元素分析仪性能测定方法 编制说明

食品科学等学科的研究工作中，对民生、经济提升仪器制造与检测行业水平，推动产品性能优化，根据“国家标准化管理委员会关于下达2024年第六批推荐性国家标准计划起草单位包括（排名不分先后清华大学、东华大学、中国地质大学（武误差、重复性、灵敏度、最小检测量、检出限、2025年4月-5月，起草工作组成员以电话、微信、邮件以及线上讨论会等2025年5月底，标准文本经多次修改，形成标准征求意见稿；并汇总标准的正确度。为尽量避免待测元素含量因素影响示值误差对仪器测试正确度的表灵敏度参与后续检出限/最小检测量的计算，表征了仪器对于待测物量变化的响样量的质量单位（本标准中限定mg以确保同类检测器间可比性。常使用的“最小检测量”表示，望文生义，更易指一定置信度下特定分析方法能够检出的可分辨的最小分析信号所求得的最低选取测试对象原则为覆盖仪器测量范围的多个待测元素含量区间、供货稳性能测定方法验证试验对象选用各种有机化工产品标准物质（或标准样品氧氮氢元素分析仪与碳硫元素分析仪性能测定方法验证试验对象选用钢铁标准物YSBC21080-2-2008测量元素单位C（0.0010）S（0.0015）工作曲线方程Y=0.1480x+0.2913Y=0.5655x+0.4367工作曲线相关系数0.99980.9996单点校准10.000990.00150单点校准20.000940.00150单点校准30.001060.00150校准系数0.793YSBC21080-3-2008C＜0.002%S＜0.002%标准值0.00120.0017%测量值10.001320.00170%测量值20.001230.00170%测量值30.001130.00173%测量平均值0.001230.00171%示值误差2.50（C＜0.002%）0.59（S＜0.002%）%GSB03-2458-2008测量元素单位C（0.030）S（0.030）工作曲线方程Y=0.1480x+0.2913Y=0.5655x+0.4367工作曲线相关系数0.99980.9996单点校准10.030360.03040单点校准20.030190.03005单点校准30.029450.02955校准系数YSBC11026-2015C：0.002%--0.01%S：0.002%--0.01%标准值0.00220.0082%测量值10.002380.00833%测量值20.002310.00826%测量值30.002210.00849%测量平均值0.002300.00836%示值误差4.55（C：0.002%--0.01%）1.95（S：0.002%--0.01%）%YSBC28125-95测量元素单位C（0.465）S（0.0155）工作曲线方程Y=10.2615x+0.9311Y=0.5655x+0.4367工作曲线相关系数0.99990.9996单点校准10.46560.01573单点校准20.46440.01550单点校准30.46500.01526校准系数1.009571.029453YSBC11230-99标准值0.092±0.0060.011±0.001%S：0.01%--0.05%测量值10.096730.01054%测量值20.094940.01045%测量值30.096420.01051%测量平均值0.096030.01050%示值误差4.38（C：0.01%--0.1%）-4.55（S：0.01%--0.05%）%YSBC11033-2018测量元素单位C（1.95）S（0.143）工作曲线方程Y=10.2615x+0.9311Y=0.5655x+0.4367工作曲线相关系数0.99990.9996单点校准10.1430单点校准20.1447单点校准30.1431校准系数0.9971980.995617YSBC11417d-2011YSBC11031-2018S：0.05%--0.1%标准值0.7410.079%测量值10.74270.08091%测量值20.74140.08075%测量值30.74120.08010%测量平均值0.74180.08059%示值误差%测量元素单位工作曲线方程Y=10.2615x+0.9311Y=0.5655x+0.4367工作曲线相关系数0.99990.9996单点校准10.1272单点校准23.0820.1306单点校准30.1323校准系数1.0067451.03116YSBC11033-2018C＞1%标准值0.143%测量值10.1475%测量值20.1493%测量值30.1476%测量平均值1.96870.1481%示值误差0.96（C＞1%）3.57（S＞0.1%）%测量元素单位CS工作曲线方程Y=0.153651x-0.038169Y=0.029172x-0.000394工作曲线相关系数0.9993860.999047GBW01401aC:<0.002%S:<0.002%标准值0.001500.0015%测量值10.001490.00153%测量值20.001440.00160%测量值30.001410.00154%测量平均值0.001450.00156%示值误差-3.56（C:<0.002%）3.78（S:<0.002%）%YSB15339-01C:0.002%~0.01%S:0.002%~0.01%标准值0.007000.00650%测量值10.006920.00669%测量值20.006890.00666%测量值30.006950.00657%测量平均值0.006920.00664%示值误差（C:0.002%~0.01%）2.15（S:0.002%~0.01%）%YSBC28103c-13CS05-15C:0.01%~0.1%S:0.01%~0.05%标准值0.052000.01600%测量值10.052020.01562%测量值20.051940.01592%测量值30.052240.01570%测量平均值0.052070.01575%示值误差0.128（C:0.01%~0.1%）-1.58（S:0.01%~0.05%）%YSBC19226-2000S:0.05%~0.1%标准值0.440.053%测量值10.440990.05333%测量值20.440010.05234%测量值30.439330.05302%测量平均值0.440110.05