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4.5Typicalglasses,1.Silicateglasses2.Borateglasses3.Otheroxidesglasses,1.Silicateglasses,AdvantagesofSilicateglasses:highchemicalstability,highhardness,simpleproductionmethod,lowprice,rawmaterialMicroscopically,quartzglassisarandomframenetwork,whichisformedoftheconnectionofSiO4bysharingvertex.BondanglerangeofSi-Oinquartzglassisfrom120to180,whichiswiderthanthatofquartzcrystal.,SiO2isformeroxideofsilicateglass,structureandstateofwhichdeterminethepropertiesofsilicateglass.Addingofalkalioxidesandalkaliearthoxidesinsilicateglassresultsinnetworkbreaking.F.E.:AddingofNa2OSi-O-Si+Na-O-NaNaSi-OO-SiNa,Functionofintermediateformercationinsilicateglassdependonthecoordinationnumberofit,whichisdeterminedbychemicalcompositionofglass.Al+AlO4AlO6,Parametersfordescribingsilicateglassnetworkfeatures:R:ratioofoxygenatomstonetworkformercationsSiO2:R=;12molNa2O+10molCaO+78molSiO2R(12+10+782)/782.28,Z:numberofoxygenatomsinnetworkformercationpolyhedron.X:numberofnon-bridgeoxygenatomsinnetworkformercationpolyhedron.Y:numberofbridgeoxygenatomsinnetworkformercationpolyhedron.RelationshipamongR,Z,XandYcanbedescribedbybelowformula:ZXY(33)RXY(34)Insilicateglass,Z=4,andbelowformulacanbederived:XY(35)X2R-(36)Y8-2R,ValuesofX,YandRofsometypicalglasses,Yisanimportantparametertojudgeglass.AhighYsuggesthighpolymerizationofglassnetworkinsilicateglassandviceverse.3DnetworkcannotbeformedinsilicateglasswhenY2.,2.Borateglasses,Borateglasseshavesomeoutstandingfeatures,suchasslowneutronabsorptionofboronoxideglass,highX-raytransmissionandelectricinsulationofborateglasses.,B2O3isatypicalglassnetworkformer,justlikeSiO2.B2O3canformboronoxideglassesseparately.StructureunitofitisBO3.Parametersofboronoxideglasses:Z3R1.5X2R-3330Y2Z-2R633.,Inboronoxideglasses,BO3Sharevertexwithnearbyoneandformboroxolring.,Somecertainpropertiesofboronoxideglassesarelowerthanrespectivepropertiesofsilicateglassesduetothelayeredstructureorchainlikestructure.Lowsofteningtemperature(about450)DeliquesceinairHighexpansioncoefficient,YandexpansioncoefficientofNa2O-B2O3glassescontainingdifferentcontentofNa2O,BoronanomalyNa2O1516mol%:Na2O,expansioncoefficientNa2O1516mol%:Na2O,expansioncoefficientWhenNa2Ocontentislessthan1516mol%,partofBO3transformtoBO4.DuetothenegativeelectrificationofBO4,itcannotconnectwitheachotherdirectly.BO4BO4.BO4BO3BO4WhenBO4/BO3=1/4,andY1/54十4/533.2,expansioncoefficientreachitsminimumvalue.Inboros

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