华东理工大学课堂教学方案设计表(1).doc

华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院牟伯中物理化学（双语I）3/48必修12006/2本讲知识点、重点、难点0. Introduction1. The properties of gases 1.1 The states of gases1.2 The gas laws重点与难点：Definitions Extensive property and intensive property, System and surroundings, States, Function of states, Equation of statesThe states of gases the perfect gas, the perfect gas equation, gas constant, Mole fractions and partial pressures, Daltons Law. 本讲所用方法和手段、与上一讲的衔接，与下一讲的联系阐明物理化学理论框架，基本概念及其联系。阐明物质的pVT关系是宏观层次上的物质的特性，通过实验的方法获得物质的特性，从而关联普遍定律的方法论。 本讲师生互动设计课堂讨论：The gas law and the weather本讲布置的作业、思考题等内容Exercises: P39-41 (a)2, 7, 8, 13, 14, 16, 17, 21, 22, 24, 27, 29, 30Problems: P42-43: 4, 7, 10, 15, 29华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院牟伯中物理化学（双语I）3/48必修22006/2本讲知识点、重点、难点1. The properties of gases 1.3 The kinetic model of gases1.4 Molecular interactions1.5 The van de Waals equation1.6 The principle of corresponding states 重点与难点：The kinetic model of gases Three assumptions for the kinetic model, Molecular mean speeds, The collision frequency, The mean free path. The Molecular interactions Repulsive forces and attractive forces, The compression factor, Virial coefficients, Phase diagram, Critical constants.The van der Waals equation Real gas, van der Waals coefficients, internal pressure.The principle of corresponding Relative variables, The corresponding states, principle of corresponding states.本讲所用方法和手段、与上一讲的衔接，与下一讲的联系简单复习物质特性获得的三种方法。由范德华方程推导过程，即从实际流体的行为与理想气体的差别出发，通过建立模型，对理想气体状态方程进行修正，探讨对实际系统研究的方法。所涉及的数学方法。本讲师生互动设计课堂讨论： The properties and applications of Super Critical FluidsThe difference between perfect gases and real gases本讲布置的作业、思考题等内容Exercises: P39-41 (a)2, 7, 8, 13, 14, 16, 17, 21, 22, 24, 27, 29, 30Problems: P42-43: 4, 7, 10, 15, 29华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院牟伯中物理化学（双语I）3/48必修32006/2本讲知识点、重点、难点2. The First Law: the concepts2.1 Work, heat, and energy2.2 The First Law2.3 Expansion work2.4 Heat transactions2.5 Enthalpy重点与难点：The First Law The First Law, The internal energy.Expansion work Unimolecular reactions The general expression, Free expansion, Against constant pressure, Isothermal reversible expansion. Heat transactions Heat capacity at constant VEnthalpy Definition, Heat capacity at constant p, The variation of enthalpy with temperature, The relation between two heat capacities, 本讲所用方法和手段、与上一讲的衔接，与下一讲的联系pVT关系与系统的内能变化的关联 引入描述系统状态的新函数：焓本讲师生互动设计课堂讨论： 就热力学能与功和热的关系讨论状态函数与过程变量的区别本讲布置的作业、思考题等内容Exercises on Page 75-78 :2.4(a); 2.6(a); 2.8(a); 2.11(a); 2.13(a); 2.15(a); 2.19(a); 2.21(a); 2.24(a); 2.27(a); 2.29(b); 2.32(a); 2.35(a); 2.39(a); 2.40(a); 2.44(a).Problem on Page 42-43: 2.2; 2.3; 2.4; 2.7.华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院牟伯中物理化学（双语I）3/48必修42006/2本讲知识点、重点、难点2. The First Law: the concepts2.6 Adiabatic changes2.7 Standard enthalpy changes2.8 Standard enthalpies of formation2.9 The temperature dependence of reaction enthalpies重点与难点：Adiabatic changes The functions of adiabatic change, Heat capacity ratio. Standard enthalpy changes Standard states, Enthalpies of physical change, Enthalpies of chemical change, Enthalpy of combustion, enthalpy of formation, Hesss lawThe temperature dependence of reaction enthalpies Kirchhoff law, 本讲所用方法和手段、与上一讲的衔接，与下一讲的联系加深对状态函数焓的理解，进一步掌握系统发生物理、化学变化时系统能量焓的变化，以及焓随温度变化的特征。