【聚合物塑料热解与燃烧研究现状的文献综述3900字】

-PAGE44--PAGE43-聚合物塑料热解与燃烧研究现状的文献综述固体可燃物热解是燃烧发生的前提，热解产生的可燃气体有利于燃烧。专家学者对聚合物塑料的热解与燃烧已经有数十年，具有大量的文献可以参考。本节分别从热解（无氧）和燃烧两个方面对前人关于几种典型聚合物塑料的研究进行总结回顾。其中热解方面包括热解动力学的求解、热解模型的建立、聚合物与其他物质共热解以及热解气态产物的分析，燃烧研究则是侧重材料的厚度、外加热辐射通量与燃烧参数关系和火灾危险性的判定。1.1典型聚合物热解动力学及机理Chen等人ADDINEN.CITEADDINEN.CITE.DATA[\o"Chen,2019#114"9,\o"Chen,2020#113"10]研究了微米粒径的PMMA废弃物在氮气中的热解动力学，反应机理以及挥发产物。他们认为微米粒径PMMA废弃物热解的活化能值大于前人研究中传统粒径PMMA热解的活化能值，在实际应用中，适当提高反应器的升温速率，可以使微米粒径PMMA废料在惰性气氛中热解获得较高的MMA产率。Cheng等人ADDINEN.CITE<EndNote><Cite><Author>Cheng</Author><Year>2016</Year><RecNum>117</RecNum><DisplayText><styleface="superscript">[11]</style></DisplayText><record><rec-number>117</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1601603354">117</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Cheng,Jie</author><author>Pan,Yong</author><author>Yao,Jun</author><author>Wang,Xiaoping</author><author>Pan,Fei</author><author>Jiang,Juncheng</author></authors></contributors><titles><title>MechanismsandkineticsstudiesonthethermaldecompositionofmicronPoly(methylmethacrylate)andpolystyrene</title><secondary-title>JournalofLossPreventionintheProcessIndustries</secondary-title></titles><periodical><full-title>JournalofLossPreventionintheProcessIndustries</full-title></periodical><pages>139-146</pages><volume>40</volume><dates><year>2016</year></dates><isbn>09504230</isbn><urls></urls><electronic-resource-num>10.1016/j.jlp.2015.12.017</electronic-resource-num></record></Cite></EndNote>[\o"Cheng,2016#117"11]采用热重法研究了不同尺寸的微米粒径PMMA和PS在氮气环境下的热分解。采用多种降解模型来研究这些聚合物的热解动力学和机理。结果表明，微米粒径PMMA和PS在氮气气氛下的热分解遵循一级反应机理，聚合物的热分解稳定性随温度的升高而增大。Fateh等人ADDINEN.CITE<EndNote><Cite><Author>Fateh</Author><Year>2016</Year><RecNum>115</RecNum><DisplayText><styleface="superscript">[12]</style></DisplayText><record><rec-number>115</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1601603306">115</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Fateh,Talal</author><author>Richard,Franck</author><author>Rogaume,Thomas</author><author>Joseph,Paul</author></authors></contributors><titles><title>Experimentalandmodellingstudiesonthekineticsandmechanismsofthermaldegradationofpolymethylmethacrylateinnitrogenandair</title><secondary-title>JournalofAnalyticalandAppliedPyrolysis</secondary-title></titles><periodical><full-title>JournalofAnalyticalandAppliedPyrolysis</full-title></periodical><pages>423-433</pages><volume>120</volume><dates><year>2016</year></dates><isbn>01652370</isbn><urls></urls><electronic-resource-num>10.1016/j.jaap.2016.06.014</electronic-resource-num></record></Cite></EndNote>[\o"Fateh,2016#115"12]通过热重分析（TGA），提出一个精确的PMMA热降解模型。利用非等温条件下的TGA和傅里叶变换红外光谱（FTIR）研究了黑色PMMA在惰性（氮气）和氧化（空气）环境中不同升温速率下的热降解。应用遗传算法（GA）估算动力学参数表明，动力学参数与相应的实验观察结果具有良好的一致性。Pielichowski等人ADDINEN.CITE<EndNote><Cite><Author>Pielichowski</Author><Year>2003</Year><RecNum>232</RecNum><DisplayText><styleface="superscript">[13]</style></DisplayText><record><rec-number>232</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1614061665">232</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>KrzysztofPielichowski</author><author>KamilKulesza</author><author>EliM.Pearce</author></authors></contributors><titles><title>ThermalDegradationStudiesonRigidPolyurethaneFoamsBlownwithPentane</title><secondary-title>JournalofAppliedPolymerScience</secondary-title></titles><periodical><full-title>JournalofAppliedPolymerScience</full-title></periodical><pages>2319–2330</pages><volume>88</volume><dates><year>2003</year></dates><urls></urls></record></Cite></EndNote>[\o"Pielichowski,2003#232"13]详细研究了硬质PU泡沫的热解动力学。