EP7.0滴定液配制与标定

1、Volumetricsolutions:Hydrochloricacid盐酸滴定液1MHydrochloricacid:Dilute103.0gofhydrochloricacidRto1000.0mlwithwaterR.称取103.0g盐酸至1000ml量瓶中，加水稀释至刻度。Standardisation:Dissolve1.000gofsodiumcarbonateRVin50mlofwaterR,add0.1mLofmethylorangesolutionRandtitratewiththehydrochloricaciduntilthesolutionjustbecomesyell

2、owish-red.Boilfor2min.Thesolutionrevertstoyellow.Coolandcontinuethetitrationuntilayellowish-redcolourisobtained.1mLof1Mhydrochloricacidisequivalentto53.00mgofNa2CO3.标定：称取1.000g基准无水碳酸钠溶解于50ml水中，加0.1ml甲基橙溶液，用盐酸滴定液滴定至溶液出现黄红色。煮沸2分钟。溶液变成黄色。冷却至室温，继续滴定至溶液由黄色变成黄红色。每1mL盐酸滴定液（1mol/L）相当于53.00mg无水碳酸钠。0.1MHydroc

3、hloricacid:Dilute100.0mLof1Mhydrochloricacidto1000.0mLwithwaterR.量取100ml1mol/L盐酸滴定液至1000ml量瓶中，加水稀释至刻度。Standardisation.Carryoutthetitrationdescribedfor1Mhydrochloricacidusing0.100gofsodiumcarbonateRVdissolvedin20mLofwaterR.1mLof0.1MHydrochloricacidisequivalentto5.30mgofNa2CO3.标定：按标定1mol/L盐酸滴定液进行，称取0.

4、100g无水碳酸钠溶于20ml水中。每1ml0.1mol/l盐酸滴定液相当于5.30mg碳酸钠。0.01MHydrochloricacid:Dilute10.0mLof1Mhydrochloricacidto1000.0mLwithwaterR.量取10.0mL1mol/L盐酸滴定液并用水稀释至1000.0mL.Standardisation.Sodiumhydroxide氢氧化钠滴定液1Msodiumhydroxide:1mol/L氢氧化钠滴定液Dissolve42gofsodiumhydroxideRincarbondioxide-freewaterRanddiluteto1000.0mL

5、withthesamesolvent.称取42g氢氧化钠，加去二氧化碳水稀释至1000.0mlStandardisation.Titrate20.0mLofthesodiumhydroxidesolutionwith1Mhydrochloricacidusingtheindicatorprescribedintheassayinwhich1Msodiumhydroxideisused.标定：量取20.0ml氢氧化钠溶液，用1mol/L盐酸滴定液标定。使用酚酞指示液指示终点。0.1MSodiumhydroxide:Dilute100.0mLof1Msodiumhydroxideto1000.0m

6、Lwithcarbondioxide-freewaterR.量取1mol/L氢氧化钠滴定液100.0mL，用去二氧化碳水稀释至1000.0mL。Standardisation.Titrate20.0mLofthesodiumhydroxidesolutionwith0.1Mhydrochloricacid,usingtheend-pointdetectionprescribedfortheassayinwhichthe0.1Msodiumhydroxideisused.标定：量取20.0mL氢氧化钠溶液，用0.1mol/L盐酸滴定液滴定。用0.01Msodiumhydroxide:0.02Ms

7、odiumhydroxide:Sulfuricacid硫酸滴定液0.5MSulfuricacid:Dissolve28mLofsulfuricacidRinwaterRanddiluteto1000.0mLwiththesamesolvent.量取硫酸溶液28mL，缓慢加入水中，并用水稀释至lOOOmL。Standardisation.Dissolve1.000gofsodiumcarbonateRVin50mLofwaterR,add0.1mLofmethylorangesolutionR,andtitratewiththesulfuricaciduntilthesolutionbegins

8、toturnreddish-yellow.Boilforabout2min.Thecolourofthesolutionsrevertstoyellow.Coolandtitrateagainuntilthereddish-yellowcolourreappears.标定。称取l.OOOg无水碳酸钠溶于50mL水中，加O.lmL甲基橙试液，用硫酸滴定液滴定至溶液出现红黄色。煮沸2分钟。溶液颜色变黄。冷却至室温，继续滴定至红黄色出现。lmLof0.5Msulfuricacidisequivalentto53.00mgofNa2CO3.每lmL0.5mol/L硫酸滴定液相当于53.00mg无水碳酸

9、钠。0.05MSulfuricacid:Dilutel00.0mLof0.5Msulfuricacidtol000.0mLwithwaterR.量取100.0mL0.5mol/L硫酸滴定液，加水稀释至lOOO.OmL.Standardisation.Carryoutthetitrationdescribedfor0.5Msulfuricacid,using0.l00gofsodiumcarbonateRV,dissolvedin20mLofwaterR,标定：按标定0.5mol/L硫酸滴定液进行标定，称取氢氧化钠O.lOOg溶于20mL水中。lmLof0.05Msulfuricacidiseq