290%示值误差0.025（C:0.1%~1%）-0.195（S:0.05%~0.1%）%机字84-35C:>1%标准值2.080.196%测量值12.082090.19677%测量值22.075030.19647%测量值32.080420.19514%测量平均值2.079180.19613%示值误差-0.039(C:＞1%)0.065(S:＞0.1%)%测量元素单位CS工作曲线方程y=1.30211985x-0.00001256y=0.98454445x-0.00000366工作曲线相关系数0.9999910.994804钢YSBC11025-2015C0.002%标准值0.00120.0010%测量值10.0013180.001096%测量值20.0010810.001026%钢502-935S0.002%测量值30.0012210.001145%测量平均值0.0012070.001089%示值误差0.0556（C:＜0.002%）8.90(S:＜0.002%)%钢YSBC11026-2015C：0.002%~0.01%S：0.002%~0.01%标准值0.00220.0082%测量值10.0019820.008061%测量值20.0023170.008231%测量值30.0023480.008245%测量平均值0.0022160.008179%示值误差0.712(C:0.002%~0.01%)-0.256(S:0.002%~0.01%)%钢502-863C：0.01%~0.1%S：0.01%~0.05%标准值0.0420.0132%测量值10.042450.01266%测量值20.041740.01293%测量值30.041800.01310%测量平均值0.0022160.008179%示值误差-0.008(C:0.01%~0.1%)-2.30(S:0.01%~0.05%)%钢YSBC11417d-2011S：0.05%~0.1%标准值0.7410.056%测量值10.73670.05896%测量值20.74550.05697%测量值30.74150.05212%测量平均值0.74120.05602%示值误差0.031(C:0.1%~1%)0.030(S:0.05%~0.1%)%生铁YSBC11003b-2011C1%S0.1%标准值3.360.154%测量值13.3700.1565%测量值23.3760.1473%测量值33.3770.1571%测量平均值3.3740.1536%示值误差0.427(C:＞1%)-0.238(S:＞0.1%)%测量元素单位CS校准曲线方程y=0.27976x²+0.01817x+0.00067y=0.00254x²+0.00248x+0.00003校准曲线相关系数0.9999980.999994纯铁助熔剂821EYSBC28099-96C0.002%S0.002%标准值0.00040.0012%测量值10.000350.00113%测量值20.000420.00109%测量值30.000450.00124%测量平均值0.0004070.001153%示值误差1.75（C:＜0.002%）-3.92(S:＜0.002%)%工业纯铁QD16-257C：0.002%~0.01%S：0.002%~0.01%标准值0.00220.0036%测量值10.002120.003415%测量值20.0021010.003285%测量值30.0022450.003319%测量平均值0.0021550.00334%示值误差-2.05(C:0.002%~0.01%)-7.22(S:0.002%~0.01%)%钢铁BH1314-1G08MnPREC：0.01%~0.1%S：0.01%~0.05%标准值0.0920.011%测量值10.091260.01086%测量值20.092110.01285%测量值30.092450.01031%测量平均值0.091940.01134%示值误差-0.065(C:0.01%~0.1%)3.09(S:0.01%~0.05%)%低合金钢GBW01303S：0.05%~0.1%标准值0.70.064%测量值10.704290.06383%测量值20.695350.06486%测量值30.709120.06364%测量平均值0.702920.06411%示值误差0.4171430.171875%碳工钢T12QD98-28、合金铸铁463C1%S0.1%标准值1.20(C:0.1%~1%)0.233(S:0.05%~0.1%)%测量值11.2034510.22813%测量值21.2005010.23174%测量值31.2032640.22687%测量平均值1.2024050.22891%示值误差0.034(C:＞1%)-1.76(S:＞0.1%)%GBW(E)020215GBW(E)020142测量元素单位O（0.0034%）N（0.0042%）H（0.00058）工作曲线方程Y=0.1096x+0.0658Y=0.7561x+0.35Y=0.2089x-0.0412工作曲线相关系数0.99960.99990.9993单点校准10.0033340.0042500.000566单点校准20.0035180.0041690.000593单点校准30.0033480.0041810.000581校准系数0.9833561.010371.0877GBW(E)020126O:＜0.003%N:＜0.004%GBW(E)020147标准值0.00120.00220.00013%测量值10.0012300.0022590.000140%测量值20.0012400.0020780.000135%测量值30.0012410.0021080.000141%H:＜0.0002测量平均值0.0012370.0021480.000139%相对示值误差3.08(O：<0.003%）-2.36（N：<0.004%）6.92（H：<0.0002）%GBW(E)020215GBW(E)020142测量元素单位O（0.0034%）N（0.0042%）H（0.00058%）工作曲线方程Y=0.1096x+0.0658Y=0.7561x+0.35Y=0.2089x-0.04工作曲线相关系数0.99960.99990.9993单点校准10.0033340.0042500