在氮气和空气环境氛围中，三种不同的阻燃添加剂——磷酸盐（NaH3PO4和Na3HP2O7）和碳酸盐（NaAl(CO3)2O2）对硬质PU泡沫热解的初始阶段有明显影响。当磷酸盐作为阻燃剂时，热解活化能值可以在一个很宽的转化率范围内保持稳定；而当碳酸盐作为阻燃剂时，活化能随转化率的变化则分为两个不同阶段。Kulesza等人ADDINEN.CITE<EndNote><Cite><Author>Font</Author><Year>2001</Year><RecNum>233</RecNum><DisplayText><styleface="superscript">[14]</style></DisplayText><record><rec-number>233</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1614063492">233</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>R.Font</author><author>A.Fullana</author><author>J.A.Caballero</author><author>J.Candela</author><author><styleface="normal"font="default"size="100%">A.Garc</style><styleface="normal"font="default"charset="238"size="100%">ı</style><styleface="normal"font="default"size="100%">´a</style></author></authors></contributors><titles><title>Pyrolysisstudyofpolyurethane</title><secondary-title>JournalofAnalyticalandAppliedPyrolysis</secondary-title></titles><periodical><full-title>JournalofAnalyticalandAppliedPyrolysis</full-title></periodical><pages>63-77</pages><volume>58-59</volume><dates><year>2001</year></dates><urls></urls></record></Cite></EndNote>[\o"Font,2001#233"14]将热重与红外光谱、质谱以及气相色谱等技术联用，研究了聚醚型PU热分解过程，并讨论了其详细机理。TG-FTIR和TG-MS结合分析了PU热解释放出旳气态产物。曾文茹等人ADDINEN.CITE<EndNote><Cite><Author>曾文茹</Author><Year>2008</Year><RecNum>237</RecNum><DisplayText><styleface="superscript">[15]</style></DisplayText><record><rec-number>237</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1614064632">237</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author><styleface="normal"font="default"charset="134"size="100%">曾文茹</style></author><author><styleface="normal"font="default"charset="134"size="100%">姚</style><styleface="normal"font="default"size="100%"></style><styleface="normal"font="default"charset="134"size="100%">斌</style><styleface="normal"font="default"size="100%"></style></author><author><styleface="normal"font="default"charset="134"size="100%">宗若雯</style></author><author><styleface="normal"font="default"charset="134"size="100%">周允基</style></author></authors></contributors><titles><title><styleface="normal"font="default"charset="134"size="100%">非线性等转化率法研究聚苯乙烯热解反应活化能与转化率的关系</style></title><secondary-title><styleface="normal"font="default"charset="134"size="100%">高分子材料科学与工程</style></secondary-title></titles><periodical><full-title>高分子材料科学与工程</full-title></periodical><pages>128-131</pages><volume>24</volume><number>8</number><dates><year>2008</year></dates><urls></urls><electronic-resource-num>10.16865/ki</electronic-resource-num></record></Cite></EndNote>[\o"曾文茹,2008#237"15]采用非线性等转化率法研究了在氮气气氛中的PS的非等温TG曲线。发现PS的活化能随转化率发生明显变化。在热解起始阶段，反应活化能值仅为80kJ/mol，当转化率超过0.9时会迅速减小。在此基础上，吴用等人ADDINEN.CITE<EndNote><Cite><Author>吴用</Author><Year>2006</Year><RecNum>235</RecNum><DisplayText><styleface="superscript">[16]</style></DisplayText><record><rec-number>235</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1614064276">235</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author><styleface="normal"font="default"charset="134"size="100%">吴用</style></author><author><styleface="normal"font="default"charset="134"size="100%">曾文茹</style></author></authors></contributors><titles><title><styleface="normal"font="default"charset="134"size="100%">聚苯乙烯在空气中热降解的化学动力学研究</style></title><secondary-title><styleface="normal"font="default"charset="134"size="100%">安徽化工</style></secondary-title></titles><periodical><full-title>安徽化工</full-title></periodical><pages>24-26</pages><volume>6</volume><dates><year>2006</year></dates><urls></urls></record></Cite></EndNote>[\o"吴用,2006#235"16]研究了空气气氛下PU的热解行为，釆用模型拟合法Coats-Redfern法求解动力学参数。