过氧化氢催化氧化处理含氯酚废水的研究_图文

1、 36 华东理工大学学报 第 24 卷 参 考 文 献 1Fen ton H J H. O x idation of tartaric acid in p resence of iron. J Chem Soc, 1894, 65: 899 905 2E isenhau ser H R. O x idation of p heno lic w aste. J W ater Po ll Con tro l Fed, 1964, 36 (9 : 1 116 1 128 3E isenhau ser H R. Chem ical rem oval of ABS from w astew ater e

2、ffluen ts. J W ater Po ll Con tro l Fed, 1965, 37 (11 : 1 567 1 577 4 B iho rp D F , Stern G. H yd rogen p erox ide catalytic ox idation of refracto ry o rgan ic in m un icip al w astew ater. Ind Eng 117 Chem P ro D esign D ev, 1968, 7: 110 5Sed lak D L , A nd ren A W. O x idation of ch lo robenzene

3、 w ith Fen tons reagen t. Environ Sci T echno l, 1991, 25: 777 782 6 . T he ox idation of alcoho ls by Fen tons reagen t. J Am Chem Soc, 1971, 93 (17 : 4 275 4 281 W alling C, Kato S I 7 W alling C, Gam il M , Jobn son R A. Fen tons reagen t I V. Structu re and reactivity relation s in the reaction

4、s of hyd roxyl 139 rad icals and the redox reaction s of rad icals. J Am Chem Soc, 1974, 96 (1 : 130 8 N o rm an R O C, P ritchett R J. E lectron sp in resonance stud ies p art X I . H yd ro lytic fragm en tation s of hyd roxycyclo 2 930 hexad ienyl rad icals. J Chem Sci B , 1967, 926 9 J efcoate C

5、R E, L ind say S J R , N o rm an R O C. H yd roxylation p art I V. O x idation of som e benzeno id com pound s by 1 018 Fen tons reagen t and the u ltravio let irrad iation of hyd rogen p erox ide. J Chem Sci B , 1969, 1 013 10 N o rm an R O C, Sto rey P M. O x idative fragm en tation of p henylacet

6、ic acid and related com pound s induced by som e 1 106 oxygen 2con tain ing rad icals. J Chem Sci B , 1970, 1 099 11Barb W G. R eaction s of ferrou s and ferric ion s w ith hyd rogen p erox ide. T ran s Faraday Soc, 1951, 47 (3 : 463 500 12 W ells C F , Salam M A. A k inetic app roach to nayu re of

7、ferrou s ion s in aqueou s so lu tion. N atu re, 1964, 203 (4 946 : 751 752 13 M offett J W , Zike R G. R eaction k inetics of hyd rogen p erox ide w ith copp er and iron in seaw ater. Environ Sci T echno l, 1987, 21 (8 : 804 810 14A rdon M. O xygen. N ew Yo rk: Ben jam in W A Inc, 1965, 86 93 15 L

8、ou J C, L ee S S. Chem ical ox idation of BTX u sing Fen tons reagen t. H azW aste & H azM ater, 1995, 12 (2 : 185 193 Trea tm en t of Chlorophenol-Con ta in ing W a stewa ter by Ca ta lyzed O x ida tion w ith Hydrogen Perox ide L u J un , L iu Z haojun , T an F ux ian and W ang L i 3 (D ep a rt

9、m en t of E ng ergy R esou rces C hem ica l T echnology ECU S T , S hang ha i 200237 Abstract: In th is p ap er, ch lo rop heno l w a s selected a s m odel com pound sub jected to ox i2 2+ 3+ da t ion u sing hyd rogen p erox ide w ith iron ion (Fe o r Fe a s ca ta ly st. T est resu lt s ind ica t2 e

10、d tha t hyd rogen p erox ide w a s decom po sed in to hyd roxy l rad ica l w ith iron ion s a s ca ta ly st. D isso lved ch lo rop heno l can be effect ively ox id ized and com p letely rem oved from aqueou s so 2 . A n average COD low ering of over 80% w a s ob 2 lu t ion in a p eriod less than ten m inu tes ta ined. T he am oun t s of H 2O 2、 Fe . m ova l of ch lo rop heno l 2+ o r Fe 3