MTI Global Harmonization System Webinar - rev 2 HV -- 中文

1、Global Harmonization System and Safety Data Sheets全球化学品统一分类和标签制度及安全数据表Webinar June 2015网络培训-2015年6月中文翻译校对：Martin徐明、于萍霞The Globally Harmonized System (GHS) for Hazard Classification and Labelling全球化学品统一分类和标签制度（GHS)Development of a Worldwide System for Hazard Communication编制全球通用的危险信息沟通体系What is the GH

2、S? 什么是全球化学品统一分类和标签制度？ A common and coherent approach to defining and classifying hazards, and communicating information on labels and safety data sheets. Target audiences include workers, consumers, transport workers, and emergency responders. Provides the underlying infrastructure for establishment

3、 of national, comprehensive chemical safety programs. 采用通用、一致的危险定义与分类方法，并通过一致的标签与安全数据表传递危险信息。 目标群体包括工作人员、消费者、运输工人以及应急处理人员。 为尚未建立化学品分类制度的发展中国家提供化学品安全管理基础框架。Why is the GHS needed?为何需要GHS？No country has the ability to identify and specifically regulate every hazardous chemical product.For example, in t

4、he United States, there are an estimated 650,000 such products.Adoption of requirements for information to accompany the product helps address protection needs.Countries with systems have different requirements for hazard definitions as well as information to be included on a label or material safet

5、y data sheet.For example, a product may be considered flammable or toxic in one country, but not in another to which it is being shipped.没有任何单个国家有能力单独识别并专门管制每种危险化学品。例如，在美国估计就有650,000种类的化学品。提供化学品附随的危险信息，有助于明确防护要求。虽然很多国家已采用了相关制度，但危险定义、标签信息及材料安全数据表的要求等却不尽相同。例如，A国将某种化学品认定为易燃或有毒产品，但作为输出国的B国却无此认定。Why? (ex

6、ample)为何需要GHS？（示例）Current Global Disharmony in Classification and LabelingExample: Different risk phrases used for a substance with an Acute Oral Toxicity LD50 = 257 mg/kg/dayEU Harmful (St Andrews Cross)US ToxicCAN ToxicAustralia HarmfulIndia Non-toxicJapan ToxicMalaysia HarmfulThailand HarmfulNew

7、Zealand HazardousChina Not DangerousKorea ToxicGHS. Danger (Skull & Cross Bones)当前各国危险品分类与标签制度不一致情况：示例：对于急性口服毒性为 LD50 = 257 mg/kg/天的一种物质，各国的风险描述不一致欧盟 有害（斜十字）美国 有毒加拿大 有毒澳大利亚 有害印度 无毒日本 有毒马来西亚 有害泰国 有害新西兰 危险中国 无危险韩国 有毒GHS. 危险 （骷髅与骨头十字）Benefits of Harmonization统一的好处 Countries, international organizat

8、ions, chemical producers, distributors and users of chemicals all benefit. Enhance protection of humans and environment. Facilitate international trade in chemicals. Reduce need for testing and evaluation. Assist countries and international organizations to ensure the sound management of chemicals.

9、各个国家、国际组织、化学品生产商、分销商以及用户均会受益。 加强对人类健康和环境保护。 促进化学品国际贸易。 减少测试与评估需求。 利于各国及各国际组织对化学品实施有效彻底的管理。Principles Of Harmonization统一的原则 Protections will not be reduced; comprehensibility will be key. 统一将不降低保护等级；统一的关键是易理解性。 All types of chemicals will be covered; will be based on intrinsic properties (hazards) of

10、 chemicals. 将涵盖所有类型的化学品；立足于化学物质的固有特性（危害）。 Does not apply to:不适用于 Hazardous waste危险废物 Tobacco烟草 Wood products that are not hazardous无危害的木制品 Articles日用品 Food or alcohol食品或酒类制品 Drugs 药品 Cosmetics化妆品 Consumer products日常消费品 Nuisance particles有害颗粒 Ionizing and non-ionizing radiation电离和非电离辐射 Biological haz

11、ards生物危害Old to NEW 旧新对比 The GHS Elements GHS元素Classification Criteria分类标准 Health and Environmental Hazards 健康危害、环境危害 Physical Hazards 物理危害 Mixtures 化学物质和混合物Hazard Communication危险信息公示方式 Labels 包装标签 Safety Data Sheets 化学品安全数据表Health & Environmental Hazards健康与环境危害Acute ToxicitySkin Corrosion/Irrita

12、tionSerious Eye Damage/Eye IrritationRespiratory or Skin SensitizationGerm Cell MutagenicityCarcinogenicityReproductive ToxicityTarget Organ Systemic Toxicity Single and Repeated DoseHazardous to the Aquatic Environment急性毒性皮肤腐蚀/刺激严重的眼部伤害/眼部刺激呼吸系统或皮肤致敏生殖细胞致突变性致癌性生殖毒性特定靶器官系统毒性-单次或重复剂量水生环境危险 Physical H