王昭君等人ADDINEN.CITE<EndNote><Cite><Author>王昭君</Author><Year>2011</Year><RecNum>234</RecNum><DisplayText><styleface="superscript">[17]</style></DisplayText><record><rec-number>234</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1614064266">234</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author><styleface="normal"font="default"charset="134"size="100%">王昭君</style><styleface="normal"font="default"size="100%">,</style><styleface="normal"font="default"charset="134"size="100%">孙诗兵</style><styleface="normal"font="default"size="100%">,</style><styleface="normal"font="default"charset="134"size="100%">田英良</style><styleface="normal"font="default"size="100%">,</style><styleface="normal"font="default"charset="134"size="100%">陈</style><styleface="normal"font="default"size="100%"></style><styleface="normal"font="default"charset="134"size="100%">超</style></author></authors></contributors><titles><title><styleface="normal"font="default"charset="134"size="100%">挤塑聚苯乙烯板材的受热过程研究</style></title><secondary-title><styleface="normal"font="default"charset="134"size="100%">中国朔料</style></secondary-title></titles><periodical><full-title>中国朔料</full-title></periodical><pages>49-51</pages><volume>25</volume><number>3</number><dates><year>2011</year></dates><urls></urls><electronic-resource-num>10.19491/j.issn.1001</electronic-resource-num></record></Cite></EndNote>[\o"王昭君,2011#234"17]利用TG-FTIR联用，对挤塑聚苯乙烯（XPS）材料的热解特性和气态产物进行了研究。Park等人ADDINEN.CITE<EndNote><Cite><Author>Park</Author><Year>2019</Year><RecNum>2</RecNum><DisplayText><styleface="superscript">[18]</style></DisplayText><record><rec-number>2</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1601543568">2</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Park,Ki-Bum</author><author>Jeong,Yong-Seong</author><author>Guzelciftci,Begum</author><author>Kim,Joo-Sik</author></authors></contributors><titles><title>Characteristicsofanewtypecontinuoustwo-stagepyrolysisofwastepolyethylene</title><secondary-title>Energy</secondary-title></titles><periodical><full-title>Energy</full-title></periodical><pages>343-351</pages><volume>166</volume><dates><year>2019</year></dates><isbn>03605442</isbn><urls></urls><electronic-resource-num>10.1016/j.energy.2018.10.078</electronic-resource-num></record></Cite></EndNote>[\o"Park,2019#2"18]用螺旋反应器和流化床反应器对废弃聚乙烯（PE）进行了热解研究。研究的主要目的是在适中的反应条件下，制备高烯烃含量的热解气和清洁的热解油。Al-Salem和Liu等人ADDINEN.CITE<EndNote><Cite><Author>Al-Salem</Author><Year>2010</Year><RecNum>21</RecNum><DisplayText><styleface="superscript">[19,20]</style></DisplayText><record><rec-number>21</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1601543569">21</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Al-Salem,S.M.</author><author>Lettieri,P.