.000566单点校准20.0035180.0041690.000593单点校准30.0033480.0041810.000581校准系数0.9833561.010371.0877GBW(E)020209O:0.003%-0.01%N:0.004%-0.04%YSBS20602-2008H:0.0002%-0.0005%标准值0.00310.00580.000355%测量值10.0029620.0058350.000364%测量值20.0028730.0060540.000361%测量值30.0029370.0060040.000345%测量平均值0.0029240.0059640.000356%相对示值误差-5.680.003%-0.01%)2.830.004%-0.04%）0.280.0002%-0.0005%）%GBW(E)020083GBW(E)020142GBW(E)020260测量元素单位O（0.012%）N（0.031%）H(0.001)工作曲线方程Y=0.1096x+0.0658Y=0.7561x+0.35Y=0.2089x-0.0412工作曲线相关系数0.99960.99990.9993单点校准10.0120590.0307010.000985单点校准20.0120040.0310540.001033单点校准30.0119360.0312450.000982校准系数0.993721.0028270.9583GBW(E)020260O:＞0.01%N:＞0.04%GBW(E)020146H:＞0.0005%标样编号GBW(E)020260N：GBW(E)020260GBW(E)020146%标准值0.0170.0640.00072%测量值10.0168040.0642990.000682%测量值20.0165650.0642920.000678%测量值30.0165540.0643740.000692%测量平均值0.0166410.0643220.000684%相对示值误差0.01%）0.50（N:＞0.04%）-5.00（H:＞0.0005%）%测量元素单位%ONH工作曲线方程Y=0.007495x+0.000575Y=0.005497x+0.004135Y=0.002498x+0.000645工作曲线相关系数0.9990700.9991150.999255GBW(E)020126YSBC35318-2017O:<0.003%N:<0.004%H:<0.0002%标准值0.00120.00220.00018%测量值10.0011710.0022510.0001699%测量值20.0011650.0022970.000179%测量值30.0012060.0021590.000185%测量平均值0.0011800.0022360.000178%示值误差-1.63（O:<0.003%）（N:<0.004%）-0.488（H:<0.0002%）%GBW(E)020280O:0.003%~0.01%N:0.004%~0.04%H:0.0002%~0.0005%标准值0.00740.0360.00041%测量值10.0072810.0368690.000405%测量值20.0073110.0364980.0004%测量值30.0074030.0361210.000395%测量平均值0.0073310.0364960.0004%示值误差-0.923（O:0.003%~0.01%）（N:0.004%~0.04%）-2.44（H:0.0002%~0.0005%）%GBW(E)020260O:>0.01%N:>0.04%H:>0.0005%标准值0.0170.0640.001%测量值10.0170170.0636140.000961%测量值20.0166080.0641020.000995%测量值30.0173540.0641160.00104%测量平均值0.0169930.0639440.000999%示值误差-0.041（O:>0.01%）-0.088（N:>0.04%）-0.133（H:>0.0005%）%测量元素单位ONH工作曲线方程y=0.92995692x-0.00000003y=0.79735318x-0.00000897y=0.65928849x工作曲线相关系数0.9992310.9998961钢502-935Ln0719-1O＜0.003%高磷钢GBW（E）020085N＜0.004%标准值0.00270.000750.00020%测量值10.002710.0007850.00020%测量值20.002750.0007780.000203%测量值30.002650.0007460.000191%测量平均值0.002700.0007700.000198%示值误差0.1232.62-1.00%不锈钢GBW（E）020066H＜0.0002(O＜0.003%)(N＜0.004%)(H＜0.0002)钢502-903O:0.003%~0.0钢502-893N:0.004%~0.04%钢502-935Ln0719-1H:0.0002%~0.0005%标准值0.00650.00480.00022%测量值10.00660.004830.000198%测量值20.006400.004870.000220%测量值30.006460.004930.000220%测量平均值0.006490.004880.000213%示值误差-0.205(O:0.003%~0.01%)(N:0.004%~0.04%)-3.33(H:0.0002%~0.0005%)%钢503-537O:＞0.01%N:＞0.04%H:＞0.0005%标准值0.01110.06770.00069%测量值10.01120.06820.000655%测量值20.01100.06720.000715%测量值30.01130.06830.000683%测量平均值0.01120.06790.000684%示值误差0.601(O:＞0.01%)0.295(N:＞0.04%)-0.821(H:＞0.0005%)%测量元素单位ONH校准曲线方程y=0.00700974x-0.00093836y=0.005001352x+0.003543706y=0.00224375x+0.000169786校准曲线相关系数0.999090