微量元素地球化学中国地质大学4微量元素在不同地质体中的分布与分配ppt课件

1、4. 4. 微量元素在各主要地质体中微量元素在各主要地质体中的分布的分布 矿物矿物岩石岩石地球化学储库地球化学储库主要造岩矿物n橄榄石n单斜辉石n斜方辉石n石榴石n尖晶石n斜长石橄榄石橄榄石Kd Database Search ResultsRock TypeMineralZElementValueKd TypeReferenceBasaltOlivine3Li0.35ExperimentalNikogosian & Sobolev 2019BasaltOlivine12Mg6.6ExperimentalKloeck & Palme 1988BasaltOlivine22Ti0

2、.007ExperimentalNikogosian & Sobolev 2019BasaltOlivine24Cr0.73ExperimentalNikogosian & Sobolev 2019BasaltOlivine26Fe1.85ExperimentalKloeck & Palme 1988BasaltOlivine27Co3.1ExperimentalPaster et al. 1974BasaltOlivine28Ni12.2Phenocrysts-MatrixBougault & Hekinian 1974BasaltOlivine30Zn0.8

3、6Phenocrysts-MatrixBougault & Hekinian 1974BasaltOlivine37Rb0.04Phenocrysts-MatrixVillemant et al. 1981BasaltOlivine39Y0.009ExperimentalNikogosian & Sobolev 2019BasaltOlivine40Zr0.06Phenocrysts-MatrixVillemant et al. 1981BasaltOlivine56Ba0.03Phenocrysts-MatrixVillemant et al. 1981BasaltOlivi

4、ne57La0.0004CalculatedMcKenzie & ONions 1991BasaltOlivine58Ce0.01ExperimentalPaster et al. 1974BasaltOlivine59Pr0.0008CalculatedMcKenzie & ONions 1991BasaltOlivine62Sm0.0013CalculatedMcKenzie & ONions 1991BasaltOlivine63Eu0.0016CalculatedMcKenzie & ONions 1991BasaltOlivine65Tb0.0015C

5、alculatedMcKenzie & ONions 1991BasaltOlivine66Dy0.007ExperimentalNikogosian & Sobolev 2019BasaltOlivine67Ho0.0016CalculatedMcKenzie & ONions 1991BasaltOlivine69Tm0.009Phenocrysts-MatrixFrey 1969BasaltOlivine70Yb0.021ExperimentalNikogosian & Sobolev 2019BasaltOlivine71Lu0.018Phenocrys

6、ts-MatrixFrey 1969BasaltOlivine72Hf0.04Phenocrysts-MatrixVillemant et al. 1981BasaltOlivine73Ta0.03Phenocrysts-MatrixVillemant et al. 1981BasaltOlivine79Au0.7ExperimentalKloeck & Palme 19880.0010.010.1110100100010000Li7Al27Si29P31Ca42Sc45Ti49V51Cr53Co59Ni60Cu63Ga71Rb85Sr88Y89Zr90Nb93Cs133Ba137La

7、139Ce140Pr141Nd143Sm147Eu151Gd155Tb159Dy163Ho165Er166Tm169Yb173Lu175Hf179Ta181Pb208Th232U238含量 （ppm）0.00010.0010.010.1110Li Sc V Cr Co Ni CuGa Rb Sr Y Zr Nb CsBa La Ce Pr NdSmEuGd Tb DyHo Er TmYb Lu Hf Ta Pb Th U原始地幔归一化值Kd Database Search ResultsRock TypeMineralZElementValueKd TypeReferenceBasaltLow

8、 Calcium Pyroxene3Li0.26Phenocrysts-MatrixMatsui et al. 1977BasaltLow Calcium Pyroxene22Ti0.786Phenocrysts-MatrixMatsui et al. 1977BasaltLow Calcium Pyroxene24Cr4.22Phenocrysts-MatrixMatsui et al. 1977BasaltLow Calcium Pyroxene28Ni1.1ExperimentalMysen 1978BasaltLow Calcium Pyroxene30Zn0.41Phenocryst

9、s-MatrixMatsui et al. 1977BasaltLow Calcium Pyroxene37Rb0.0006CalculatedMcKenzie & ONions 1991BasaltLow Calcium Pyroxene38Sr0.002Phenocrysts-Matrix / ExpKeleman & Dunn 1992BasaltLow Calcium Pyroxene40Zr0.02Phenocrysts-Matrix / ExpKeleman & Dunn 1992BasaltLow Calcium Pyroxene41Nb0.003Phen

10、ocrysts-Matrix / ExpKeleman & Dunn 1992BasaltLow Calcium Pyroxene56Ba0.0035Phenocrysts-MatrixMatsui et al. 1977BasaltLow Calcium Pyroxene57La0.0005Phenocrysts-Matrix / ExpKeleman & Dunn 1992BasaltLow Calcium Pyroxene58Ce0.001Phenocrysts-Matrix / ExpKeleman & Dunn 1992BasaltLow Calcium Py