</author></authors></contributors><titles><title>Kineticstudyofhighdensitypolyethylene(HDPE)pyrolysis</title><secondary-title>ChemicalEngineeringResearchandDesign</secondary-title></titles><periodical><full-title>ChemicalEngineeringResearchandDesign</full-title></periodical><pages>1599-1606</pages><volume>88</volume><number>12</number><dates><year>2010</year></dates><isbn>02638762</isbn><urls></urls><electronic-resource-num>10.1016/j.cherd.2010.03.012</electronic-resource-num></record></Cite><Cite><Author>Zhisheng</Author><Year>2014</Year><RecNum>17</RecNum><record><rec-number>17</rec-number><foreign-keys><keyapp="EN"db-id="5rx2ztss5pv206evxvwx2sen5dr5xvzarv5v"timestamp="1604058316">17</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Zhisheng,Xu</author><author>Long,Yan</author><author>Yong,Liu</author></authors></contributors><titles><title>StudyonCorrelationsbetweentheFlammabilityandDynamicSmokePropertiesofFourDecorativeMaterials</title><secondary-title>ProcediaEngineering</secondary-title></titles><periodical><full-title>ProcediaEngineering</full-title></periodical><pages>498-505</pages><volume>84</volume><dates><year>2014</year></dates><isbn>18777058</isbn><urls></urls><electronic-resource-num>10.1016/eng.2014.10.461</electronic-resource-num></record></Cite></EndNote>[\o"Al-Salem,2010#21"19,\o"Zhisheng,2014#17"20]研究了高密度聚乙烯（HDPE）的热解动力学。Al-Salem等人利用获得的数据提出了一种新的动力学模型方法，基于聚合物的一次和二次解聚反应热裂解形成热解产物，而Liu等人则是首次将ReaxFF分子动力学应用于模拟含有7216个原子的HDPE模型体系的热解过程。此外，Kai等人ADDINEN.CITE<EndNote><Cite><Author>Kai</Author><Year>2017</Year><RecNum>84</RecNum><DisplayText><styleface="superscript">[21,22]</style></DisplayText><record><rec-number>84</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1601543677">84</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>XingpingKai</author><author>RundongLi</author><author>TianhuaYang</author><author>ShengqiangShen</author><author>QiuxiaJi</author><author>TaoZhang</author></authors></contributors><titles><title>Studyontheco-pyrolysisofricestrawandhighdensitypolyethyleneblendsusingTG-FTIR-MS</title><secondary-title>EnergyConversionandManagement</secondary-title></titles><periodical><full-title>EnergyConversionandManagement</full-title></periodical><pages>20-33</pages><volume>146</volume><dates><year>2017</year></dates><urls></urls><electronic-resource-num>10.1016/j.enconman.2017.05.026</electronic-resource-num></record></Cite><Cite><Author>Kai</Author><Year>2019</Year><RecNum>75</RecNum><record><rec-number>75</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1601543677">75</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Kai,Xingping</author><author>Yang,Tianhua</author><author>Shen,Shengqiang</author><author>Li,Rundong</author></authors></contributors><titles><title>TG-FTIR-MSstudyofsynergisticeffectsduringco-pyrolysisofcornstalkandhigh-densitypolyethylene(HDPE)</title><secondary-title>EnergyConversionandManagement</secondary-title></titles><periodical><full-title>EnergyConversionandManagement</full-title></periodical><pages>202-213</pages><volume>181</volume><dates><year>2019</year></dates><isbn>01968904</isbn><urls></urls><electronic-resource-num>10.1016/j.enconman.2018.11.065</electronic-resource-num></record></Cite></EndNote>[\o"Kai,2017#84"21,\o"Kai,2019#75"22]利用TG-FTIR-MS研究HDPE与稻草、玉米秸秆共混物的共热解。他们认为稻草与HDPE、玉米秸秆和HDPE的共混比例对产物的类别和气体挥发物没有多大影响，但是对于产物的生成顺序和量的多少会有影响。Miranda等人ADDINEN.CITEADDINEN.CITE.DATA[\o"Miranda,1999#26"23,\o"Miranda,1999#27"24]研究了PVC在真空环境下的热解过程，并进行了动力学和产物分析。结果表明PVC在真空和氮气环境下热解主要分为三个阶段，并且三表观反应模型被提出，与一些文献数据具有很好的一致性。PVC的热解气态和液态产物主要是氯化氢（HCl）和含氯的碳氢化合物，而剩余的固体残渣则被用来确定元素含量，表面特征和热值分析。