本讲师生互动设计课堂讨论:热性质测定的各种实验方法本讲布置的作业、思考题等内容Exercises on Page 75-78 :2.4(a); 2.6(a); 2.8(a); 2.11(a); 2.13(a); 2.15(a); 2.19(a); 2.21(a); 2.24(a); 2.27(a); 2.29(b); 2.32(a); 2.35(a); 2.39(a); 2.40(a); 2.44(a).Problem on Page 42-43: 2.2; 2.3; 2.4; 2.7.华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院牟伯中物理化学（双语I）3/48必修52006/2本讲知识点、重点、难点3. The First Law: the machinery3.1 State functions3.2 The temperature dependence of the enthalpy3.3 The reaction between Cv and CpTutorial 重点与难点：State functions State functions, Path functions, Exact and inexact differential, The internal pressure, expansion coefficient.The temperature dependence of the enthalpy Changes in enthalpy at constant volume, The isothermal compressibility, The Joule -Thomson effectThe reaction between Cv and Cp 本讲所用方法和手段、与上一讲的衔接，与下一讲的联系 在上一讲的基础上，继续加深对热力学第一定律的理解，充分讨论系统焓的变化。本讲师生互动设计课堂讨论：The difference between State functions and Path functionsThe Joule -Thomson effect and its applications in the cooling.本讲布置的作业、思考题等内容Exercises: P93 (a)10, 11, 12.Problems: P93-95: 3, 16, 24, 29.华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院牟伯中物理化学（双语I）3/48必修62006/2本讲知识点、重点、难点4. The Second Law: the concepts4.1 The dispersal of energy4.2 Entropy重点与难点：The dispersal of energy The direction of spontaneous change, Second Law of Thermodynamics.Entropy The thermodynamic definition of entropy, The Carnot cycle, The entropy as a state function, The efficiency of a heat engine, The thermodynamic temperature, The entropy of system and surroundings, The Clausius inequality, The criterion for spontaneous direction.本讲所用方法和手段、与上一讲的衔接，与下一讲的联系由上一讲能量的转化，展开到本讲能量的传递，由热机效率及第二类永动机的不可能性引出热和功的本质区别，建立热力学第二定律从热力学第二定律，以卡诺定理的结论，建立判断过程方向和限度的普遍规律的热力学基本方法。本讲师生互动设计课堂讨论： Use Clausius inequality to discuss the spontaneous direction of different thermodynamic process本讲布置的作业、思考题等内容Exercises on Page 120-122 :4.2(a); 4.4(a); 4.5(a); 4.6(a); 4.10(a); 4.11(a); 4.12(a); 4.13(a); 4.14(a); 4.18(a); 4.20(a); 4.22(a); 4.23(a).Problem on Page 122-123: 4.1, 4.5, 4.8, 4.12, 4.22. 华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院牟伯中物理化学（双语I）3/48必修72006/2本讲知识点、重点、难点4. The Second Law: the concepts 4.3 Entropy changes accompanying specific processes4.4 The Third Law of thermodynamics4.5 Reaching very low temperatures重点与难点：Entropy changes accompanying specific processes The entropy of phase transition, The isothermal expansion of a perfect gas, The variation of entropy with temperature, The measurement of entropy form heat capacity.The Third Law of thermodynamics The Nernst heat theorem, The Third-Law entropy, standard entropy, The standard reaction entropy, Reaching very low temperatures.本讲所用方法和手段、与上一讲的衔接，与下一讲的联系 结合具体过程，继续深化讨论系统熵的变化，在讨论绝对熵的基础上，引出热力学第三定律。本讲师生互动设计课堂讨论： Reaching very low temperature本讲布置的作业、思考题等内容Exercises on Page 120-122 :4.2(a); 4.4(a); 4.5(a); 4.6(a); 4.10(a); 4.11(a); 4.12(a); 4.13(a); 4.14(a); 4.18(a); 4.20(a); 4.22(a); 4.23(a).Problem on Page 122-123: 4.1, 4.5, 4.8, 4.12, 4.22. 