分区HazardZones危险区域30|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlySafetyManagement

平安管理TrainingandInstruction培训和指导MarkingEx-Zones防爆区域标示PreventiveMaintenance预防性维修WorkPermitSystem平安作业许可证制度SurveillanceandAudits巡回及审查ManagementofChange变更管理EmergencyManagement应急管理31|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyChemicalExposureandPrevention

化学品的接触和预防32|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnly32WhatareRoutesofChemicalExposure?

化学泄露的危害流程如何？Thewaysinwhichachemicalmayenterthebody.其流程正是化学物质进入人体的过程ChemicalHealthHazards化学危害33|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyRoutesofToxicEntry

有毒品进入人体路线Inhalation吸入Ingestion吞摄Absorption吸收Absorption吸收Absorption吸收Absorption吸收Absorption吸收Injection渗入血管34|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyChemicalHealthHazards

化学危害Toxicologytermsforhazards:毒物性危害：Toxin毒素Mutagen诱导有机体突变的物质Teratogen致畸剂Carcinogen致癌物质Sensitizer感光剂Allergen过敏原Endocrinedisrupter致内分泌紊乱物35|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyChemicalHealthHazards

化学危害ToxicologyTerms毒性条件Exposure接触Acute急性的Chronic慢性的Dose吸入剂量LD50半数致死量是药物、毒物及病原微生物等毒力水平的一个标志。它表示能使全部实验对象死亡半数的剂量或浓度,有弪皮、弪口或1小时等几种类型〕LC50半致死浓度动物实验中施用之化学物质能使百分之五十实验动物族群发生死亡时所需要之浓度〕Systemic全身组织Targetorgan被伤害的组织36|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyChemicalHealthHazards

化学危害Airborneconcentrationsofchemicalscanoftenbecomparedtostandardsestablishedbynational,international,orgovernmentalorganizations.空气中的化学浓度会被要求严格遵守该国家、国际或政府组织的相关标准Moststandardsarebaseduponexposuresintheworkenvironmentratherthanactualdosesreceivedbytheworkerbecauseofdifficultiesindeterminingdoses.很多标准以在工作环境中对化学品的接触程度而设定，而不是建立在工作人员所接收到的剂量的根底上，毕竟决定剂量比较困难。37|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnly37ChemicalHealthHazards

化学危害Manyoccupationalsafetyandhealthexposurelevelsareregulatory(laws).许多职业平安及化学接触程度均是受到一定制度约束的〔法律〕Theyareintendedforlifetimeexposuresfornormallyhealthy,adultworkers.某些接触对于成年工作者来说终其一生也只会维持在一定水平Theyarenotclearboundariesbetween“safe〞and“notsafe〞.对于“平安〞比例的概念并不是绝对的38|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyChemicalExposureStandard(GB)

化学品接触标准〔国标〕39|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyCategoryofToxicChemical

剧毒化学品分类剧毒物品分级、分类与品名编号(GB57-93)Level级别OralLD50经口LD50(mg/kg)DermalLD50经皮肤LD50(mg/kg)InhaleLC50吸入LC50(mg/l)InhaleLC50forliquid/vapor

吸入剧毒物品液体蒸汽或气体的LC50(ml/m3)A=5=40=0.5V=10LCandLC≤1000B>5～50>40～200>0.5～2V≥LCandLC≤3000(A级除外)40|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnly中国化学品接触标准〔GBZ2-2002〕工作场所有害因素职业接触限值

OccupationalExposureLimitforHazardousAgentsintheWorkplacePC-TWA时间加权平均容许浓度（8小时）。PC-MAC最高容许浓度，指在一个工作日内任何时间都不应超过的浓度。PC-STEL短时间接触容许浓度（15分钟）。*表1：数值系根据“超限系数”推算；表2：粉尘TWA的接触上限值。**表1：“其他粉尘”指不含有石棉且游离SiO2含量低于10%，不含有毒物质，尚未制订专项卫生标准的粉尘。总粉尘指直径为40mm的滤膜，按标准粉尘测定方法采样所得的粉尘。呼尘呼吸性粉尘，指按呼吸性粉尘采样方法所采集的可进入肺泡的粉尘粒子，其空气动力学直径均在7.07μｍ以下，空气动力学直径5μｍ粉尘粒子的采样效率为50%。41|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyOccupationalExposureLimitforHazardousAgentsintheWorkplace〔GBZ2-2002〕工作场所有害因素职业接触限值工作场所空气中有毒物质容许浓度(mg/m3)例如ExamplesNo中文名（CASNo.）英文名MACTWA*STEL1.安妥(86-88-4)Antu--0.30.9*2.氨(7664-41-7)Ammonia--20303.2-氨基吡啶（皮）（504-29-0）2-Aminopyridine(skin)--25*4.氨基磺酸铵（7773-06-0）Ammoniumsulfamate--615*5.氨基氰（420-04-2）Cyanamide--25*6.奥克托今（2691-41-0）Octogen--247.巴豆醛（4170-30-3）Crotonaldehyde12----8.百菌清（1897-45-6）Chlorothalonile1----9.倍硫磷（皮）（55-38-9）Fenthion(skin)--0.20.310.苯（皮）（71-43-2）Benzene(skin)--61042|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnly42WhatareEngineeringControls?