11、roxene59Pr0.0048CalculatedMcKenzie & ONions 1991BasaltLow Calcium Pyroxene60Nd0.382Phenocrysts-MatrixMatsui et al. 1977BasaltLow Calcium Pyroxene62Sm0.01CalculatedMcKenzie & ONions 1991BasaltLow Calcium Pyroxene63Eu0.013CalculatedMcKenzie & ONions 1991BasaltLow Calcium Pyroxene64Gd0.82Ph

12、enocrysts-MatrixMatsui et al. 1977BasaltLow Calcium Pyroxene65Tb0.019CalculatedMcKenzie & ONions 1991BasaltLow Calcium Pyroxene66Dy0.022CalculatedMcKenzie & ONions 1991BasaltLow Calcium Pyroxene67Ho0.026CalculatedMcKenzie & ONions 1991BasaltLow Calcium Pyroxene68Er0.03CalculatedMcKenzie

13、& ONions 1991BasaltLow Calcium Pyroxene69Tm1.09Phenocrysts-MatrixMatsui et al. 1977BasaltLow Calcium Pyroxene70Yb0.049CalculatedMcKenzie & ONions 1991BasaltLow Calcium Pyroxene71Lu0.06CalculatedMcKenzie & ONions 1991BasaltLow Calcium Pyroxene72Hf0.01CalculatedMcKenzie & ONions 1991Ba

14、saltLow Calcium Pyroxene82Pb0.0013CalculatedMcKenzie & ONions 1991BasaltLow Calcium Pyroxene90Th0.013Phenocrysts-MatrixMatsui et al. 1977BasaltLow Calcium Pyroxene92U0.017Phenocrysts-MatrixMatsui et al. 19770.00010.0010.010.1110100100010000Li ScV Cr Co Ni Cu Ga Rb SrYZr Nb Cs Ba La Ce Pr Nd Sm E

15、u Gd Tb Dy Ho Er Tm Yb Lu Hf Ta Pb Th U含量 （ppm）0.0010.010.1110100Li Sc V Cr Co Ni Cu Ga Rb Sr Y Zr Nb Cs Ba La Ce Pr NdSmEuGd Tb Dy Ho Er TmYb Lu Hf Ta Pb Th U原始地幔归一化值Rock TypeMineralZElementValueKd TypeReferenceBasaltClinopyroxene4Be0.047ExperimentalHart & Dunn 1993BasaltClinopyroxene5B0.036Exp

16、erimentalHart & Dunn 1993BasaltClinopyroxene19K0.0072ExperimentalHart & Dunn 1993BasaltClinopyroxene21Sc0.808ExperimentalHauri et al. 1994BasaltClinopyroxene22Ti0.229ExperimentalSobolev et al. 2019BasaltClinopyroxene23VExperimentalHauri et al. 1994BasaltClinopyroxene24CrExperimentalHauri et

17、al. 1994BasaltClinopyroxene25MnExperimentalPaster et al. 1974BasaltClinopyroxene27CoExperimentalPaster et al. 1974BasaltClinopyroxene28NiExperimentalMysen 1978BasaltClinopyroxene29Cu0.36ExperimentalHart & Dunn 1993BasaltClinopyroxene30Zn0.49ExperimentalPaster et al. 1974BasaltClinopyroxene31Ga0.

18、74ExperimentalHart & Dunn 1993BasaltClinopyroxene38Sr0.082ExperimentalSobolev et al. 2019BasaltClinopyroxene39Y0.245ExperimentalSobolev et al. 2019BasaltClinopyroxene40Zr0.046ExperimentalSobolev et al. 2019BasaltClinopyroxene41Nb0.004ExperimentalJohnson 1994BasaltClinopyroxene55Cs0.0058Experimen

19、talHauri et al. 1994BasaltClinopyroxene56Ba0.002ExperimentalSobolev et al. 2019BasaltClinopyroxene57La0.032ExperimentalSobolev et al. 2019BasaltClinopyroxene58Ce0.057ExperimentalSobolev et al. 2019BasaltClinopyroxene59Pr0.277ExperimentalHauri et al. 1994BasaltClinopyroxene60Nd0.129ExperimentalSobole

20、v et al. 2019BasaltClinopyroxene61Pm0.462ExperimentalHauri et al. 1994BasaltClinopyroxene62Sm0.211ExperimentalSobolev et al. 2019BasaltClinopyroxene63Eu0.27ExperimentalPaster et al. 1974BasaltClinopyroxene64Gd0.41ExperimentalPaster et al. 1974BasaltClinopyroxene65Tb0.711ExperimentalHauri et al. 1994