华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院牟伯中物理化学（双语I）3/48必修82006/2本讲知识点、重点、难点4. The Second Law: the concepts 4.6 The Helmholtz and Gibbs energies4.7 Standard molar Gibbs energies重点与难点：The Helmholtz and Gibbs energies Clausius inequality，the definition of Helmholtz and Gibbs energies, Maximum work, Maximum non-expansion work. Standard molar Gibbs energies The standard Gibbs energies of reaction, The standard Gibbs energies of formation. 本讲所用方法和手段、与上一讲的衔接，与下一讲的联系 本讲结合Clausius inequality，讨论系统在等容或等压条件下，热力学函数Helmholtz and Gibbs energies的计算，通过学习使学生了解和掌握普遍规律和物质特性间的联系以及如何应用普遍规律和物质的特性解决实际问题。本讲师生互动设计课堂讨论：After the introduction of Helmholtz energy, explain the Gibbs energy by the students themselves.本讲布置的作业、思考题等内容Exercises on Page 120-122 :4.2(a); 4.4(a); 4.5(a); 4.6(a); 4.10(a); 4.11(a); 4.12(a); 4.13(a); 4.14(a); 4.18(a); 4.20(a); 4.22(a); 4.23(a).Problem on Page 122-123: 4.1, 4.5, 4.8, 4.12, 4.22. 华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院牟伯中物理化学（双语I）3/48必修92006/2本讲知识点、重点、难点5. The Second Law: the machinery 5.1 Properties of the internal energy5.2 Properties of the Gibbs energy5.3 The chemical potential of a pure substance重点与难点：Properties of the internal energy Five state functions in the First and Second Laws, The fundamental equations, The Maxwell relations, The variation of internal energy with volume, Properties of the Gibbs energy The outline of the Gibbs energy with T and p,The temperature dependence of the Gibbs energy, The pressure dependence of the Gibbs energy,.The chemical potential of a pure substance Partial molar quantities, The definition of chemical potential, The chemical potential of a pure substance.本讲所用方法和手段、与上一讲的衔接，与下一讲的联系 明确各热力学函数的相互计算的关系，重点讨论Gibbs energy随温度和压力的变化组成可变的多相多组分系统的热力学是组成不变的均相封闭系统的延伸，起着承前启后的作用；引入偏摩尔量和化学势的意义和重要性。本讲师生互动设计课堂讨论： Deduce the relation among the five state functions through the fundamental equations and the Maxwell relations, then from the easier measured state function to calculate the others.本讲布置的作业、思考题等内容Exercises on Page 137 :5.2(a); 5.3(a); 5.5(a); 5.6(a); 5.7(a); 5.9(a); 5.10(a).Problem on Page 137-138: 5.1, 5.3, 5.4 (Numerical) 5.5, 5.6, 5.10 (Theoretical)华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院牟伯中物理化学（双语I）3/48必修102006/2本讲知识点、重点、难点5. The Second Law: the machinery 5.4 The definition of fugacity5.5 Standard states of real gases5.6 The relation between fugacity and pressure重点与难点：The definition of fugacity definition of fugacity, the fugacity at different pressure, Standard states of real gases Standard states of real gasesThe relation between fugacity and pressure fugacity coefficient, expression for the fugacity coefficient at any pressure p本讲所用方法和手段、与上一讲的衔接，与下一讲的联系 逸度是用来表达真实气体化学势的一种物质特性，首先引入真实气体标准状态，使真实与理想气体化学势表达式具有相同的表达形式，逸度因子是对非理想性的一种度量。 本讲师生互动设计课堂讨论：通过实际气体化学势表达式的推导，理解路易斯提出逸度概念的意义本讲布置的作业、思考题等内容 Exercises on Page 137 :5.2(a); 5.3(a); 5.5(a); 5.6(a); 5.7(a); 5.9(a); 5.10(a).Problem on Page 137-138: 5.1, 5.3, 5.4 (Numerical) 5.5, 5.6, 5.10 (Theoretical)华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院牟伯中物理化学（双语I）3/48必修112006/2本讲知识点、重点、难点Midterm review重点与难点：本讲所用方法和手段、与上一讲的衔接，与下一讲的联系 本讲师生互动设计课堂讨论：本讲布置的作业、思考题等内容 华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院胡军物理化学（双语I）3/48必修122006/2本讲知识点、重点、难点6. Physical transformations of pure substances 6.1 The stabilities of phases6.2 Phase boundaries6.3 Three typical phase diagrams重点与难点：The stabilities of phases Definition of phase, The phase transition, The transition temperature.Phase boundaries The phase diagram, Phase boundaries, The triple point, Boiling Melting and Freezing points, Critical points, supercritical fluid.Three typical phase diagrams Water, Carbon dioxide, The helium.