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/LaboratoryWastewaterdisposal(Read748times)Herethechemicalusedineverytestperformed.

1.

ChloridecontentofcementﻫConc.Nitricacid

diluteNitricacid(1+2)&(1+100)ﻫsilvernitrate(8.494g/L)

AmmniumThiocyante(3.8g/L

Ammoniumironsulphate—saturatedsolutionﻫﻫ2.InsolubleresidueﻫConc.Hydrochloricacid&(1+19)

sodiumcarbonate(50g/L0

3.sulphatecontent

concHCl&(1+19)ﻫNaoh(1+16)ﻫBariumchloride(100g/L)ﻫ4。SilicaﻫAmmoniumchloride(0。5gaddto250mlwaterﻫHCl

Sulpuricacid

hydrofluricacidﻫsulpuricandhydroflouricareaddedtotheprecipiateinacrucibleandthenignited(soitsnotaddedtowastewater)ﻫfiltratesolniskeptfortotaloxidedetermination

4。totaloxidesﻫmethyred(2g/linethanol)

concnitricacidﻫammoniasoln(1:1)ﻫammoniumnitratesoln(2%)ﻫfiltratesolutioniskeptforcalciumoxidedeterminatiolciumoxide

DiluteAmmnia(1:4)

diluteHCl(1:4)

ammniumOxalate(1g/L)ﻫOxalicacid

filtratesolutionisreservedforMagnesiadeterminationﻫ6.Magnesiatestﻫconcnitric

diluteHClﻫDiammniumhydrogenphosphate(saturated)ﻫconcammonia

dilute(25ml/L)&(1:3)

ammoniumnitrate(2g/L)ﻫ7。Ferricoxidedeterminationﻫstannouschloridesoln-5gaddedto10mlHClanddiluteto100mlﻫbariumdiphenylamoinesulphonate—0。3gin100mlwaterﻫpotassiumdichromate-2。457g/Lﻫstauratedsolnofmercuricchloride

Mostlythetestiscarriedoutbyheating/boiling,washingwithacid,filtering。precipiateburnatfurnace1000Cthenweigh.

ﻫThefiltrateisdiposedirectlyintothesinkthenatthedrainageandeventuallytothesea..pHnormallyisacidic.butweneutraliseitwithdiluteammoniumhydroxide。

Isthissufficientenough?

IboughtaplasticwatertanksoIcancollectallthefiltratesandflushitlargevolumeofwaterbeforeIdisposeittothedrainage

Thefiltratesaftereachtestislessthan4liters.Pleasnyoupleasesuggestwhatisthebestwayandeasiestwaytotreatthissmllamountofwastewaterinthelab.THEPROCESSTheFacultyofSciencethroughtheirresearchactivitiesandtheirAwardProgramsproduceasignificantquantityofchemicalwastewater。Priortotheadoptionoftheircleanerproductioninitiative,thechemicalwastewaterwascollected,treatedanddisposedofbyawastecontractservice.Giventhesignificantquantitiesofwastewaterproduced,thisoptionforcollectionanddisposalprovedtobeextremelycostly.Directdischargetosewerprovidesthemosteconomicallyviableoptionforthelaboratorywastewaterofanacceptableofstandard.DespitetheFacultyofScience抯wastewaterundergoingminimalpre-treatmentwithinthelaboratoriespriortodisposalitdidnotattaintheacceptablepHstandardfordirectdischargetothePowerandWaterAuthority(PAWA)sewer。Forwastewatereffluenttobedischargeddirectlytothesewer,thepHshouldgenerallynotbelowerthan6.5andnothigherthan11.TheacidandalkaliwastestreamsthatdonotoccurwithinthisrangehavethepotentialtoseriouslyaffectthepHvalueofthereceivingwateriftheyaredischargeddirectlywithoutacceptablepre-treatment.Theacidwastewaterreactswiththealkalinityofthereceivingwaterby:Ca(HCO3)2+2HCl=CaCl2+2H2O+2CO2Alkalisreactwithfreecarbondioxidedissolvedinthereceivingwaterandincreaseitsalkalinityby:2NaOH+CO2=Na2CO3+H2OIftheFacultyofSciencehaddischargedtheirwastewaterdirectlytosewerandhadnotadjustedthereactionofthepH,thenthefollowingproblemswouldhaveoccurred:1。Biocoensisasbothanimalandplantorganismsperishinexcessivelyacidandexcessivelyalkalinemedia。2.DamagetoPAWAsewerlinesandplantstructuresfromuntreatedeffluentthatwouldcorrodebothconcreteandmetals.3.Alkalishavethepotentialtocauseseriousdifficultiesintheoperationofthereceivingtreatmentplant。Sealantsusedinconduitsmaybeattackedbyalkalis,causingleakageanddamageinthenetworkaswellascausingprecipitationofvariousdepositsandhencechokingofthepipes.4。Increaseddemandforexcessivechemicalsnecessaryforcoagulationwhenemployedasatreatmentmethod;5.Insufficientprovisionforoptimumbacterialactivityinthebiologicaltreatmentofwastes;6.ProductionofnoxiousodourswhichmayemittedatloworhighpHvalues;7。DamagetothereceivingDarwinwatersandenvironsduetothedetrimentaleffectsoftheLaboratorywastewater.Consciousofthepossibledetrimentalimpactsoftheuntreatedwastewaterandtheincreasingcostofemployingawastecontractservice,theFacultyofScienceidentifiedtheneedtoinstalltheirowntreatmentsystemwhichcouldbeutilised

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