【《金属有机框架的设计与合成方法研究文献综述》2800字】

金属有机框架的设计与合成方法研究文献综述目录TOC\o"1-3"\h\u209金属有机框架的设计与合成方法研究文献综述 197811.1金属有机框架的合成方法 1290111.2有机配体的选择 2自金属有机框架材料问世以来，就受到了学术界的广泛关注，每年都有成千上万的新的金属有机框架材料被合成出来。金属有机框架材料的合成过程可以看做是金属离子和有机配体的自组装过程，这个自组装过程可以分为两种，一种是通过有机配体与金属离子配位直接形成不同空间维度的金属有机框架；另一种则是通过分子间作用力（例如范德华力、氢键、π-π堆积等作用力）间接使低维的材料自组装成高维的框架材料ADDINEN.CITE<EndNote><Cite><Author>杜旭</Author><Year>2014</Year><RecNum>77</RecNum><DisplayText><styleface="superscript">[24]</style></DisplayText><record><rec-number>77</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621110955">77</key></foreign-keys><ref-typename="Thesis">32</ref-type><contributors><authors><author>杜旭</author></authors></contributors><titles><title>新型含氮杂环配体配合物的合成,结构及性质研究</title></titles><dates><year>2014</year></dates><publisher>河北联合大学</publisher><urls></urls></record></Cite></EndNote>[24]。1.1金属有机框架的合成方法金属有机框架材料经历了几十年的发展，已经形成了一系列相对成熟的合成方法与途径。MOFs经典的合成方法有扩散法和水热-溶剂热法ADDINEN.CITE<EndNote><Cite><Author>Li</Author><Year>1999</Year><RecNum>80</RecNum><DisplayText><styleface="superscript">[17]</style></DisplayText><record><rec-number>80</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621111868">80</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Li,H.L.</author><author>Eddaoudi,M.M.</author><author>O'Keeffe,M.</author><author>Yaghi,O.M.</author></authors></contributors><titles><title>DesignandSynthesisofanExceptionallyStableandHighlyPorousMetal-OrganicFramework</title><secondary-title>Nature</secondary-title></titles><periodical><full-title>Nature</full-title></periodical><volume>402</volume><number>6759</number><dates><year>1999</year></dates><urls></urls></record></Cite></EndNote>[17]，而随着对MOFs研究的深入，科学家们又探索出微波法ADDINEN.CITE<EndNote><Cite><Author>Ahn</Author><Year>2008</Year><RecNum>78</RecNum><DisplayText><styleface="superscript">[25]</style></DisplayText><record><rec-number>78</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621111606">78</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Ahn,Kws</author></authors></contributors><titles><title>Metal–organicframeworkMOF-5preparedbymicrowaveheating:Factorstobeconsidered</title><secondary-title>MicroporousandMesoporousMaterials</secondary-title></titles><periodical><full-title>MicroporousandMesoporousMaterials</full-title></periodical><dates><year>2008</year></dates><urls></urls></record></Cite></EndNote>[25]、超声法ADDINEN.CITE<EndNote><Cite><Author>Bhattacharjee</Author><Year>2010</Year><RecNum>79</RecNum><DisplayText><styleface="superscript">[26]</style></DisplayText><record><rec-number>79</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621111737">79</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Bhattacharjee,S.</author><author>Choi,JungSik</author><author>Yang,SeungTae</author><author>Choi,S.B.</author><author>Kim,J.</author><author>Ahn,WhaSeung</author></authors></contributors><titles><title>SolvothermalSynthesisofFe-MOF-74andItsCatalyticPropertiesinPhenolHydroxylation</title><secondary-title>JournalofNanoscienceandNanotechnology</secondary-title></titles><periodical><full-title>JournalofNanoscienceandNanotechnology</full-title></periodical><pages>135-141</pages><volume>10</volume><number>1</number><dates><year>2010</year></dates><urls></urls></record></Cite></EndNote>[26]、机械混合法ADDINEN.CITE<EndNote><Cite><Author>Klimakow</Author><Year>2010</Year><RecNum>170</RecNum><DisplayText><styleface="superscript">[27]</style></DisplayText><record><rec-number>170</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621124145">170</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Klimakow,M.