【氧化石墨烯水泥基复合材料国内外研究现状的文献综述3800字】

氧化石墨烯水泥基复合材料国内外研究现状的文献综述目录TOC\o"1-3"\h\u22126氧化石墨烯水泥基复合材料国内外研究现状的文献综述 1155371.1对和易性的影响 1190101.2对力学性能和耐久性能的影响 2178481.3对微观结构的影响 3305361.4对智能/多功能特性的影响 4氧化石墨烯（GO）是一种二维片层状纳米材料，由石墨烯高度氧化生成，具有以六方晶格状排列的sp2杂化碳原子形成的蜂窝状结构ADDINEN.CITE<EndNote><Cite><Author>Compton</Author><Year>2010</Year><RecNum>233</RecNum><DisplayText><styleface="superscript">[59]</style></DisplayText><record><rec-number>233</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1649061692">233</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Compton,OwenC.</author><author>Nguyen,SonBinhT.</author></authors></contributors><titles><title>GrapheneOxide,HighlyReducedGrapheneOxide,andGraphene:VersatileBuildingBlocksforCarbon-BasedMaterials</title><secondary-title>Small</secondary-title></titles><periodical><full-title>Small</full-title></periodical><pages>711-723</pages><volume>6</volume><number>6</number><keywords><keyword>composites</keyword><keyword>graphene</keyword><keyword>grapheneoxide</keyword><keyword>thinfilms</keyword></keywords><dates><year>2010</year><pub-dates><date>2010/03/22</date></pub-dates></dates><publisher>JohnWiley&Sons,Ltd</publisher><isbn>1613-6810</isbn><work-type>/10.1002/smll.200901934</work-type><urls><related-urls><url>/10.1002/smll.200901934</url></related-urls></urls><electronic-resource-num>/10.1002/smll.200901934</electronic-resource-num><access-date>2022/04/04</access-date></record></Cite></EndNote>[59]。理想的GO具有纳米级（小于10nm）单片层厚度，大量的含氧官能团分布在GO片层的表面和边缘，一方面增强了片层间的范德华力，扩大了GO片层间距，促进GO在水中的分散并改善其亲水性，另一方面能够为水泥基材料的水化反应提供反应位点，促进水化反应。1.1对和易性的影响和易性是影响到新拌水泥砂浆运输和泵送施工的关键，而GO表面的含氧官能团会吸收水分，同时GO较大的比表面积需要更多的水来润湿表面，所以在给定水灰比下会减少润滑所需要的自由水含量，因此会严重降低水泥砂浆的流动性。LvSADDINEN.CITE<EndNote><Cite><Author>Lv</Author><Year>2014</Year><RecNum>202</RecNum><DisplayText><styleface="superscript">[60]</style></DisplayText><record><rec-number>202</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647829919">202</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Lv,Shenghua</author><author>Liu,Jingjing</author><author>Sun,Ting</author><author>Ma,Yujuan</author><author>Zhou,Qingfang</author></authors></contributors><titles><title>EffectofGOnanosheetsonshapesofcementhydrationcrystalsandtheirformationprocess</title><secondary-title>ConstructionandBuildingMaterials</secondary-title></titles><periodical><full-title>ConstructionandBuildingMaterials</full-title></periodical><pages>231-239</pages><volume>64</volume><keywords><keyword>Cement</keyword><keyword>Hydrationreaction</keyword><keyword>Hydrationcrystals</keyword><keyword>Formationprocess</keyword></keywords><dates><year>2014</year><pub-dates><date>2014/08/14/</date></pub-dates></dates><isbn>0950-0618</isbn><urls><related-urls><url>/science/article/pii/S095006181400378X</url></related-urls></urls><electronic-resource-num>/10.1016/j.conbuildmat.2014.04.061</electronic-resource-num></record></Cite></EndNote>[60]研究了GO对水泥砂浆流动性的影响，坍落度测试结果表明，随着GO掺量的增加，砂浆流动性明显下降，最高下降52.3%，此时GO掺量为0.05%。GongK等人ADDINEN.CITE<EndNote><Cite><Author>Gong</Author><Year>2015</Year><RecNum>203</RecNum><DisplayText><styleface="superscript">[61]</style></DisplayText><record><rec-number>203</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647830163">203</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Gong,Kai</author><author>Pan,Zhu</author><author>KorayemAsghar,H.