490.9993297020.999672286GBW(E)020126O＜0.003%N＜0.004%YSBC35318-2017H＜0.0002标准值0.00120.00220.00018%测量值10.0011350.0022220.000199%测量值20.0011090.0022050.000168%测量值30.0011190.0021920.000172%测量平均值0.0011210.0022063330.000179667%示值误差-6.58(O＜0.003%)0.288(N＜0.004%)6.21(H＜0.0002)%GSB03-1065-1999O:0.003%~0.01%N:0.004%~0.04%YSBS3531标准值0.00640.01650.0029%测量值10.0062650.0165190.000284%测量值20.006540.0168390.000275%测量值30.0065610.0167790.000308%测量平均值0.0064553330.0167123330.000289%示值误差0.865-0.345%2-2016H:0.0002%~0.0005%(O:0.003%~0.01%)(N:0.004%~0.04%)(H:0.0002%~0.0005%)GBW(E)020260O:＞0.01%N:＞0.04%H:＞0.0005%标准值0.0170.0640.001%测量值10.0168460.06360.001001%测量值20.0169070.0636910.000999%测量值30.0172140.064020.001079%测量平均值0.0169890.0637703330.001026333%示值误差-0.065(O:＞0.01%)-0.359(N:＞0.04%)2.63(H:＞0.0005%)%测量元素单位CHNS校准曲线方程Y=3.068E-06*X-0.0009Y=9.440E-07*X+0.0003Y=8.564E-06*X-0.0135Y=6.907E-060.0054校准曲线相关系数0.99997680.99988840.99996650.9999636对氨基苯磺酸标准值41.5734.0748.08718.515%测量值141.5494.0558.06918.536%测量值241.5844.0618.09318.566%测量值341.6774.0988.07218.566%测量平均值41.6034.0718.07818.556%示值误差+0.030-0.003-0.009+0.041%校准曲线方程Y=2.684E-06*X+0.0011Y=9.214E-07*X+0.0006Y=8.883E-06*X-0.0148Y=7.912E-060.0076-校准曲线相关系数0.99964860.99977790.99985380.9997554-胱氨酸标准值29.9895.03326.689%测量值129.9935.14526.545%测量值230.0645.00726.626%测量值329.9875.08626.742%测量平均值30.0155.07926.638%示值误差+0.026+0.046+0.013-0.051%测量元素单位CHNS当日校准因子11.01070.97700.99811.0199当日校准因子21.01220.97521.00011.0209当日校准因子31.01350.97391.00091.0206校准因子平均值1.01220.97540.99971.0205对氨基苯磺酸标准值41.614.078.09测量值141.604.068.10测量值241.564.068.10测量值341.654.078.09测量平均值41.604.068.10示值误差0.010.010.010.04测量元素单位CHN校准曲线方程Y=3.127E-06*X-0.0070Y=9.659E-07*X+0.0024Y=8.553E-06*X-0.0010校准曲线相关系数0.99998190.99988220.9999278对氨基苯磺酸标准值41.5734.0748.087%测量值141.6714.0658.046%测量值241.6534.088.134%测量值341.6554.0748.095%测量平均值41.6604.0738.092%示值误差+0.057-0.001+0.005%校准曲线方程Y=3.157E-06*X-0.0035Y=9.521E-07*X+0.0032Y=8.566E-06*X-0.0126校准曲线相关系数0.99979590.99992390.9994727脲标准值6.7346.70%测量值120.0486.70846.818%测量值219.9196.60646.759%测量值320.0186.68746.755%测量平均值19.9956.66746.777%示值误差+0.045-0.063+0.077%校准曲线方程Y=3.143E-06*X-0.0119Y=9.539E-07*X+0.0034Y=8.685E-06*X-0.0095校准曲线相关系数0.99997570.99993560.9998782乙酰苯胺标准值71.0896.71210.363%测量值171.0276.63810.414%测量值270.9916.70810.424%测量值371.0546.72110.357%测量平均值71.0246.68910.398%示值误差-0.065-0.023+0.035%测量元素单位CHN当日校准因子10.9940.9910.994当日校准因子20.9950.9990.997当日校准因子3校准因子平均值0.9970.9990.997脲标准值6.6546.57%测量值16.1746.89%测量值26.5247.66%测量值36.6347.62%测量平均值6.4447.39%示值误差-6.36-3.16%对氨基苯磺酸标准值41.634.0768.092%测量值141.163.998.13%测量值241.023.938.09%测量值341.013.938.05%测量平均值41.063.958.09%示值误差-1.37-3.09-0.025%乙酰苯胺标准值71.0876.71210.363%测量值170.096.88%测量值270.426.88%测量值370.266.88%测量平均值70.266.88