</author><author>Klobes,P.</author><author>AFThüNemann</author><author>Rademann,K.</author><author>Emmerling,F.</author></authors></contributors><titles><title>MechanochemicalSynthesisofMetal−OrganicFrameworks:AFastandFacileApproachtowardQuantitativeYieldsandHighSpecificSurfaceAreas</title><secondary-title>ChemistryofMaterials</secondary-title></titles><periodical><full-title>ChemistryofMaterials</full-title></periodical><pages>5216-5221</pages><volume>22</volume><number>18</number><dates><year>2010</year></dates><urls></urls></record></Cite></EndNote>[27]、电化学法ADDINEN.CITE<EndNote><Cite><Author>Ameloot</Author><Year>2009</Year><RecNum>83</RecNum><DisplayText><styleface="superscript">[28]</style></DisplayText><record><rec-number>83</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621112028">83</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Ameloot,R.</author><author>Stappers,L.</author><author>Fransaer,J.</author><author>Alaerts,L.</author><author>Sels,B.F.</author><author>DeVos,DirkE.</author></authors></contributors><titles><title>PatternedGrowthofMetal-OrganicFrameworkCoatingsbyElectrochemicalSynthesis</title><secondary-title>ChemistryofMaterials</secondary-title></titles><periodical><full-title>ChemistryofMaterials</full-title></periodical><pages>2580-2582</pages><volume>21</volume><number>13</number><dates><year>2009</year></dates><urls></urls></record></Cite></EndNote>[28]等新型合成方法，为MOFs的结构多样化与功能多样化奠定了基础。表1.1常见的MOFs合成方法合成方法具体内容扩散法扩散法是指将有机配体与金属离子通过扩散在中间层慢慢反应，从而合成MOFs晶体的方法。水热-溶剂热法水热-溶剂热法是指通过在密闭容器中产生高温高压的反应条件，从而使常规条件下不溶或难溶的反应物生成溶解产物，并在升温-恒温-降温的过程中逐渐析出MOFs晶体的方法。微波法微波法是指通过使反应在微波加热的条件下进行，从而加剧分子热运动，增加反应物分子的碰撞机率，从而反应生成MOFs晶体的方法。超声法超声法是指让反应在超声条件下进行，从而能够快速合成MOFs晶体的方法。机械混合法机械混合法是指在无溶剂的条件下，将配合物与金属混合均匀并研磨的从而反应得到MOFs材料的方法。电化学法电化学法是在常温常压条件下，通过利用电解池合成MOFs材料的方法。本文主要采用了水热-溶剂热法来制备MOFs，在160℃到170℃的反应温度下，将反应物置于拥有较高沸点的极性溶剂（例如水、N,N-二甲基甲酰胺等溶剂）中混合，通过有机配体与金属离子的自组装得到具有新颖结构的MOFs材料。1.2有机配体的选择随着对金属有机框架材料研究的深入，人们发现影响MOFs合成与结构的因素有很多，例如有机配体、金属离子，反应温度，pH，反应物浓度，溶剂等因素ADDINEN.CITEADDINEN.CITE.DATA[29-33]。因此，我们需要不断地实验尝试探索和总结合成MOFs的最佳反应条件，从而能通过对这些影响因素的调控来合成具有新颖结构和预期性质的金属有机框架材料。其中，有机配体是金属有机框架的自组装过程中最重要的影响因素之一，它不仅对MOFs的结构起着决定性作用还对MOFs的功能产生影响ADDINEN.CITE<EndNote><Cite><Author>He</Author><Year>2019</Year><RecNum>92</RecNum><DisplayText><styleface="superscript">[34]</style></DisplayText><record><rec-number>92</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621114495">92</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>He,Z.</author><author>Zhao,X.</author><author>Pan,X.</author><author>YLi</author><author>Xu,Z.</author></authors></contributors><titles><title>LigandgeometrycontrollingZn-MOFpartialstructuresfortheircatalyticperformanceinKnoevenagelcondensation</title><secondary-title>RSCAdvances</secondary-title></titles><periodical><full-title>RSCAdvances</full-title></periodical><pages>25170-25176</pages><volume>9</volume><number>43</number><dates><year>2019</year></dates><urls></urls></record></Cite></EndNote>[34]。