</author><author>Qiu,Ling</author><author>Li,Dan</author><author>Collins,Frank</author><author>WangChien,Ming</author><author>DuanWen,Hui</author></authors></contributors><titles><title>ReinforcingEffectsofGrapheneOxideonPortlandCementPaste</title><secondary-title>JournalofMaterialsinCivilEngineering</secondary-title></titles><periodical><full-title>JournalofMaterialsinCivilEngineering</full-title></periodical><pages>A4014010</pages><volume>27</volume><number>2</number><dates><year>2015</year><pub-dates><date>2015/02/01</date></pub-dates></dates><publisher>AmericanSocietyofCivilEngineers</publisher><urls><related-urls><url>/10.1061/(ASCE)MT.1943-5533.0001125</url></related-urls></urls><electronic-resource-num>10.1061/(ASCE)MT.1943-5533.0001125</electronic-resource-num><access-date>2022/03/20</access-date></record></Cite></EndNote>[61]通过最小坍落度测试发现，在水灰比为0.5时，掺入0.03%GO的砂浆坍落度降低了34.6%。与此相似的是，在相同的水灰比下，PanZADDINEN.CITE<EndNote><Cite><Author>Pan</Author><Year>2015</Year><RecNum>204</RecNum><DisplayText><styleface="superscript">[62]</style></DisplayText><record><rec-number>204</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647830253">204</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Pan,Zhu</author><author>He,Li</author><author>Qiu,Ling</author><author>Korayem,AsgharHabibnejad</author><author>Li,Gang</author><author>Zhu,JunWu</author><author>Collins,Frank</author><author>Li,Dan</author><author>Duan,WenHui</author><author>Wang,MingChien</author></authors></contributors><titles><title>Mechanicalpropertiesandmicrostructureofagrapheneoxide–cementcomposite</title><secondary-title>CementandConcreteComposites</secondary-title></titles><periodical><full-title>CementandConcreteComposites</full-title></periodical><pages>140-147</pages><volume>58</volume><keywords><keyword>Grapheneoxide</keyword><keyword>Portlandcement</keyword><keyword>Compressivestrength</keyword><keyword>Flexuralstrength</keyword><keyword>Microstructure</keyword></keywords><dates><year>2015</year><pub-dates><date>2015/04/01/</date></pub-dates></dates><isbn>0958-9465</isbn><urls><related-urls><url>/science/article/pii/S0958946515000207</url></related-urls></urls><electronic-resource-num>/10.1016/j.cemconcomp.2015.02.001</electronic-resource-num></record></Cite></EndNote>[62]进行了坍落度测试，结果表明当GO掺量为0.05%时，水泥砂浆的和易性降低了41.7%。ShangYADDINEN.CITE<EndNote><Cite><Author>Shang</Author><Year>2015</Year><RecNum>206</RecNum><DisplayText><styleface="superscript">[63]</style></DisplayText><record><rec-number>206</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647831037">206</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Shang,Yu</author><author>Zhang,Dong</author><author>Yang,Chao</author><author>Liu,Yanyun</author><author>Liu,Yong</author></authors></contributors><titles><title>Effectofgrapheneoxideontherheologicalpropertiesofcementpastes</title><secondary-title>ConstructionandBuildingMaterials</secondary-title></titles><periodical><full-title>ConstructionandBuildingMaterials</full-title></periodical><pages>20-28</pages><volume>96</volume><keywords><keyword>Grapheneoxide</keyword><keyword>Grapheneoxideencapsulatedsilicafume</keyword><keyword>Cement</keyword><keyword>Rheologicalproperties</keyword></keywords><dates><year>2015</year><pub-dates><date>2015/10/15/</date></pub-dates></dates><isbn>0950-0618</isbn><urls><related-urls><url>/science/article/pii/S0950061815302038</url></related-urls></urls><electronic-resource-num>/10.1016/j.conbuildmat.2015.07.181</electronic-resource-num></record></Cite></EndNote>[63]发现GO会显著影响水泥砂浆的流变性能，增加了浆体的稠度和黏度，水泥砂浆的流动性随着GO掺量的提高而下降，在GO掺量为0.08%时最高降低了36.2%，屈服应力值和塑性黏度分别增加了311.3%和132.1%。