Gui等ADDINEN.CITE<EndNote><Cite><Author>Gui</Author><Year>2013</Year><RecNum>18</RecNum><DisplayText><styleface="superscript">[25]</style></DisplayText><record><rec-number>18</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1601543569">18</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Gui,Ben</author><author>Qiao,Yu</author><author>Wan,Dan</author><author>Liu,Shuai</author><author>Han,Zainan</author><author>Yao,Hong</author><author>Xu,Minghou</author></authors></contributors><titles><title>Nascenttarformationduringpolyvinylchloride(PVC)pyrolysis</title><secondary-title>ProceedingsoftheCombustionInstitute</secondary-title></titles><periodical><full-title>ProceedingsoftheCombustionInstitute</full-title></periodical><pages>2321-2329</pages><volume>34</volume><number>2</number><dates><year>2013</year></dates><isbn>15407489</isbn><urls></urls><electronic-resource-num>10.1016/ci.2012.08.013</electronic-resource-num></record></Cite></EndNote>[\o"Gui,2013#18"25]对PVC进行了热解实验，研究了特征温度、峰值保持时间和升温速率对新生的焦油的影响。根据实验结果，提出了一种新的聚氯乙烯焦油生成的四阶段机理，即：（1）脱氯伴有内环作用，（2）芳烃链断裂，（3）准3环或3环基团的释放，（4）2环基团的释放。Sun等人ADDINEN.CITE<EndNote><Cite><Author>Sun</Author><Year>2007</Year><RecNum>22</RecNum><DisplayText><styleface="superscript">[26]</style></DisplayText><record><rec-number>22</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1601543569">22</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Sun,Qing-lei</author><author>Shi,Xin-gang</author><author>Lin,Yun-liang</author><author>Zhu,He</author><author>Wang,Xiao</author><author>Cheng,Chuan-ge</author><author>Liu,Jian-hua</author></authors></contributors><titles><title>Thermogravimetric-MassSpectrometricStudyofthePyrolysisBehaviorofPVC</title><secondary-title>JournalofChinaUniversityofMiningandTechnology</secondary-title></titles><periodical><full-title>JournalofChinaUniversityofMiningandTechnology</full-title></periodical><pages>242-245</pages><volume>17</volume><number>2</number><dates><year>2007</year></dates><isbn>10061266</isbn><urls></urls><electronic-resource-num>10.1016/s1006-1266(07)60080-7</electronic-resource-num></record></Cite></EndNote>[\o"Sun,2007#22"26]使用热重-质谱方法研究了PVC的热分解产物主要为氯化氢、苯、小分子烃和含氯气体。Wu等人ADDINEN.CITE<EndNote><Cite><Author>Wu</Author><Year>2014</Year><RecNum>98</RecNum><DisplayText><styleface="superscript">[27]</style></DisplayText><record><rec-number>98</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1601543677">98</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Wu,J.</author><author>Chen,T.</author><author>Luo,X.</author><author>Han,D.</author><author>Wang,Z.</author><author>Wu,J.</author></authors></contributors><auth-address>KeyLaboratoryofBiofuels,QingdaoInstituteofBioenergy&BioprocessTechnology,ChineseAcademyofSciences(CAS),Qingdao266101,China. KeyLaboratoryofBiofuels,QingdaoInstituteofBioenergy&BioprocessTechnology,ChineseAcademyofSciences(CAS),Qingdao266101,China.Electronicaddress:wangzq@.</auth-address><titles><title>TG/FTIRanalysisonco-pyrolysisbehaviorofPE,PVCandPS</title><secondary-title>WasteManag</secondary-title><alt-title>Wastemanagement</alt-title></titles><periodical><full-title>WasteManag</full-title><abbr-1>Wastemanagement</abbr-1></periodical><alt-periodical><full-title>WasteManagement</full-title></alt-periodical><pages>676-82</pages><volume>34</volume><number>3</number><keywords><keyword>EnvironmentalPollutants/*chemistry</keyword><keyword>*Incineration</keyword><keyword>Polyethylene/*chemistry</keyword><keyword>Polystyrenes/*chemistry</keyword><keyword>PolyvinylChloride/*chemistry</keyword><keyword>*Spectroscopy,FourierTransformInfrared</keyword><keyword>*Thermogravimetry</keyword></keywords><dates><year>2014</year><pub-dates><date>Mar</date></pub-dates></dates><isbn>1879-2456(Electronic) 0956-053X(Linking)</isbn><accession-num>24411064</accession-num><urls><related-urls><url>/pubmed/24411064</url></related-urls></urls><electronic-resource-num>10.1016/j.wasman.2013.12.005</electronic-resource-num></record></Cite></EndNote>[\o"Wu,2014#98"27]分析了PE,PS和PVC氮气环境下共热解行为通过热重-红外光谱。