因此，科学家们通过精心选择和设计有机配体从而实现MOFs的结构调控与功能设计ADDINEN.CITE<EndNote><Cite><Author>Liu</Author><Year>2020</Year><RecNum>93</RecNum><DisplayText><styleface="superscript">[35]</style></DisplayText><record><rec-number>93</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621114591">93</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Liu,X.</author><author>Zhang,L.</author><author>Wang,J.</author></authors></contributors><titles><title>DesignStrategiesforMOF-derivedPorousFunctionalMaterials:PreservingSurfacesandNurturingPores</title><secondary-title>JournalofMateriomics</secondary-title></titles><periodical><full-title>JournalofMateriomics</full-title></periodical><volume>7</volume><number>3</number><dates><year>2020</year></dates><urls></urls></record></Cite></EndNote>[35]。有机配体在配位过程中提供孤对电子，金属离子提供空轨道，因此有机配体需要有两个或两个以上的给电子基团与金属离子形成配位共价键。有机配体含有的不同种类的配原子使得它与不同金属的亲和力不同，而其配原子的个数以及角度则决定了有机配体的配位数与配位方式。所以，有机配体的官能团种类、官能团的数目以及有机配体本身的结构等因素，对MOFs最终的结构与性质都有着很大影响。由于含有N，O等杂原子的有机配体具有较强的供电子能力，含氮杂环类配体ADDINEN.CITEADDINEN.CITE.DATA[36]以及羧酸类配体ADDINEN.CITE<EndNote><Cite><Author>Mallick</Author><Year>2020</Year><RecNum>94</RecNum><DisplayText><styleface="superscript">[37]</style></DisplayText><record><rec-number>94</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621114807">94</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Mallick,A.</author><author>Liang,H.</author><author>Shekhah,O.</author><author>Jia,J.</author><author>Mouchaham,G.</author><author>Shkurenko,A.</author><author>Belmabkhout,Y.</author><author>Alshareef,H.N.</author><author>Eddaoudi,M.</author></authors></contributors><auth-address>FunctionalMaterialsDesign,DiscoveryandDevelopmentResearchGroup(FMD3),AdvancedMembranesandPorousMaterialsCenter(AMPMC),DivisionofPhysicalSciencesandEngineering(PSE),KingAbdullahUniversityofScienceandTechnology(KAUST),Thuwal23955-6900,KingdomofSaudiArabia.mohamed.eddaoudi@.sa. MaterialsScienceandEngineering,DivisionofPhysicalSciencesandEngineering(PSE),KingAbdullahUniversityofScienceandTechnology(KAUST),Thuwal23955-6900,KingdomofSaudiArabia.husam.alshareef@.sa.</auth-address><titles><title>Made-to-orderporouselectrodesforsupercapacitors:MOFsembeddedwithredox-activecentersasacasestudy</title><secondary-title>ChemCommun(Camb)</secondary-title></titles><periodical><full-title>ChemCommun(Camb)</full-title></periodical><pages>1883-1886</pages><volume>56</volume><number>12</number><edition>2020/01/18</edition><dates><year>2020</year><pub-dates><date>Feb11</date></pub-dates></dates><isbn>1364-548X(Electronic) 1359-7345(Linking)</isbn><accession-num>31951225</accession-num><urls><related-urls><url>/pubmed/31951225</url></related-urls></urls><electronic-resource-num>10.1039/c9cc08860a</electronic-resource-num></record></Cite></EndNote>[37]受到了科学家们的青睐，并在此基础上合成了许多结构新颖、性能优异的MOFs材料。含氮杂环类配体氮原子容易与过渡金属离子进行配位，因此含氮杂环类配体经常用于与过渡金属配位从而构筑MOFs材料。常见的含氮杂环类配体有三氮唑及其衍生物、咪唑类、吡唑类等ADDINEN.CITEADDINEN.CITE.DATA[36]。但由于氮原子与过渡金属桥连角度较小，导致含氮杂环与过渡金属配位方式较为简单，往往生成一些低维的MOFs材料。此外，由于含氮杂环类配体一般为中性配体，其形成的金属有机框架结构的稳定性较差。因此，科学家们经常使用含氮原子较多的杂环配体（例如三氮唑、四氮唑等）ADDINEN.CITE<EndNote><Cite><Author>Liu</Author><Year>2016</Year><RecNum>99</RecNum><DisplayText><styleface="superscript">[38,39]</style></DisplayText><record><rec-number>99</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621115302">99</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Liu,J.