本讲所用方法和手段、与上一讲的衔接，与下一讲的联系 相平衡研究的两条途径;其一是直接实验测定制作相图或解析式，其二是根据热力学普遍规律给出的相平衡条件进行理论计算。本讲师生互动设计课堂讨论：Why the solid and liquid phase boundary of CO2 and H2O have different sign of the slope本讲布置的作业、思考题等内容Exercises on Page 160 :6.1(a); 6.2(a); 6.3(a); 6.4(a); 6.5(a); 6.8(a); 6.9(a); 6.12(a); 6.13(a); 6.14(a);Problem on Page 161: 6.2, 6.5, 6.10华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院胡军物理化学（双语I）3/48必修132006/2本讲知识点、重点、难点6. Physical transformations of pure substances 6.4 The thermodynamic criterion of equilibrium6.5 The dependence of stability on the conditions6.6 The location of phase boundaries6.7 The Ehrenfest classification of phase 重点与难点：The thermodynamic criterion of equilibrium The thermodynamic criterion of equilibrium.The dependence of stability on the conditions The temperature dependence, The response of melting to applied pressure, The effect of applied pressure on vapour pressure.The location of phase boundaries The Clapeyron equation, The slopes of the phase boundaries (L-G, L-S, G-S).The Ehrenfest classification of phase The first-order phase transition, The second-order phase transition.本讲所用方法和手段、与上一讲的衔接，与下一讲的联系从化学势随系统条件的变化，进一步分析物质相变的热力学规律本讲师生互动设计课堂讨论：Estimate the typical size of the effect of increasing pressure on the boiling point of a liquid.本讲布置的作业、思考题等内容Exercises on Page 160 :6.1(a); 6.2(a); 6.3(a); 6.4(a); 6.5(a); 6.8(a); 6.9(a); 6.12(a); 6.13(a); 6.14(a);Problem on Page 161: 6.2, 6.5, 6.10华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院胡军物理化学（双语I）3/48必修142006/2本讲知识点、重点、难点6. Physical transformations of pure substances 6.8 Surface tension6.9 Curved surfaces6.10 Capillary action重点与难点：Surface tension The definition of surface tension，Curved surfaces Bubbles, cavities, and droplets, Laplace equation, Kelvin equation, The supersaturated vapour, The superheated liquid, The supercooled liquid, Capillary action Capillary action, The contact angle, 本讲所用方法和手段、与上一讲的衔接，与下一讲的联系讨论真实界面的物理化学特性，着重分析和掌握弯曲界面和毛细管界面的特性。本讲师生互动设计课题讨论： Calculate the difference between pressures inside and outside of the bubbles, compare the results of cavities and droplets. 本讲布置的作业、思考题等内容Exercises on Page 160 :6.1(a); 6.2(a); 6.3(a); 6.4(a); 6.5(a); 6.8(a); 6.9(a); 6.12(a); 6.13(a); 6.14(a);Problem on Page 161: 6.2, 6.5, 6.10华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院胡军物理化学（双语I）3/48必修152006/2本讲知识点、重点、难点7. Simple mixtures 7.1 Partial molar quantities7.2 The thermodynamics of mixing7.3 The chemical potentials of liquids重点与难点：Partial molar quantities Partial molar volume, Partial molar quantities, The determination methods of partial molar quantities, Partial molar Gibbs energies, The wider significance of the chemical potential, The Gibbs-Duhem equation, The thermodynamics of mixing The Gibbs energy of ideal mixing, Other thermodynamic mixing functions. The chemical potentials of liquids Raoults Law, Henrys law- ideal dilute solutions. 本讲所用方法和手段、与上一讲的衔接，与下一讲的联系 明确组成可变的多相多组分系统的热力学是组成不变的均相封闭系统的延伸，起着承前启后的作用；引入偏摩尔量和化学势的意义和重要性。从理想气体的混合热力学引出溶液的混合特性。