%示值误差-1.162.500.936%测量元素单位0校准曲线方程Y=5.754E-06*X-0.0206校准曲线相关系数0.9998360对氨基苯磺酸标准值26.62%测量值126.542%测量值226.555%测量值326.567%测量平均值26.555%示值误差-0.065%校准曲线方程Y=1.832E-06*X-0.0192校准曲线相关系数0.9997959乙酰苯胺标准值%测量值1%测量值2%测量值3%测量平均值%示值误差+0.001%S单位校准曲线方程Y=8.418E-06*X+0.0429校准曲线相关系数0.9998196对氨基苯磺酸标准值18.515%测量值118.423%测量值218.464%测量值318.613%测量平均值18.500%示值误差-0.015%校准曲线方程Y=1.617E-05*X-0.0021校准曲线相关系数0.9995896胱氨酸标准值26.689%测量值126.531%测量值226.694%测量值326.638%测量平均值26.621%示值误差-0.068%示值误差结果（%）示值误差绝对值间变异系数A单位B单位C单位D单位C:＜0.002%2.5-3.560.55660.5C:0.002%~0.01%4.550.712-2.0581.3C:0.01%~0.1%4.380.128-0.008-0.0650.0250.031C:＞1%0.96-0.0390.4270.034S:＜0.002%0.593.788.90-3.9279.9S:0.002%~0.01%2.15-0.256-7.22S:0.01%~0.05%-4.55-1.58-2.303.0944.2S:0.05%~0.1%2.01-0.1950.0300.233S:＞0.1%3.570.065-0.238-1.76示值误差结果（%）示值误差绝对值间变异系数（%）A单位B单位C单位D单位O:<0.003%3.08-1.630.123-6.5897O:0.003%~0.01%-5.68-0.923-0.2050.865O:>0.01%-0.0410.601-0.065N:<0.004%-2.362.620.28861N:0.004%~0.04%2.8340N:>0.04%0.50-0.0880.295-0.35955H:<0.0002%6.92-0.4886.2192H:0.0002%~0.0005%0.28-2.44-3.33-0.34596H:>0.0005%-5.00-0.133-0.8212.63CHNCHN模式单位E脲示值误差（%）0.0450.0630.077单位G脲示值误差（%）6.363.16相对相差（%）98.696.191.6单位E对氨基苯磺酸示值误差（%）0.0570.0010.005单位G对氨基苯磺酸示值误差（%）3.090.025相对相差（%）92.0-99.9-66.7单位E乙酰苯胺示值误差（%）0.0650.0230.035单位G乙酰苯胺示值误差（%）2.50.936相对相差（%）89.498.292.8定结果，计算相对相差，其中大部分结果相对相差YSBC11026-2015各元素测量值单位C含量S含量10.0022860.008125%20.0024600.008213%30.0022700.008098%40.0022570.008285%50.0020730.008217%60.0022330.008314%70.0021720.008014%重复性5.24%YSBC19226-2000各元素测量值单位%C含量S含量10.439070.05280%20.440630.05242%30.439340.05260%40.436870.05295%50.440990.05333%60.440010.05234%70.439330.05302%重复性0.3070.668%钢502-863各元素测量值单位C含量S含量10.042200.01284%20.041800.01356%30.041970.01317%40.041980.01331%50.042540.01348%60.041900.01325%70.041770.01308%重复性0.639%钢铁BH1314-1G08MnPRE各元素测量值单位C含量S含量10.0921130.010995%20.0914530.010947%30.0914510.010938%40.0921740.011009%50.0921150.010854%60.0918340.010900%70.0920530.011120%重复性0.7850.342%GBW(E)020209YSBS20602-2008各元素测量值单位ONH10.0030220.0057660.000338%20.0030130.0056310.000340%30.0033020.0056770.000346%40.0030420.0055090.000308%50.0030160.0056210.000348%60.0031070.0057940.000338%70.0029750.0055790.000335%重复性3.603.88%GBW(E)020280各元素测量值单位ONH10.0072470.0358330.000409%20.0074150.0363670.00041%30.0072550.0362820.000393%40.0073240.0363210.000394%50.0072810.0368690.000405%60.0073110.0364980.000401%70.0074030.0361210.000395%重复性0.9180.880%钢503-537各元素测量值单位ONH10.01090.06770.000657%20.01120.06930.000685%30.01080.06800.000644%40.01120.06850.000672%50.01100.06770.000703%60.01100.06890.000647%70.01190.06760.000651%重复性3.270.983.31%GSB03-1065-1999YSBS35312-2016各元素测量值单位ONH10.0064650.0165190.000284%20.006540.0168390.000295%30.0065610.0167