</author><author>FWang</author><author>Ding,Q.R.</author><author>Zhang,J.</author></authors></contributors><titles><title>SynthesisofanEnantipureTetrazole-BasedHomochiralCuI,II-MOFforEnantioselectiveSeparation</title><secondary-title>InorganicChemistry</secondary-title></titles><periodical><full-title>InorganicChemistry</full-title></periodical><pages>12520</pages><dates><year>2016</year></dates><urls></urls></record></Cite><Cite><Author>Mariyam</Author><Year>2019</Year><RecNum>100</RecNum><record><rec-number>100</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621115367">100</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Mariyam,A.</author><author>Shahid,M.</author><author>Mantasha,I.</author><author>Khan,M.S.</author><author>Ahmad,M.S.</author></authors></contributors><titles><title>TetrazoleBasedPorousMetalOrganicFramework(MOF):TopologicalAnalysisandDyeAdsorptionProperties</title><secondary-title>JournalofInorganicandOrganometallicPolymersandMaterials</secondary-title></titles><periodical><full-title>JournalofInorganicandOrganometallicPolymersandMaterials</full-title></periodical><pages>1-9</pages><dates><year>2019</year></dates><urls></urls></record></Cite></EndNote>[38,39]，通过含氮杂环类配体的多齿配位来丰富配位模式。而且科学家们还通过在含氮杂环上修饰上苯环或者直链烃基，得到了具有柔性的含氮杂环类配体，这样的配体既增加了配位点又使配体更加灵活，有利于配位生成具有新颖结构的高维MOFs材料ADDINEN.CITEADDINEN.CITE.DATA[40-42]。羧酸类配体羧酸类配体很早就被用于合成MOFs材料，其丰富的配位方式，良好的成簇能力以及较高的配位键能使得其更易于形成多维的网络结构，且形成的网络结构也更加稳定。而且羧酸类配体还具备延展性，所以可以通过调节有机配体的长度从而实现对MOFs材料的孔洞进行调控ADDINEN.CITE<EndNote><Cite><Author>Mallick</Author><Year>2020</Year><RecNum>94</RecNum><DisplayText><styleface="superscript">[37]</style></DisplayText><record><rec-number>94</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621114807">94</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Mallick,A.</author><author>Liang,H.</author><author>Shekhah,O.</author><author>Jia,J.</author><author>Mouchaham,G.</author><author>Shkurenko,A.</author><author>Belmabkhout,Y.</author><author>Alshareef,H.N.</author><author>Eddaoudi,M.</author></authors></contributors><auth-address>FunctionalMaterialsDesign,DiscoveryandDevelopmentResearchGroup(FMD3),AdvancedMembranesandPorousMaterialsCenter(AMPMC),DivisionofPhysicalSciencesandEngineering(PSE),KingAbdullahUniversityofScienceandTechnology(KAUST),Thuwal23955-6900,KingdomofSaudiArabia.mohamed.eddaoudi@.sa. MaterialsScienceandEngineering,DivisionofPhysicalSciencesandEngineering(PSE),KingAbdullahUniversityofScienceandTechnology(KAUST),Thuwal23955-6900,KingdomofSaudiArabia.husam.alshareef@.sa.</auth-address><titles><title>Made-to-orderporouselectrodesforsupercapacitors:MOFsembeddedwithredox-activecentersasacasestudy</title><secondary-title>ChemCommun(Camb)</secondary-title></titles><periodical><full-title>ChemCommun(Camb)</full-title></periodical><pages>1883-1886</pages><volume>56</volume><number>12</number><edition>2020/01/18</edition><dates><year>2020</year><pub-dates><date>Feb11</date></pub-dates></dates><isbn>1364-548X(Electronic) 1359-7345(Linking)</isbn><accession-num>31951225</accession-num><urls><related-urls><url>/pubmed/31951225</url></related-urls></urls><electronic-resource-num>10.1039/c9cc08860a</electronic-resource-num></record></Cite></EndNote>[37]。