什么是工程控制？Engineeringcontrolsarethosechangesand/oradditionstoequipmentinordertoreduceoreliminateexposurestochemicalorphysicalagents.工程控制是对设备器材的改变或添加附件，从而减少或消除对物理或化学品的接触可能Examplesofsuchcontrolsareventilationsystems,barriers,shields,diffusers,reroutingofpiping,relocatingofvents,etc.此类控制的典型例子如：通风系统、屏障设置、防护罩、扩散装置、管道的路线变更、通风口的重置等43|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnly43WhatareEngineeringControls?

什么是工程控制？Otherengineeringcontrolsincludechangesinprocessconditions(temperatures,pressures,catalysts,etc.)orchangesinchemicalsused.其他工程控制包括运作条件的更改〔温度、压力、催化剂等〕或使用化学品的更改Engineeringcontrolshouldalwaysbethefirstmethodofcontrolused,ifcosteffective.本钱合理的情况下，工程控制应始终被作为第一控制方法44|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnly44WhatareAdministrativeControls?

什么是管理控制？Administrativecontrolsincludelimitationsuponnumberofworkhours,alterationsofworkschedules,work/restcycles,personnelsubstitutions,etc.管理控制包括工作小时数的限制，工作进度的变更、工作休息相结合、工作人员替补等Administrativecontrolsshouldbeconsiderednextifengineeringcontrolsareimpractical.管理控制应被视作工程控制不可行情况下的第二选择45|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnly45WhatisPersonalProtectiveEquipment(PPE)?

什么是个人防护设备〔PPE)？PPEarealltheitemswornbytheindividual,usuallyasabarrier,toprotectfromchemicalorphysicalexposurebyblockingarouteofexposure.个人防护设备是个人佩穿的所有防护配置，作为一种屏障来防止化学品或物理反响对人体的伤害。46|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnly46WhatisPersonalProtectiveEquipment(PPE)?

什么是个人防护设备〔简称PPE〕？PPEincludescoverallsorlabcoats,chemically-resistantgloves,respirators,safetyshoes,safetyeyewear,barriershielding,hearingprotection,etc.PPE包括连裤工作服或实验服、防化学手套、呼吸器、平安鞋、平安眼罩、屏障防护服、耳部保护等等PPEshouldonlybeusedifengineeringoradministrativecontrolsarenotpossibleorpractical;andthenonlyasatemporarymeasure.PPE只应在工程控制或管理控制不能完全保证的情况下使用，并且只应作为临时性措施47|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnly47ExampleofPPE

PPE的范例Coveralls连裤防护服Boots防护靴Gloves手套

AirlineRespirator空气管路呼吸器

Fullfaceshield全面面屏罩Earplugs耳塞Hardhatnotrequiredduetoworklocation是否需要平安帽取决于不同的场所的要求48|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyCriteriaforcategorizationofcommerciallyavailablesubstance

商业物质分类标准Category1:NonHazardousorslightlyHazardousSubstances

没有危害或低危害物质Category2:ModeratelyHazardousSubstance中等危害物质Category3:HighlyHazardousSubstances高度危害物质Category4:VeryHighlyHazardousSubstance极度危害物质49|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyCriteriaforcategorizationofcommerciallyavailablesubstance

商业物质分类标准50|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyGeneralScheme“AssignmentofProtectionMeasures〞

制定防护措施的一般方案GeneralProtectionMeasures一般保护措施Planttechnology工厂技术Ventilation通风Procedures工艺Training培训Cleaning清洁PPESpecificprotectionmeasures相应的防护措施basedonworkplacehealthriskassessment基于工作场所的风险评估HazardCategory危害种类51|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyProtectionMeasuresforCategory1

针对1类物质的保护措施RulesregardingpersonalhygieneAmbientairmonitoringfordustyorvolatilesubstancesGoodgeneralventilationLEVforopenhandlingofdustyorvolatilesubstancesPPE/specialPPE52|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyProtectionMeasuresforCategory2

针对2类物质的保护措施DecontaminationofpollutedPPEPartialrecirculationofroomairnotpermittedunlesssuitablefilterisusedandcontaminantlevelsbelowexposurelimitsLEVandPPE/specialPPEforopenhandlingDoublewardrobeforpersonnel53|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyProtectionMeasuresforCategory3

针对3类物质的保护措施Closedmaterialtransfersandprocesscontainment,avoidopenhandling.Openhandlinglimitedtosmallquantities,andLEVbeappliedOperationsofgeneratingairbornedustorvaporsmaybesegregatedthroughphysicalbarriersandseparateventilationsystem.Thetreatmentofcontaminatedair(HEPAfiltrationetc)FullPPErequiredwherecontainmentisnottechnicallyfeasible.54|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyProtectionMeasuresforCategory4

针对4类物质的保护措施TotalcontainmentrequiredFullairsuppliedsuitorequivalentistobeworn,andambientairmonitoringforopenhandlingoroperationwithpotentialexposurerisks.Negativeairpressureconditionforworkingarea(airlock/doubleairlock)Highefficiencyairtreatmentsystems(e.g.doubleHEPA)55|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnlyPhysicalHazardandPrevention物理危害和预防56|PresentationTitle|PresenterName|Date|Subject|BusinessUseOnly56PhysicalHealthHazards

物理接触危害Physicalhazardsincludesound(noise),ionisingandnon-ionisingradiation,