790.000308%40.006590.0165450.000284%50.0065840.0164650.000294%60.0066190.0165660.000294%70.006670.0164830.000293%重复性0.9770.8932.76%对氨基苯磺酸各元素测量值单位CHNS141.5254.0928.05818.310%241.7754.0668.09118.476%341.5514.0388.02718.533%441.6194.0898.01318.505%541.4694.0988.02218.575%641.6474.0998.02718.652%741.6864.0438.03918.617%重复性0.2500.6390.3340.608%对氨基苯磺酸各元素测量值单位CHNS141.654.078.09241.684.088.10341.704.088.04441.744.088.10541.694.068.09641.674.068.08741.624.068.08重复性（RSD）0.0910.2450.2540.138对氨基苯磺酸各元素测量值单位O126.409%226.373%326.714%426.784%526.453%626.576%726.574%重复性0.582%各元素测量值单位CHN141.163.998.13%241.023.938.09%341.013.938.05%43.938.22%540.933.90%641.073.92%741.083.898.15%重复性0.1940.8150.654%测试元素碳硫元素分析仪重复性（%）变异系数（%）单位A单位B单位C单位DC5.240.3070.6390.785S0.6680.34264测试元素氧氮氢元素分析仪重复性（%）变异系数（%）单位A单位B单位C单位DO0.9180.9183.270.97766N0.880.880.980.89338H3.312.7630测试元素碳氢氮硫氧元素分析仪重复性（%）变异系数%相对相差%单位E单位F单位GC0.250.0910.19445H0.6390.2450.81552N0.3340.2540.65451S0.6080.13863O0.582氧元素分析仪皆具备可行性。根据表2.13SBC11026-2015C峰面积信号值C进样量（mg）S峰面积信号值S进样量（mg）18.1191.120246.3854.1754428.671.126626.5044.1992238.0341.114086.3224.1524847.9651.109026.4534.1336257.6266.6234.2656467.8691.104186.4474.1155877.8421.130366.3514.21316灵敏度7.1520251811.54116422检测器类型红外红外YSBC19226-2000C峰面积信号值C进样量（mg）S峰面积信号值S进样量（mg）1180.4287654175.60417.3328273221.15232181.0698223175.73617.2080834921.16823180.5397175174.46017.2671726821.01454179.5247107175.64817.3820683121.15765181.2177585175.16417.5068121421.09936180.8150433175.07617.1818216321.08877180.5356082176.00017.4050474421.2000灵敏度1.0296939420.820150006检测器类型红外红外钢502-863C峰面积信号C进样量（mg）S峰面积信号S进样量(mg)1290042657228704269332670426834267042691527104270062670426887266042679灵敏度65.1360544251.85064935检测器类型红外红外序号C峰面积信号C进样量（mg）S峰面积信号S进样量（mg）10.0474047.17760.005085.640820.0463646.46920.004985.556130.0470247.13160.005045.635340.0490048.73240.005255.826750.0468546.62560.004955.574860.0460946.00920.004915.501170.0470946.89240.005105.6067灵敏度0.0010020.000897检测器类型红外红外GBW(E)020209YSBS20602-2008O峰面积信号值O进样量N峰面积信号值N进样量H峰面积信号值H进样129.0743.315767.6706.203680.37761228.9283.309567.4646.192080.37715331.7743.311427.5326.195560.37729429.1993.308637.2906.190340.37779528.9783.312357.4576.19730.37808629.8513.310187.6946.193240.37783728.5943.313597.4006.199620.37811灵敏度8.903611.2106194.69089检测器类型红外TCD红外GBW(E)020280O峰面积信号值O进样N峰面积信号值N进样量（mg）H峰面积信号值H进样量121.0967.7756.33637.819.9170.4305221.5857.7757.17537.819.9660.4305321.1197.7757.04237.819.1270.4305421.3207.7757.10337.819.1870.4305521.1957.7757.96537.819.7220.4305621.2827.7757.38137.819.5030.4305721.5507.7756.78937.819.2390.4305灵敏度2.7421768711.510925945.34959检测器类型红外TCD红外钢503-537O峰面积信号O进样量N峰面积信号N进样量H峰面积信号H进样量15.9267.739.60.6926.0767.741.40.6935.9467.738.70