羧酸类配体包括脂肪酸和芳香酸，其中脂肪酸柔性较强难于形成金属有机框架，所以常用的羧酸类配体以芳香酸为主，例如对苯二甲酸，均苯三甲酸等ADDINEN.CITE<EndNote><Cite><Author>Adams</Author><Year>2010</Year><RecNum>105</RecNum><DisplayText><styleface="superscript">[43,44]</style></DisplayText><record><rec-number>105</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621115828">105</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Adams,R.</author><author>Carson,C.</author><author>Ward,J.</author><author>Tannenbaum,R.</author><author>Koros,W.</author></authors></contributors><titles><title>Metalorganicframeworkmixedmatrixmembranesforgasseparations</title><secondary-title>Microporous&MesoporousMaterials</secondary-title></titles><periodical><full-title>Microporous&MesoporousMaterials</full-title></periodical><pages>13-20</pages><volume>131</volume><number>1-3</number><dates><year>2010</year></dates><urls></urls></record></Cite><Cite><Year>2009</Year><RecNum>106</RecNum><record><rec-number>106</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621115845">106</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors></contributors><titles><title>PreparationandEnhancedHydrostabilityandHydrogenStorageCapacityofCNT@MOF-5HybridComposite</title><secondary-title>ChemistryofMaterials</secondary-title></titles><periodical><full-title>ChemistryofMaterials</full-title></periodical><pages>1893</pages><volume>21</volume><number>9</number><dates><year>2009</year></dates><urls></urls></record></Cite></EndNote>[43,44]。含氮羧酸类配体目前，含氮杂环类配体与羧酸类配体均在MOFs材料的合成中的得到了广泛地应用ADDINEN.CITE<EndNote><Cite><Author>A</Author><Year>2013</Year><RecNum>108</RecNum><DisplayText><styleface="superscript">[45]</style></DisplayText><record><rec-number>108</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621115982">108</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>A,LiZhuangChen</author><author>A,DengDengHuang</author><author>B,JiaZhenGe</author><author>A,FangMingWang</author></authors></contributors><titles><title>AnovelAg(I)coordinationpolymersbasedon2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylicacid:Syntheses,structures,ferroelectric,dielectricandopticalproperties</title><secondary-title>InorganicaChimicaActa</secondary-title></titles><periodical><full-title>InorganicaChimicaActa</full-title></periodical><pages>95-99</pages><volume>406</volume><number>9</number><dates><year>2013</year></dates><urls></urls></record></Cite></EndNote>[45]。科学家们通过将含氮杂环或含氮基团引入羧酸类配体中，形成了兼具两者优点的含氮羧酸类配体。这种配体有着含氮配体与羧酸配体的配位能力，丰富了有机配体的配位方式使得形成的MOFs材料结构更加多样，而且还可以使结构功能化从而赋予MOFs材料特殊的性质。利用含氮羧酸类配体制备的MOFs材料已被大量报道，目前常见的含氮羧酸类配体有咪唑二羧酸ADDINEN.CITE<EndNote><Cite><Author>Cai</Author><Year>2012</Year><RecNum>109</RecNum><DisplayText><styleface="superscript">[46]</style></DisplayText><record><rec-number>109</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621116018">109</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Cai,S.L.</author><author>Zheng,S.R.</author><author>Wen,Z.Z.</author><author>Fan,J.</author><author>Zhang,W.G.