13、azards物理危害ExplosivesFlammability gases, aerosols, liquids, solidsOxidizers liquid, solid, gasesSelf-Reactive Pyrophoric liquids, solidsSelf-HeatingOrganic PeroxidesCorrosive to MetalsGases Under PressureWater-Activated Flammable Gases爆炸物易燃物质，包括气体、气溶胶、液体、固体氧化剂，包括固体、液体、气体自反应物质 可自燃物质，包括固体、液体可自发热物质有机过氧化

14、物金属腐蚀剂高压气体遇水后产生易燃气体的物质Hazard Classification危险分类Labels标签The Working Group identified about 35 different types of information that are currently required on labels by different systems.To harmonize, key information elements needed to be identified.Additional harmonization may occur on other elements i

15、n time, in particular for precautionary statements.经工作小组确认，当前不同制度要求的通过标签标示的信息有大约35种多。采用统一制度，需要明确关键信息元素。同时，也需要对其它元素进行及时统一，特别是预防说明部分。Labels标签Each chemical container must be labeled, tagged or marked with identity of the chemical and its hazards在每个化学品容器上必须使用标签等标明化学品名称及其危害Labels must be in language of U

16、ser标签必须是使用者的语言Key Label Elements标签上的关键元素 Product identifier产品标识Supplier identifier供应商标识Chemical identity化学名称Hazard pictograms*危害象形图Signal words* 信号词Hazard statements*危害说明Precautionary information 防范说明*Standardized标准化的标准化的Pictogram Shape and Colour标志的形状与颜色For transport, pictograms will have the backg

17、round and symbol colours currently used.For other sectors, pictograms will have a black symbol on a white background with a red diamond frame. Where a transport pictogram appears, the GHS pictogram for the same hazard should not appear.运输环节中应采用带背景的象形图，背景及符号颜色以现行危险货物运输要求为准。其它环节所采用的标志应为白色背景上印有黑色符号，符号外

18、则为一红色菱形框。在有运输象形图标志的地方，对于同一危害，不应同时使用其GHS标志。Requirements of a GHS LabelGHS标签要求Signal Words 信号词 “Danger” more severe hazards “危险”（Danger）-危害程度较高 “Warning” less severe hazards “警告”（Warning）-危害程度较低Pictograms 象形图 A symbol plus a red diamond border intended to convey specific information about the hazards

19、of a chemical. 4 Health Hazard Pictograms 5 Physical Hazard Pictograms 符号在红色菱形边框内，用于传达有关某种化学品危害的特定信息。 4 种健康危害象形图 5 种物理危害象形图Health Hazard Pictogram-Corrosion健康危害象形图-腐蚀腐蚀 Skin Corrosion/Burns 皮肤腐蚀/灼伤 Eye Damage 眼部伤害 Health Hazard Pictogram-Exclamation Mark健康危害图形健康危害图形- -感叹号感叹号 Irritant (skin and eye)

20、皮肤与眼部刺激 Skin Sensitizer皮肤致敏 Acute Toxicity急性毒性 Narcotic Effects麻醉效果 Respiratory Tract Irritant 呼吸道刺激 Hazardous to Ozone Layer (non-mandatory) 危害臭氧层 （非强制）Health Hazard Pictogram-Health Hazard健康危害图形健康危害图形- -健康危害健康危害 Carcinogen致癌性 Mutagen诱变性 Reproductive Toxicity生殖毒性 Respiratory Sensitizer呼吸道致敏 Target

21、Organ Toxicity 特定靶器官毒性（单次接触和反复接触） Aspiration Toxicity 吸入毒性Health Hazard Pictogram-Skull & Crossbones健康危害图形健康危害图形- -骷髅与骨头十字骷髅与骨头十字 Acute Toxicity (fatal or toxic) 急性毒性 （致命或剧毒）Physical Hazard Pictogram-Flame物理危害图形符号物理危害图形符号- -火焰火焰 Flammables易燃物质 Pyrophorics可自燃物质 Self-Heating可自发热物质 Emits Flammable

22、Gas 释放易燃气体的物质 Self-Reactives 自反应物质 Organic Peroxides 有机过氧化物Physical Hazard Pictogram-Flame Over Circle物理危害图形符号物理危害图形符号- -火焰圈火焰圈 Oxidizer a substance that is not necessarily combustible, but may, generally by yielding oxygen, cause or contribute to the combustion of other material氧化剂氧化剂- -不一定为易燃物质，但可

23、能会产生氧气等引发其它物质燃烧或有助燃作用。Physical Hazard Pictogram-Gas Cylinder物理危害图形符号-气瓶 Gases under pressure 高压气体Physical Hazard Pictogram-Exploding Bomb物理危害图形符号物理危害图形符号- -爆炸品爆炸品 Explosives 爆炸物 Self-Reactives 自反应物质 Organic Peroxides 有机过氧化物Physical Hazard Pictogram-Corrosion物理危害图形符号物理危害图形符号- -腐蚀腐蚀 Corrosive to Metal