.6945.9967.740.60.6955.9267.742.70.6966.0367.738.90.6975.9267.739.10.69灵敏度129.987130.08818316158.17805383检测器类型红外热导红外GSB03-1065-1999O峰面积0进样量N峰面积N进样量H峰面积H进样量YSBS35312-2016信号信号信号132.2296.7226.0950.304516.1490.3045232.3036.7226.4460.30450.3045332.3826.7226.5170.304515.7710.3045432.1616.7226.1880.304516.1820.3045532.0726.7225.9300.304516.4220.3045632.4206.7226.2360.304516.2920.3045733.0296.7225.9160.304516.2090.3045灵敏度4.81710286.00908752.608971检测器类型红外TCD红外C峰面积信号值C进样H峰面积信号值H进样量N峰面积信号值N进样量积信号值S进样量11850150.5691589940.0558144520.1107355130.253522306570.7051727100.0691175940.1372445880.314032141160.6581673710.0645164080.1280416970.293142196200.6739698610.0660167380.1311426490.300152335630.7192747620.0705177770.1399457460.320362155570.6610686970.0648164740.1286421580.294471927960.5908605060.05790.1149375220.2631灵敏度325810.34251054147.995128515.6586142158.7112检测器类型TCDTCDTCDTCDC峰面积信号值C进样H峰面积信号值H进样N峰面积信号值N进样积信号值S进样1253790.905081270.088570190.176051090.40262257800.918382570.089871550.178552010.40853252550.899680820.088069410.174950780.40024254100.904281280.088470320.175851170.40225257380.916782070.089771310.178251950.40786250720.893879860.087469280.173850560.39767257490.918782240.089971370.178652070.4087灵敏度28063.8043591696.6482939926.2382812718.47387检测器类型TCDTCDTCDTCDC峰面积信号值C进样量H峰面积信号值H进样量N峰面积信号值N进样量127.01533.3048.1463.2616.474227.05433.3468.0243.2656.482327.01133.3048.0123.26110.9866.474427.05933.3468.0023.2656.482527.00233.3877.9503.2696.490627.04033.2628.0253.2576.466727.00333.3047.9483.2616.474灵敏度0.8110640912.4567026331.735310006检测器类型红外红外TCDO峰面积信号值O进样量（mg）1751140.41392729710.41793794350.43664785500.43075720930.39566707110.38927705360.3863灵敏度180991.8检测器类型TCD元素检测器类型碳硫元素分析仪灵敏度变异系数单位A单位B单位C单位DC红外7.1520251.029693965.1360540.001002S红外1.54116420.8201551.8506490.000897元素检测器类型氧氮氢元素分析仪灵敏度变异系数单位A单位B单位C单位DO红外8.903612.742177129.98714.817102NTCD1.2106191.5109260.088183286.009087H红外4.6908945.3495958.17805452.60897160元素碳氢氮硫氧元素分析仪检测器类型单位E仪器灵敏度单位F单位G仪器灵敏度相对相差%CTCD325810.328063.804HTCD105414891696.648NTCD128515.739926.23853STCD142158.712718.474OTCD180991.8C红外0.8110641H红外2.4567026N红外1.73531CHNS灵敏度325810.34251054147.995128515.6586142158.7112基线噪声18.8415524.8729925.3918223.96098最小检测量（mg）0.0001730.0000710.0005930.000506检测器类型TCDTCDTCDTCDO灵敏度180991.7883基线噪声25.06495最小检测量（mg）0.000415检测器类型TCDC峰面积S峰面积13.4100.00423.4770.02733.2500.00043.7060.00053.4840.00163.6110.02773.4020.01983.6150.00093.4210.0144.5750.0293.7680.013标准偏差0.35321灵敏度7.1520251811.54116422检出限(mg)0.148检测器类型红外红外C峰面积S峰面积10.042030.0298320.010150.0454830.011280.0334640.050800.0139350.012240.0130060.012630.0233970.069170.0227480.013520.0504790.014800.016360.014640.026330.012210.02620标准偏差0.019970.01205灵敏度1.0296939420.820