</author></authors></contributors><titles><title>AssemblyofChiral/AchiralCoordinationPolymersBasedon2-(Pyridine-3-yl)-1H-4,5-imidazoledicarboxylicAcid:ChiralityTransferbetweenChiralTwo-DimensionalNetworksContainingHelicalChains</title><secondary-title>CrystalGrowth&Design</secondary-title></titles><periodical><full-title>CrystalGrowth&Design</full-title></periodical><pages>2355–2361</pages><volume>12</volume><number>5</number><dates><year>2012</year></dates><urls></urls></record></Cite></EndNote>[46]、吡唑二羧酸ADDINEN.CITE<EndNote><Cite><Author>Beatty</Author><Year>2015</Year><RecNum>110</RecNum><DisplayText><styleface="superscript">[47]</style></DisplayText><record><rec-number>110</rec-number><foreign-keys><keyapp="EN"db-id="vvzttaaz9e2rw8ef59c5ttaspv0vaaet5tdf"timestamp="1621116062">110</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Beatty,A.M.</author><author>Granger,K.E.</author><author>Simpson,A.E.</author></authors></contributors><titles><title>Crystalengineeringoforganicclaymimicsfrom3,5-pyrazoledicarboxylicacidandamines</title><secondary-title>Chemistry–AEuropeanJournal</secondary-title></titles><periodical><full-title>Chemistry–AEuropeanJournal</full-title></periodical><pages>3254-3259</pages><volume>8</volume><number>14</number><dates><year>2015</year></dates><urls></urls></record></Cite></EndNote>[47]等。参考文献[1]Furukawa,H.;Cordova,K.E.;O'Keeffe,M.;Yaghi,O.M.,Thechemistryandapplicationsofmetal-organicframeworks[J].Science,2013,341(6149):974.[2]凌平华.金属有机框架复合物的纳米组装,仿生催化与生物传感[D].南京大学,2016.[3]Liu,J.;Chen,L.;Cui,H.;Zhang,J.;Zhang,L.;Su,C.Y.,Applicationsofmetal-organicframeworksinheterogeneoussupramolecularcatalysis[J].ChemicalSocietyReviews,2014.[4]Islamoglu;Timur;Snurr;Randall;Q.;Hupp;Joseph;T.;Farha;Omar,Metal-organicframeworksfortheremovaloftoxicindustrialchemicalsandchemicalwarfareagents[J].ChemicalSocietyReviews,2017.[5]Chughtai,A.H.;Ahmad,N.;Younus,H.A.;Laypkov,A.;Verpoort,F.,Metal-organicframeworks:versatileheterogeneouscatalystsforefficientcatalyticorganictransformations[J].ChemicalSocietyReviews,2015,46(46):6804-6849.[6]Gassensingusingporousmaterialsforautomotiveapplications[J].ChemicalSocietyReviews,2015,44.[7]Yue,D.;Wang,Y.;Chen,D.;Wang,Z.,Solventtriggeringstructuralchangesfortwoterbium-basedmetal-organicframeworksandtheirphotoluminescencesensing[J].ChemCommun(Camb),2020,56(31):4320-4323.[8]Wang,Y.;Zhang,K.;Wang,X.;Xin,X.;Zhang,X.;Fan,W.;Xu,B.;Dai,F.;Sun,D.,Accuratetuningofrareearthmetal–organicframeworkswithunprecedentedtopologyforwhite-lightemission[J].JournalofMaterialsChemistryC,2020,8(4):1374-1379.[9]Zhao,Y.;Li,D.,Lanthanide-functionalizedmetal–organicframeworksasratiometricluminescentsensors[J].JournalofMaterialsChemistryC,2020,8(37):12739-12754.[10]Stavila,V.;Talin,A.A.;Allendorf,M.,MOF-basedelectronicandopto-electronicdevices[J].ChemicalSocietyReviews,2014,43(16):5994-6010.[11]Simon-Yarza,T.;Mielcarek,A.;Couvreur,P.;Serre,C.,NanoparticlesofMetal-OrganicFrameworks:OntheRoadtoInVivoEfficacyinBiomedicine[J].AdvMater,2018,30(37):e1707365.[12]郭明明.基于新型刚性含氮配体的金属有机骨架材料合成与性能研究[D].长春师范大学,2019.[13]耿爱净.基于刚性芳香羧酸配体MOFs的设计、合成与性能研究[D].聊城大学,2014.[14]刘康.含氮配体构筑金属有机骨架化合物的合成、结构与性质研究[D].吉林大学.[15]Hoskins,B.F.;Robson,R.,Infinitepolymericframeworksconsistingofthreedimensionallylinkedrod-likesegments[J].JournaloftheAmericanChemicalSociety,1989,111(15):5962-5964.[16]Yaghi,O.M.;Li,H.,HydrothermalSynthesisofaMetal-OrganicFrameworkContainingLargeRectangularChannels[J].JournaloftheAmericanChemicalSociety,1995,117(41):10