本讲师生互动设计课堂讨论： What is the chemical potential of a solution, and how does it vary with its composition?本讲布置的作业、思考题等内容Exercises on Page 187-189 :7.1(a); 7.3(a); 7.5(a); 7.6 (a); 7.8(a); 7.10(a); 7.12(a); 7.15(a); 7.16(a); 7.17(a); 7.18(a); 7.19(a).Problem on Page 189: 7.3, 7.7华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院胡军物理化学（双语I）3/48必修162006/2本讲知识点、重点、难点7. Simple mixtures 7.4 Liquid mixtures 7.5 Colligative properties7.6 The solvent activity7.7 The solute activity 重点与难点：Liquid mixtures The Gibbs energy of mixing of two liquids, The regular solution, The excess functions. Colligative properties definition of colligative properties, The elevation of boiling point, The depression of freezing point, Solubility properties, Osmotic properties. The solvent activity standard chemical potential of solvent, activity，activity coefficient. The solute activity standard chemical potential of solute, activity，activity coefficient, Activities in terms of molalities.本讲所用方法和手段、与上一讲的衔接，与下一讲的联系 结合上一讲，继续讨论液体混合过程的热力学特性，并应用于稀溶液的依数性的讨论。以及求取真实液体化学势时引入活度的重要性。本讲师生互动设计课堂讨论： From the discussion of activity measuring, understand deeply for the meaning of activity. 本讲布置的作业、思考题等内容Exercises on Page 187-189 :7.1(a); 7.3(a); 7.5(a); 7.6 (a); 7.8(a); 7.10(a); 7.12(a); 7.15(a); 7.16(a); 7.17(a); 7.18(a); 7.19(a).Problem on Page 189: 7.3, 7.7华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院胡军物理化学（双语I）3/48必修172006/2本讲知识点、重点、难点8. Phase diagrams8.1 Definitions8.2 The phase rule8.3 Vapour pressure diagrams重点与难点：Definitions The phase, Components, The number of components, Degrees of freedom, The phase rule The phase rule, One-component systems, Two-component systems.Vapour pressure diagrams At constant T Vapour pressure diagrams,The composition of the vapour, The interpretation of the diagrams, The lever rule. 本讲所用方法和手段、与上一讲的衔接，与下一讲的联系总结各类相图规律推出相律，初步了解在多相多组分系统中相平衡、相律的意义。本讲师生互动设计课堂讨论： Interpret the two-component systems vapour pressure diagrams. Liquid crystals本讲布置的作业、思考题等内容Exercises on Page 209 :8.1(a), 8.2(a), 8.4(a), 8.7(a), 8.8(a), 8.9(b), 8.10(b), 8.12(b), 8.14(b), 8.18(a)Problem on Page 2138.6, 8.8华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院胡军物理化学（双语I）3/48必修182006/2本讲知识点、重点、难点8. Phase diagrams8.4 Temperature-composition diagrams8.5 Liquid-liquid phase diagrams8.6 Liquid-solid phase diagrams重点与难点：Temperature-composition diagrams Temperature-composition diagrams, The distillation of mixtures, Azeotropes, Immiscible liquids, Liquid-liquid phase diagrams Phase separation, Critical solution temperatures, The distillation of partially miscible liquids. Liquid-solid phase diagrams The development of a L-S phase diagram, Eutectics, Reacting systems, Incongruent melting. 本讲所用方法和手段、与上一讲的衔接，与下一讲的联系应用气液及气液液平衡相图的分析结果,利用类比的方法引出并分析典型的液固平衡相图。本讲师生互动设计课堂讨论： Interpret the two-component systems vapour pressure diagrams and its applications in the distillation.本讲布置的作业、思考题等内容Exercises on Page 209 :8.1(a), 8.2(a), 8.4(a), 8.7(a), 8.8(a), 8.9(b), 8.10(b), 8.12(b), 8.14(b), 8.18(a)Problem on Page 2138.6, 8.8华东理工大学课堂教学方案设计表学院教师姓名课程名称学分/学时课程性质第几讲学年/学期化学与分子工程学院胡军物理化学（双语I）3/48必修192006/2本讲知识点、重点、难点9. Chemical equilibrium9.1 The Gibbs energy minimum 9.2 How equilibria respond to pressure9.3 The response of equilibria to temperature重点与难点：The Gibbs energy minimum The reac