21、BasaltClinopyroxene66Dy0.256ExperimentalSobolev et al. 20190.0010.010.1110100100010000Li Sc V Cr Co Ni Cu Ga Rb Sr Y Zr Nb Cs Ba La Ce Pr NdSmEuGd Tb DyHo Er TmYb Lu Hf Ta Pb Th U含量 （ppm）0.0000.0010.0100.1001.00010.000LiScVCr CoNi Cu Ga RbSrYZr Nb Cs Ba La CePr Nd Sm Eu Gd Tb Dy HoEr Tm Yb LuHfTa Pb

22、 ThU原始地幔归一化值原始地幔归一化值Kd Database Search ResultsRock TypeMineralZElementValueKd TypeReferenceBasaltGarnet21Sc2.62ExperimentalHauri et al. 1994BasaltGarnet22Ti0.688ExperimentalHauri et al. 1994BasaltGarnet23V1.48ExperimentalHauri et al. 1994BasaltGarnet24Cr2.01ExperimentalHauri et al. 1994BasaltGarnet2

23、8Ni5.1ExperimentalMysen 1978BasaltGarnet38Sr0.0099ExperimentalHauri et al. 1994BasaltGarnet39Y2.8ExperimentalJohnson 1994BasaltGarnet40Zr2.12ExperimentalHauri et al. 1994BasaltGarnet41Nb0.0538ExperimentalHauri et al. 1994BasaltGarnet56Ba0.0007ExperimentalHauri et al. 1994BasaltGarnet57La0.0164Experi

24、mentalHauri et al. 1994BasaltGarnet58Ce0.065ExperimentalHauri et al. 1994BasaltGarnet60Nd0.363ExperimentalHauri et al. 1994BasaltGarnet62Sm1.1ExperimentalHauri et al. 1994BasaltGarnet63Eu2.02ExperimentalHauri et al. 1994BasaltGarnet66Dy4.13ExperimentalHauri et al. 1994BasaltGarnet68Er3.95Experimenta

25、lHauri et al. 1994BasaltGarnet70Yb3.88ExperimentalHauri et al. 1994BasaltGarnet71Lu3.79ExperimentalHauri et al. 1994BasaltGarnet72Hf1.22ExperimentalHauri et al. 1994BasaltGarnet82Pb0.00012ExperimentalHauri et al. 1994BasaltGarnet90Th0.00137ExperimentalHauri et al. 1994BasaltGarnet92U0.00588Experimen

26、talHauri et al. 1994石榴石石榴石0.010.1110Li Sc V Cr Co Ni CuGa原始地幔归一化值Rb Sr Y Zr NbCsBa La Ce Pr NdSmEuGd Tb DyHo ErTmYb Lu Hf Ta Pb Th U石榴石石榴石0.0010.010.1110100Li Sc V Cr Co Ni CuGa Rb Sr Y Zr Nb CsBa La Ce Pr NdSmEu Gd Tb Dy Ho ErTmYb Lu Hf Ta Pb Th U原始地幔归一化值Figure 13-1. After Minster et al. (1974) Geo

27、phys. J. Roy. Astr. Soc., 36, 541-576. Figure 14-6. After Zindler and Hart (1986), Staudigel et al. (1984), Hamelin et al. (1986) and Wilson (1989). Figure 15-1. Columbia River Basalts at Hat Point, Snake River area. Cover of Geol. Soc. Amer Special Paper 239. Photo courtesy Steve Reidel.Table 15-1.

28、 Major Flood Basalt ProvincesNameVolumeAgeLocalityCRB(1.7x105 km3)MioceneNW USKeeweenawan(4x105 km3)PrecambrianSuperior areaDeccan(106 km3)Cret.-EoceneIndiaParana(area 106 km2) early Cret.BrazilKarroo(2x106 km3?)early JurassicS. AfricaFigure 15-14. Diagrammatic cross section illustrating possible mo

29、dels for the development of continental flood basalts. DM is the depleted mantle (MORB source reservoir), and the area below 660 km depth is the less depleted, or enriched OIB source reservoir. Winter (20190 An Introduction to Igneous and Metamorphic Petrology. Prentice Hall.Figure 16-1. Principal s

30、ubduction zones associated with orogenic volcanism and plutonism. Triangles are on the overriding plate. PBS = Papuan-Bismarck-Solomon-New Hebrides arc. After Wilson (1989) Igneous Petrogenesis, Allen Unwin/Kluwer.Figure 16-2. Schematic cross section through a typical island arc after Gill (1981), O

31、rogenic Andesites and Plate Tectonics. Springer-Verlag. HFU= heat flow unit (4.2 x 10-6 joules/cm2/sec)Raw materialsOceanic materialMantle materialProductsMagma/VolcanoesVolatilesContinental crustResiduesChemically modified slabDelaminated lower crustMaterial Recycling in the Earth InteriorContinental crust LaCe PrNdSmEuG