WangMADDINEN.CITE<EndNote><Cite><Author>Wang</Author><Year>2016</Year><RecNum>207</RecNum><DisplayText><styleface="superscript">[64]</style></DisplayText><record><rec-number>207</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647831171">207</key><keyapp="ENWeb"db-id="">0</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Wang,Min</author><author>Wang,Rumin</author><author>Yao,Hao</author><author>Wang,Zhujun</author><author>Zheng,Shuirong</author></authors></contributors><titles><title>Adsorptioncharacteristicsofgrapheneoxidenanosheetsoncement</title><secondary-title>RSCAdvances</secondary-title></titles><periodical><full-title>RSCAdvances</full-title></periodical><pages>63365-63372</pages><volume>6</volume><number>68</number><section>63365</section><dates><year>2016</year></dates><isbn>2046-2069</isbn><urls></urls><electronic-resource-num>10.1039/c6ra10902k</electronic-resource-num></record></Cite></EndNote>[64]研究了GO在水泥中的吸附特性和其对流动性的影响，发现GO在水泥中的吸附能力较强，且随GO掺量的增加而提高，吸附能力的增强对水泥砂浆和易性有着不良影响。LiXADDINEN.CITE<EndNote><Cite><Author>Li</Author><Year>2018</Year><RecNum>205</RecNum><DisplayText><styleface="superscript">[65]</style></DisplayText><record><rec-number>205</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647830969">205</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Li,Xiangyu</author><author>Li,Chenyang</author><author>Liu,Yanming</author><author>Chen,ShuJian</author><author>Wang,C.M.</author><author>Sanjayan,JayG.</author><author>Duan,WenHui</author></authors></contributors><titles><title>Improvementofmechanicalpropertiesbyincorporatinggrapheneoxideintocementmortar</title><secondary-title>MechanicsofAdvancedMaterialsandStructures</secondary-title></titles><periodical><full-title>MechanicsofAdvancedMaterialsandStructures</full-title></periodical><pages>1313-1322</pages><volume>25</volume><number>15-16</number><dates><year>2018</year><pub-dates><date>2018/12/10</date></pub-dates></dates><publisher>Taylor&Francis</publisher><isbn>1537-6494</isbn><urls><related-urls><url>/10.1080/15376494.2016.1218226</url></related-urls></urls><electronic-resource-num>10.1080/15376494.2016.1218226</electronic-resource-num></record></Cite></EndNote>[65]研究了GO对水泥净浆和水泥砂浆流动性的影响，结果发现，掺入0.04%的GO后，水泥净浆的流动性降低了24.4%，而水泥砂浆的流动性仅降低了7.8%。1.2对力学性能和耐久性能的影响抗折强度和抗压强度是评价水泥基材料力学性能的关键指标，也是水泥基材料最主要的研究方向。大量研究表明，GO的掺入可以调控水化产物生长和排布，起到增强增韧的水泥基材料的效果。PanZADDINEN.CITE<EndNote><Cite><Author>Pan</Author><Year>2015</Year><RecNum>204</RecNum><DisplayText><styleface="superscript">[62]</style></DisplayText><record><rec-number>204</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647830253">204</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Pan,Zhu</author><author>He,Li</author><author>Qiu,Ling</author><author>Korayem,AsgharHabibnejad</author><author>Li,Gang</author><author>Zhu,JunWu</author><author>Collins,Frank</author><author>Li,Dan</author><author>Duan,WenHui</author><author>Wang,MingChien</author></authors></contributors><titles><title>Mechanicalpropertiesandmicrostructureofagrapheneoxide–cementcomposite</title><secondary-title>CementandConcreteComposites</secondary-title></titles><periodical><full-title>CementandConcreteComposites</full-title></periodical><pages>140-147</pages><volume>58</volume><keywords><keyword>Grapheneoxide</keyword><keyword>Portlandcement</keyword><keyword>Compressivestrength</keyword><keyword>Flexuralstrength</keyword><keyword>Microstructure</keyword></keywords><dates><year>2015</year><pub-dates><date>2015/04/01/</date></pub-dates></dates><isbn>0958-9465</isbn><urls><related-urls><url>/science/article/pii/S0958946515000207</url></related-urls></urls><electronic-resource-num>/10.1016/j.cemconcomp.2015.02.001</electronic-resource-num></record></Cite></EndNote>[62]等人采用GO增强水泥净浆的力学性能，研究发现，GO在较低的掺量下即可对水泥净浆实现较高程度的增强效果，GO的最佳掺量为0.05%，抗折强度和抗压强度分别提升41%~58%和15%~33%。