24、s 金属腐蚀剂Non-mandatory Pictogram-Environment非强制图形符号非强制图形符号- -环保环保 Aquatic Toxicity危害水生环境物质Role of the SDS in the GHS SDS在GHS中的作用The SDS should provide comprehensive information about a chemical substance or mixture including hazardsDeveloped by manufacturer or importerMust be provided with each shipme

25、nt Primary Use: The WorkplaceEmployers and workers use the SDS as a source of information about hazards and to obtain advice on safety precautions.安全数据表（SDS）应提供化学品或混合物的综合信息，包括危害信息应由生产商或进口商编制每次运输均应提供主要用途：工作场所雇主和工人可从SDS中获取物质危害信息及安全防护建议。 SDS Format SDS格式1.Identification 化学品及企业标识2.Hazard(s) identificati

26、on危害性概述3.Composition/information on ingredients 组成/成分信息4. First-aid measures 急救措施5. Fire-fighting measures 消防措施6. Accidental release measures 泄露应急处理7.Handling and storage 操作处置与储存8. Exposure control/personal protection 接触控制/个人防护 SDS Format: (cont.) SDS格式：（续）9.Physical and chemical properties 理化特性10.

27、Stability and reactivity 稳定性与反应性11. Toxicological information 毒理学信息12. Ecological information 生态学信息13. Disposal considerations 废弃处置14. Transport information 运输信息15. Regulatory information法规信息16. Other information其它信息Example示例 Completed Product flag with Hazard Pictogram and SDS Labeling 完成后的产品标签：含危害

28、象形图及SDS标签MTI requirements MTI要求Each location must have a written chemical safety program based on standard EHS-SAF-01Each location shall maintain a list of all chemical substances at the site including Raw materials, Intermediate products, Finished products, Laboratory reagents and Maintenance chemi

29、cals. The name of the chemical on the list must match with the Safety Data SheetInitial and refresher Training 应按照EHS-SAF-01标准的要求，每个工厂应编制一书面的化学品安全管理程序。每个工厂应维护包含你作业场所所有化学品的清单，包括原材料、中间产品、成品、实验室试剂及维修用化学品。清单中化学品名称应与安全数据表上一致。入职培训、再培训MTI SDS AccessAccess to SDS by everyone By Hard Copy Digital via MTI Com

30、pany Intranet PCEVendor SDS https:/PCE SDS http:/usqhomsgen/default.aspxFuture centralised access point will have links on onto the Myamcol EHS page https:/ PCC and Performance MineralsMSDS Online MINTEQ MSDS / Cheme Dox Product SDS https:/apps.the- Material SDShttps:/apps.the- MTI SDS查阅任何人均可查阅SDS，包

31、括： 纸质文件 可通过MTI公司内部网络查阅电子版本 PCE供应商SDS https:/PCE SDS http:/usqhomsgen/default.aspx 将来可通过Myamcol EHS 页面https:/ PCC与Performance MineralsMSDS Online MINTEQ MSDS / Cheme Dox 产品SDS https:/apps.the- Implementation实施Timing to comply with GHS and SDS Labeling requirements vary by country.US: June 1, 2015*EU:

32、 June 1, 2015*Canada: June 1, 2016 Please check with your local regulatory agency for compliance dates Employers must update HAZCOM programs and provide additional trainingGHS与SDS标签要求的实施期限（各国有所不同）美国：2015年6月1日*欧盟：2015年6月1日*加拿大：2016年6月1日 请与当地执法管理机构确认具体实施期限雇主必须更新HAZCOM 计划，并提供附加培训Excluding transfer time

33、 for existing products不包括现有产品的转换时间 Other resources其它资源 OSHA美国职业安全与健康管理局/dsg/hazcom/index.html UN联合国/trans/danger/publi/ghs/ghs_welcome_e.html Society for Chemical Hazard Communication美国化学品危害交流协会中国http:/ http:/ Back up slides支持性资料Routes of Entry

34、进入人体的途径Chemicals may enter the body in four ways:化学品可以四种方式进入人体：Inhalation (breathing) 吸入（呼吸）Ingestion (swallowing) 摄入（吞入）Absorption through the skin 皮肤吸收Injection 注射Back up slides支持性资料Hazard Definitions & TermsDose: The amount of materials an individual is exposed toDose effects: Depend on the c

35、oncentration of materials over a period of timeAcute effects: Occur rapidly as a result of short-term exposures, and are of short durationChronic effects: Occur as a long-term exposure, and are of long duration危害定义与术语剂量剂量：某种物质的个体接触量剂量效应剂量效应：接触一定浓度物质一段时间后的反应急性效应急性效应：短期接触即发生的反应，历时较短慢性效应慢性效应：长期接触后发生的反应，历时较长Chemical ClassificationHealth HazardsHazard ClassHazard CategoryAcute toxicity 1234Skin Corrosion/Irritation 1A1B1C2Serious Eye Damage/Eye Irritation 12A2BRespiratory or Skin Sensitization1Germ Cell Mutagenicity 1A1B2Carcinogenicity 1A1B2Reproductiv