TGA结果表明：PVC、PS和PE的热稳定性依次提高。红外光谱的结果表明：当PE与PVC或PS混合后，产物中存在的大量不饱和炔烃含量降低。上面内容主要是阐述了几种典型聚合物PMMA、PU、PS、PE和PVC在热解动力学、机理和气态产物等方面的研究，而对于CPVC在这些方面的研究很少。Elakesh等人ADDINEN.CITEADDINEN.CITE.DATA[\o"Elakesh,2005#23"28,\o"Elakesh,2003#24"29]进行了热重分析在氮气、空气和氧气气氛中，CPVC在不同升温速率下的热解行为与PVC相比有显著差异。Carty等人ADDINEN.CITE<EndNote><Cite><Author>Carty</Author><Year>2002</Year><RecNum>25</RecNum><DisplayText><styleface="superscript">[30]</style></DisplayText><record><rec-number>25</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1601543569">25</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>PeterCarty</author><author>DennisPrice</author><author>G.JohnMilnes</author></authors></contributors><titles><title>ChlorinatedPoly(vinylchloride)andPlasticizedChlorinatedPoly(vinylchloride)-ThermalDecompositionStudies</title><secondary-title>JournalOfVinyl&AdditweTechnology</secondary-title></titles><periodical><full-title>JournalOfVinyl&AdditweTechnology</full-title></periodical><pages>227-237 </pages><volume>8</volume><dates><year>2002</year></dates><urls></urls></record></Cite></EndNote>[\o"Carty,2002#25"30]比较了一个未增塑的CPVC和三个增塑的CPVC的热分解。然而，上述研究还不足以揭示CPVC热解动力学，所以本文的第一个研究点是探索其热解行为并获得合适的动力学参数和反应模型，然后将红外光谱及质谱技术联合热重分析确定其可能的气态产物和热解反应。1.2典型聚合物燃烧特性Rhodes等人ADDINEN.CITE<EndNote><Cite><Author>Rhodes</Author><Year>1996</Year><RecNum>64</RecNum><DisplayText><styleface="superscript">[31]</style></DisplayText><record><rec-number>64</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1601543610">64</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>BrianT.Rhodes</author><author>JamesG.Quintiere</author></authors></contributors><titles><title>BurningRateandFlameHeatFluxforPMMAinaConeCalorimeter</title><secondary-title>FireSafetyJournal</secondary-title></titles><periodical><full-title>FireSafetyJournal</full-title></periodical><pages>221-240</pages><volume><styleface="normal"font="default"charset="134"size="100%">26</style></volume><number>3</number><dates><year><styleface="normal"font="default"charset="134"size="100%">1996</style></year></dates><urls></urls></record></Cite></EndNote>[\o"Rhodes,1996#64"31]在锥形量热计加热装置中，研究了PMMA的点燃和燃烧速率数据并建立一个测试方案，预测点燃和燃烧速率。Luche等人ADDINEN.CITE<EndNote><Cite><Author>Luche</Author><Year>2011</Year><RecNum>101</RecNum><DisplayText><styleface="superscript">[32]</style></DisplayText><record><rec-number>101</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1601543677">101</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Luche,Jocelyn</author><author>Rogaume,Thomas</author><author>Richard,Franck</author><author>Guillaume,Eric</author></authors></contributors><titles><title>CharacterizationofthermalpropertiesandanalysisofcombustionbehaviorofPMMAinaconecalorimeter</title><secondary-title>FireSafetyJournal</secondary-title></titles><periodical><full-title>FireSafetyJournal</full-title></periodical><pages>451-461</pages><volume>46</volume><number>7</number><dates><year>2011</year></dates><isbn>03797112</isbn><urls></urls><electronic-resource-num>10.1016/j.firesaf.2011.07.005</electronic-resource-num></record></Cite></EndNote>[\o"Luche,2011#101"32]通过锥形量热仪耦合傅里叶红外变换光谱确定了PMMA的燃烧主要产生气体（CO2，CO，H2O，NO和O2），并且采用标准耗氧法计算了不同热辐射通量下的热释放速率、总放热量和有效燃烧热。