10、uivalentto5.30mgofNa2CO3.0.1MSilvernitrate0.1mol/L硝酸银滴定液Dissolvel7.0gofsilvernitrateRinwaterRanddilutetol000.0mLwiththesamesolvent.称取l7.0g硝酸银溶于水中，并用水稀释至lOOO.OmLStandardisation.Dissolve0.l00gofsodiumchlorideRVin30mLofwaterR.Titratewiththesilvernitratesolution,determiningtheend-pointpotentiometrically

11、(2.2.2O).标定：称取O.lOOg氯化钠溶于30mL水中。用硝酸银溶液滴定，用电位滴定法(2220)指示终点。lmLof0.1Msilvernitrateisequivalentto5.844mgofNaCl.没lmLO.lmol/L硝酸银滴定液相当于5.844mg氯化钠。Storage:protectedfromlight.贮存：避光保存。0.1MSodiumedetateDissolve37.5gofsodiumedetateRin500mLofwaterR,add100mLof1Msodiumhydroxideanddiluteto1000.0mLwithwaterR.称取37.5

12、g乙二胺四乙酸二钠溶于500mL水中，加入lmol/L氢氧化钠滴定液100mL并用水稀释至1000.0mL.Standardisation.Dissolve0.120gofzincRVin4mLofhydrochloricacidR1andadd0.1mLofbrominewaterR.Driveofftheexcessofbrominebyboiling,adddilutesodiumhydroxidesolutionRuntilthesolutionisweaklyacidorneutralandcarryouttheassayofzincbycomplexometry(2.5.11)标定

13、：量取0.120g基准锌溶于4mL盐酸溶液R1，加入O.lmL溴水。1mLof0.1Msodiumedentateisequivalentto6.54mgofZn.Storage:inapolyethylenecontainer.贮存：聚乙烯瓶0.1MZincsulfate0.1mol/L硫酸锌滴定液:Dissolve29gofzincsulfateRinwaterRanddiluteto1000.0mLwiththesamesolvent.称取29g硫酸锌溶于水中，用水稀释至lOOO.OmL.Standardisation.To20.0mLofthezincsulfatesolutionad

14、d5mLofdiluteaceticacidRandcarryoutthedeterminationofzincbycomplexometry(2.5.11)标定：量取20.0mL硫酸锌溶液，并往其加入5mL稀醋酸，用配位滴定法(2.5.11)指示终点。Sodiumthiosulfate硫代硫酸钠滴定液0.1MSodiumthiosulfate：Dissolve25gofsodiumthiosulfateRand0.2gofsodiumcarbonateRincarbondioxide-freewaterRanddiluteto1000.0mLwiththesamesolvent.称取25g硫

15、代硫酸钠和0.2g碳酸钠溶于去二氧化碳水中，并用去二氧化碳水稀释至1000.0mL.Standardisation.To10.0mLof0.033Mpotassiumbromate,add40mLofwaterR,10mLofpotassiumiodidesolutionRand5mLofhydrochloricacidR1.Titratewiththesodiumthiosulfatesolution,using1mLofstarchsolutionR,addedtowardstheendofthetitration,asindicator.标定：量取10.0mL0.033mol/L溴酸钾滴

16、定液，加入40mL水，10mL碘化钾溶液和5mL盐酸。用硫代硫酸钠标定，并用1mL淀粉溶液作为指示剂滴定终点。0.05MSodiumthiosulfate:0.05MIodine碘滴定液：Dissolve12.7gofiodineRand20gofpotassiumiodideRinwaterRanddiluteto1000.0mLwiththesamesolvent.称取12.7g碘和20g碘化钾溶于水中，并用水稀释至1000.0mL.Standardisation.To20.0mLoftheiodinesolutionadd1mLofdiluteaceticacidRand30mLofwa

17、terR.Titratewith0.1Msodiumthiosulfate,usingstarchsolutionRasindicator.标定：量取20.0mL碘滴定液，加入1mL稀醋酸和30mL水。用0.1mol/L硫代硫酸钠滴定液标定，用淀粉溶液作为指示剂。Storage:protectedfromlight.贮存：避光保存。0.1MAmmoniumandceriumnitrate0.1mol/L硝酸铈铵滴定液:Shakefor2minasolutioncontaining56mLofsulfuricacidRand54.82gofammoniumandceriumnitrateR,ad

18、dfivesuccessivequantities,eachof100mL,ofwaterR,shakingaftereachaddition.Dilutetheclearsolutionto1000.0mLwithwaterR.Standardisethesolutionafter10days.Standardisation.To25.0mLoftheammoniumandceriumnitratesolutionadd2.0gofpotassiumiodideRand150mLofwaterR.Titrateimmediatelywith0.1Msodiumthiosulfate,using1mLofstarchsolutionRasindicator.Storage:protectedfromlight.0.02MPotassiumpermangana