张亚娟ADDINEN.CITE<EndNote><Cite><Author>张亚娟</Author><Year>2016</Year><RecNum>210</RecNum><DisplayText><styleface="superscript">[66]</style></DisplayText><record><rec-number>210</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647832021">210</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>张亚娟</author></authors></contributors><auth-address>山西省交通科学研究院;</auth-address><titles><title>氧化石墨烯分散液对路用水泥砂浆性能的影响</title><secondary-title>公路交通科技(应用技术版)</secondary-title></titles><periodical><full-title>公路交通科技(应用技术版)</full-title></periodical><pages>106-108</pages><volume>12</volume><number>08</number><keywords><keyword>氧化石墨烯</keyword><keyword>水泥砂浆</keyword><keyword>力学强度</keyword><keyword>耐腐蚀性</keyword></keywords><dates><year>2016</year></dates><isbn>1002-0268</isbn><call-num>11-2279/U</call-num><urls></urls><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[66]研究GO改性水泥砂浆的7天和28天力学性能，结果显示GO对砂浆28天力学性能有显著增强效果，GO掺量增加至0.05%，水泥砂浆的抗折强度相比对照组提高17.4%、抗压强度提高31.1%。LuZ等ADDINEN.CITE<EndNote><Cite><Author>Lu</Author><Year>2016</Year><RecNum>212</RecNum><DisplayText><styleface="superscript">[67]</style></DisplayText><record><rec-number>212</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647832198">212</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Lu,Zeyu</author><author>Hou,Dongshuai</author><author>Ma,Hongyan</author><author>Fan,Tianyuan</author><author>Li,Zongjin</author></authors></contributors><titles><title>Effectsofgrapheneoxideonthepropertiesandmicrostructuresofthemagnesiumpotassiumphosphatecementpaste</title><secondary-title>ConstructionandBuildingMaterials</secondary-title></titles><periodical><full-title>ConstructionandBuildingMaterials</full-title></periodical><pages>107-112</pages><volume>119</volume><keywords><keyword>Grapheneoxide</keyword><keyword>Magnesiumpotassiumphosphatecement</keyword><keyword>Mechanicalbehavior</keyword><keyword>Microstructures</keyword></keywords><dates><year>2016</year><pub-dates><date>2016/08/30/</date></pub-dates></dates><isbn>0950-0618</isbn><urls><related-urls><url>/science/article/pii/S0950061816307851</url></related-urls></urls><electronic-resource-num>/10.1016/j.conbuildmat.2016.05.060</electronic-resource-num></record></Cite></EndNote>[67]研究了0.05%和0.10%的GO对0.15水胶比的磷酸镁钾水泥浆体力学性能的影响，结果表明，GO掺量为0.05%时改善了水泥浆体的力学性能，抗压和抗折强度相比对照组分别提高6.8%和8.3%，而GO掺量提高至0.10%，水泥浆体的力学性能下降且低于对照组。KangD等人ADDINEN.CITE<EndNote><Cite><Author>Kang</Author><Year>2017</Year><RecNum>209</RecNum><DisplayText><styleface="superscript">[68]</style></DisplayText><record><rec-number>209</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647831907">209</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Kang,Donghoon</author><author>Seo,KangSeok</author><author>Lee,HeeYoung</author><author>Chung,Wonseok</author></authors></contributors><titles><title>ExperimentalstudyonmechanicalstrengthofGO-cementcomposites</title><secondary-title>ConstructionandBuildingMaterials</secondary-title></titles><periodical><full-title>ConstructionandBuildingMaterials</full-title></periodical><pages>303-308</pages><volume>131</volume><keywords><keyword>GrapheneOxide</keyword><keyword>GOcontent</keyword><keyword>Curingage</keyword><keyword>Mechanicalstrength</keyword><keyword>FE-SEM</keyword></keywords><dates><year>2017</year><pub-dates><date>2017/01/30/</date></pub-dates></dates><isbn>0950-0618</isbn><urls><related-urls><url>/science/article/pii/S0950061816318438</url></related-urls></urls><electronic-resource-num>/10.1016/j.conbuildmat.2016.11.083</electronic-resource-num></record></Cite></EndNote>[68]研究了GO水溶液对水泥砂浆抗压、抗折和抗拉强度的影响，结果表明，GO的最佳掺量在0.05%~0.1%左右，对强度提升幅度在20%~32%左右。