Xu等人ADDINEN.CITE<EndNote><Cite><Author>Xu</Author><Year>2018</Year><RecNum>231</RecNum><DisplayText><styleface="superscript">[33]</style></DisplayText><record><rec-number>231</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1614056651">231</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Xu,Qiang</author><author>Jin,Cong</author><author>Majlingova,Andrea</author><author>Zachar,Martin</author><author>Restas,Agoston</author></authors></contributors><titles><title>EvaluatetheflammabilityofaPUfoamwithdouble-scaleanalysis</title><secondary-title>JournalofThermalAnalysisandCalorimetry</secondary-title></titles><periodical><full-title>JournalofThermalAnalysisandCalorimetry</full-title></periodical><pages>3329-3337</pages><volume>135</volume><number>6</number><section>3329</section><dates><year>2018</year></dates><isbn>1388-6150 1588-2926</isbn><urls></urls><electronic-resource-num>10.1007/s10973-018-7494-2</electronic-resource-num></record></Cite></EndNote>[\o"Xu,2018#231"33]对一种软质PU泡沫塑料进行了微尺度和小尺度的燃烧性能实验。微尺度实验耦合傅里叶变换红外光谱分析得到了气体的演化成分、单位质量的放热率、总放热量、放热能力和最低点燃温度。在小尺度实验中，获得了单位面积的峰值放热率、有效燃烧热、最小点燃热辐射通量以及不同入射热辐射通量的单位面积总放热量。根据测试结果，采用多元判别函数分析方法对PU泡沫塑料进行了评价，分析了两种尺度实验之间的关系。安等人ADDINEN.CITE<EndNote><Cite><Author>An</Author><Year>2015</Year><RecNum>95</RecNum><DisplayText><styleface="superscript">[34]</style></DisplayText><record><rec-number>95</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1601543677">95</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>WeiguangAn</author><author><styleface="normal"font="default"charset="134"size="100%">LinJiang</style></author><author><styleface="normal"font="default"charset="134"size="100%">JinhuaSun</style></author><author><styleface="normal"font="default"charset="134"size="100%">K.M.Liew</style></author></authors></contributors><titles><title>Correlationanalysisofsamplethickness,heatflux,andconecalorimetrytestdataofpolystyrenefoam</title><secondary-title>JournalofThermalAnalysisandCalorimetry</secondary-title></titles><periodical><full-title>JournalofThermalAnalysisandCalorimetry</full-title></periodical><pages><styleface="normal"font="default"size="100%">229</style><styleface="normal"font="default"charset="134"size="100%">–238</style></pages><volume>119</volume><dates><year>2015</year></dates><urls></urls><electronic-resource-num>10.1007/s10973-014-4165-9</electronic-resource-num></record></Cite></EndNote>[\o"An,2015#95"34]研究了EPS和XPS在锥形量热仪中的热性能和燃烧性能。对样品厚度、热辐射通量与实验结果进行了相关分析表明热辐射通量与标准水平线到样品的垂直距离呈线性关系。Xu等人ADDINEN.CITE<EndNote><Cite><Author>Xu</Author><Year>2016</Year><RecNum>151</RecNum><DisplayText><styleface="superscript">[35]</style></DisplayText><record><rec-number>151</rec-number><foreign-keys><keyapp="EN"db-id="fdvtpde509v2d2e0wt7xe95tvv05zat2e2vr"timestamp="1605517438">151</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Xu,Qiang</author><author>Jin,Cong</author><author>Jiang,Yong</author></authors></contributors><titles><title>Comparetheflammabilityoftwoextrudedpolystyrenefoamswithmicro-scalecombustioncalorimeterandconecalorimetertests</title><secondary-title>JournalofThermalAnalysisandCalorimetry</secondary-title></titles><periodical><full-title>JournalofThermalAnalysisandCalorimetry</full-title></periodical><pages>2359-2366</pages><volume>127</volume><number>3</number><dates><year>2016</year></dates><isbn>1388-6150 1588-2926</isbn><urls></urls><electronic-resource-num>10.1007/s10973-016-5754-6</electronic-resource-num></record></Cite></EndNote>[\o"Xu,2016#151"35]采用微尺度锥形量热仪和锥形量热仪测试了两种XPS的燃烧特性。用微尺度燃烧量热仪测试是最大比热释放率、比热释放率、热释放温