磷酸二辛脂MSDS英文.doc

MATERIAL SAFETY DATA SHEET20130901* SECTION 1 - Product Identification *MSDS : Phosphoric acid, bis(2-ethylhexyl) esterCAS : 298-07-7SYNONYMS : * Bis(2-ethylhexyl)hydrogen phosphate* Bis(2-ethylhexyl)orthophosphoric acid* Bis(2-ethylhexyl)phosphate* Bis(2-ethylhexyl)phosphoric acid* Dehpa extractant* Di(2-ethylhexyl)orthophosphoric acid* Di(2-ethylhexyl)phosphate* Di-2(ethylhexyl)phosphoric acid* 2-Ethyl-1-hexanol hydrogen phosphate* Hdehp* Kyselina di-(2-ethylhexyl)fosforecna* SECTION 2 - HAZARDS IDENTIFICATION *EMERGENCY OVERVIEWHarmful in contact with skin. Causes burns.Corrosive.Potential Health EffectsEye:Causes eye burns.Skin:Causes skin burns. May be harmful if absorbed through the skin.Ingestion:May cause irritation of the digestive tract.Inhalation:May cause respiratory tract irritation.Chronic:No information found.* SECTION 3 - Composition/Information on Ingredients *CAS# | Chemical Name | % | EINECS# |-|-|-|-| 298-07-7 |Bis(2-ethylhexyl) hydrogen phosphate | 95.0 | 206-056-4 |Hazard Symbols: CRisk Phrases: 21 34* SECTION 4 - FIRST AID MEASURES *Eyes:Immediately flush eyes with plenty of water for at least 15 minutes,occasionally lifting the upper and lower eyelids. Get medical aidimmediately.Skin:Get medical aid immediately. Flush skin with plenty of water for atleast 15 minutes while removing contaminated clothing and shoes.Ingestion:If victim is conscious and alert, give 2-4 cupfuls of milk or water.Never give anything by mouth to an unconscious person. Get medicalaid immediately.Inhalation:Remove from exposure and move to fresh air immediately. If notbreathing, give artificial respiration. If breathing is difficult,give oxygen. Get medical aid.Notes to Physician:* SECTION 5 - FIRE FIGHTING MEASURES *General Information:As in any fire, wear a self-contained breathing apparatus inpressure-demand, MSHA/NIOSH (approved or equivalent), and fullprotective gear. During a fire, irritating and highly toxic gasesmay be generated by thermal decomposition or combustion. Contactwith metals may evolve flammable hydrogen gas. Containers may explodewhen heated.Extinguishing Media:Do NOT get water inside containers. For large fires, use drychemical, carbon dioxide, alcohol-resistant foam, or water spray. Forsmall fires, use carbon dioxide, dry chemical, dry sand, oralcohol-resistant foam. Cool containers with flooding quantities ofwater until well after fire is out.* SECTION 6 - ACCIDENTAL RELEASE MEASURES *General Information: Use proper personal protective equipment as indicatedin Section 8.Spills/Leaks:Absorb spill with inert material (e.g. vermiculite, sand or earth),then place in suitable container. Do not get water insidecontainers.* SECTION 7 - HANDLING and STORAGE *Handling:Wash thoroughly after handling. Remove contaminated clothing andwash before reuse. Use with adequate ventilation. Do not get in eyes,on skin, or on clothing. Keep container tightly closed. Avoidingestion and inhalation.Storage:Store in a tightly closed container. Store in a cool, dry,well-ventilated area away from incompatible substances.* SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION *Engineering Controls:Use adequate ventilation to keep airborne concentrations low.Exposure LimitsCAS# 298-07-7:Personal Protective EquipmentEyes:Wear appropriate protective eyeglasses or chemicalsafety goggles as described by OSHAs eye and faceprotection regulations in 29 CFR 1910.133 or EuropeanStandard EN166.Skin:Wear appropriate protective gloves to prevent skinexposure.Clothing:Wear appropriate protective clothing to prevent skinexposure.Respirators:Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Use aNIOSH/MSHA or European Standard EN 149 approvedrespirator if exposure limits are exceeded or ifirritation or other symptoms are experienced.* SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES *Physical State: LiquidColor: amberOdor: none reportedpH: Not available.Vapor Pressure: Not available.Viscosity: Not available.Boiling Point: 48 deg C 12.00mmHgFreezing/Melting Point: - 60.00 - - 0.00 degAutoignition Temperature: Not available.Flash Point: 137 deg C ( 278.60 deg F)Explosion Limits, lower: Not available.Explosion Limits, upper: Not available.Decomposition Temperature:Solubility in water: slightly solubleSpecific Gravity/Density: .9700g/cm3Molecular Formula: C16H35O4PMolecular Weight: 322.42* SECTION 10 - STABILITY AND REACTIVITY *Chemical Stability:Stable under normal temperatures and pressures.Conditions to Avoid:Incompatible materials, strong oxidants.Incompatibilities with Other Materials:Strong oxidizing agents - strong bases.Hazardous Decomposition Products:Phosphorous fumes.Hazardous Polymerization: Has not been reported.* SECTION 11 - TOXICOLOGICAL INFORMATION *RTECS#:CAS# 298-07-7: TB7875000LD50/LC50:CAS# 298-07-7: Draize test, rabbit, eye: 5 mg Moderate; Draize test,rabbit, eye: 250 ug/24H Severe; Draize test, rabbit, skin: 5 mg/24HSevere; Oral, rat: LD50 = 4940 uL/kg; Skin, rabbit: LD50 = 1250uL/kg.Carcinogenicity:Bis(2-ethylhexyl) hydrogen phosphate -Not listed by ACGIH, IARC, or NTP.Other:See actual entry in RTECS for complete information.* SECTION 12 - ECOLOGICAL INFORMATION * SECTION 13 - DISPOSAL CONSIDERATIONS *Dispose of in a manner consistent with federal, state, and local regulations.* SECTION 14 - TRANSPORT INFORMATION *IATAShipping Name: DIISOOCTYL ACID PHOSPHATEHazard Class: 8UN Number: 1902Packing Group: IIIIMOShipping Name: DIISOOCTYL ACID PHOSPHATEHazard Class: 8UN Number: 1902Packing Group: IIIRID/ADRShipping Name: DIISOOCTYL ACID PHOSPHATEHazard Class: 8UN Number: 1902Packing group: III* SECTION 15 - REGULATORY INFORMATION *European/International RegulationsEuropean Labeling in Accordance with EC DirectivesHazard Symbols: CRisk Phrases:R 21 Harmful in contact with skin.R 34 Causes burns.Safety Phrases:S 24/25 Avoid contact with skin and eyes.S 25 Avoid contact with eyes.S 36/37/39 Wear suitable protective clothing, glovesand eye/face protection.S 45 In case of accident or if you feel unwell, seekmedical advice immediately (show the label wherepossible).WGK (Water Danger/Protection)CAS# 298-07-7: 1CanadaCAS# 298-07-7 is listed on Canadas DSL List.CAS# 298-07-7 is listed on Canadas Ingredient Disclosure List.US FEDERALTSCACAS# 298-07-7 is listed on the TSCA inventory.* SECTION 16 -