150006检出限(mg)0.0580.044检测器类型红外红外C峰面积S峰面积10.50320.54130.62940.46450.48860.370.060680.26990.7360.825标准偏差0.32灵敏度65.1360544251.85064935检出限(mg)0.0570.019检测器类型红外红外C峰面积S峰面积10.000020.0000520.000010.0000530.000010.0000440.000010.0000750.000010.0000460.000020.0000970.000010.0000580.000010.0000690.000010.000120.000010.000040.000020.00005标准偏差0.0000050.000025灵敏度0.0010020.000897检出限（mg）0.0160.083检测器类型红外红外O峰面积N峰面积H峰面积10.0000.0350.04420.0000.0000.01730.0060.0240.01440.0000.0000.03750.0000.0030.02660.0000.0070.02870.0090.0240.01880.0380.0000.02990.0000.0000.0160.0000.0010.0210.0000.0110.030标准偏差0.01140.01250.0094灵敏度8.903611.2106194.69089检出限(mg)0.00380.03100.0060检测器类型红外TCD红外O峰面积N峰面积H峰面积10.01380.00780.005920.01400.02140.006730.01220.00510.009740.01230.00470.004150.01570.00150.003060.02340.00510.010070.01260.01320.007080.01240.00630.002490.01300.00630.00560.01270.00270.00760.01360.00150.0093标准偏差0.0032280.0058340.002601灵敏度2.742176871.51092645.34959检出限(mg)0.00350.01160.0002检测器类型红外TCD红外O峰面积N峰面积H峰面积158.20.0001254.60.00040.525343.30.00110.363440.00.0014543.90.0002643.60.00032.07746.30.00200.649854.70.0007955.40.00152.6958.30.00100.96245.20.00100.652标准偏差6.820.00060.75灵敏度129.987130.08818316158.17805383检出限(mg)0.15740.02040.0387检测器类型红外TCD红外O峰面积N峰面积H峰面积10.05940.01290.012920.06590.01660.017330.05030.03010.017640.07170.01550.010750.05760.01230.017660.06560.00980.016570.06160.00520.013980.06380.00550.019890.06800.00810.01800.06250.00340.01360.06160.00350.0146标准偏差0.0056690.0078020.002712灵敏度4.81710286.00908752.608971检出限(mg)0.003530.0002720.000155检测器类型红外TCD红外C峰面积H峰面积N峰面积S峰面积143575824241555724341605426441644221534494523636485774145528354050936415125394459394347标准偏差3.00308.15205.63913.1392灵敏度28063.8043591696.6482939926.2382812718.47387检出限(mg)0.0003210.0002670.0004240.000741检测器类型TCDTCDTCDTCDCHN10.35080.09561.330220.34000.11851.557630.32330.09201.393440.31550.08941.335650.32230.08341.404860.32700.07641.254270.32280.09211.243580.32520.06981.264190.32580.09051.31670.30980.06861.25700.33220.09431.0977标准偏差0.01120.01390.1165灵敏度0.8110640912.4567026331.735310006检出限(mg)0.0410.0170.201检测器类型红外红外TCD碳硫元素分析仪检出限（mg）变异系数%元素检测器类型单位A单位B单位C单位DC红外0.1480.0580.0570.016S红外0.0230.0440.0190.08369元素检测器类型氧氮氢元素分析仪检出限（mg）变异系数%单位A单位B单位C单位DO红外0.00380.00350.15740.00353NTCD0.0310.01160.02040.000272H红外0.0060.00020.03870.000155碳氢氮硫氧元素分析仪元素检测器类型单位F仪器检出限元素检测器类型单位G仪器检出限CTCD0.000321C红外0.041HTCD0.000267H红外0.017NTCD0.000424N红外0.201STCD0.000741A单位B单位C单位D单位开始时间09:14:2112:43:2409:47:51结束时间09:27:3612:53:0609:56:40运行总时间(s)795582900529测量时间(s)76A单位B单位C单位D单位开始时间16:11:0013:46:4714:15:17结束时间16:34:0514:18:5114:47:42运行总时间(s)2460测量时间(s)275351278E单位F单位开始时间结束时间运行总时间(s)46203420测量时间(s)660489G单位开始时间结束时间运行总时间(s)3125测量时间(s)446E单位开始时间6:1