LongW-JADDINEN.CITE<EndNote><Cite><Author>Long</Author><Year>2018</Year><RecNum>213</RecNum><DisplayText><styleface="superscript">[69]</style></DisplayText><record><rec-number>213</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647832269">213</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Long,Wu-Jian</author><author>Wei,Jing-Jie</author><author>Xing,Feng</author><author>Khayat,KamalH.</author></authors></contributors><titles><title>Enhanceddynamicmechanicalpropertiesofcementpastemodifiedwithgrapheneoxidenanosheetsanditsreinforcingmechanism</title><secondary-title>CementandConcreteComposites</secondary-title></titles><periodical><full-title>CementandConcreteComposites</full-title></periodical><pages>127-139</pages><volume>93</volume><keywords><keyword>Grapheneoxide</keyword><keyword>Cementpaste</keyword><keyword>Dynamicmechanicalproperties</keyword><keyword>Poremicrostructure</keyword><keyword>Reinforcingmechanism</keyword></keywords><dates><year>2018</year><pub-dates><date>2018/10/01/</date></pub-dates></dates><isbn>0958-9465</isbn><urls><related-urls><url>/science/article/pii/S0958946517311666</url></related-urls></urls><electronic-resource-num>/10.1016/j.cemconcomp.2018.07.001</electronic-resource-num></record></Cite></EndNote>[69]等人研究发现，GO掺量为0.05%~0.2%，水泥净浆的力学性能先增大后降低，28天的抗折强度可提高12%~26%，抗压强度提高2%~28%。另有研究表明，GO能同其它材料协同增强增韧水泥基材料。LiX等人ADDINEN.CITE<EndNote><Cite><Author>Li</Author><Year>2015</Year><RecNum>216</RecNum><DisplayText><styleface="superscript">[70]</style></DisplayText><record><rec-number>216</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647832615">216</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Li,Xueguang</author><author>Wei,Wei</author><author>Qin,Hao</author><author>HangHu,Yun</author></authors></contributors><titles><title>Co-effectsofgrapheneoxidesheetsandsinglewallcarbonnanotubesonmechanicalpropertiesofcement</title><secondary-title>JournalofPhysicsandChemistryofSolids</secondary-title></titles><periodical><full-title>JournalofPhysicsandChemistryofSolids</full-title></periodical><pages>39-43</pages><volume>85</volume><keywords><keyword>Nanostructures</keyword><keyword>X-raydiffraction</keyword><keyword>Mechanicalproperties</keyword></keywords><dates><year>2015</year><pub-dates><date>2015/10/01/</date></pub-dates></dates><isbn>0022-3697</isbn><urls><related-urls><url>/science/article/pii/S0022369715001055</url></related-urls></urls><electronic-resource-num>/10.1016/j.jpcs.2015.04.018</electronic-resource-num></record></Cite></EndNote>[70]首次研究了GO和单壁碳纳米管（SWCNTs）在水泥砂浆中的共同影响作用，结果表明，1.5%掺量的GO和0.5%掺量的SWCNTs复掺表现出更好的协同效应，使砂浆的抗折强度提高了72.7%，远高于GO和SWCNTs在单一作用下对抗折强度51.2%和26.3%的增强幅度。LuCADDINEN.CITE<EndNote><Cite><Author>Lu</Author><Year>2016</Year><RecNum>215</RecNum><DisplayText><styleface="superscript">[71]</style></DisplayText><record><rec-number>215</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647832530">215</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Lu,Cong</author><author>Lu,Zeyu</author><author>Li,Zongjin</author><author>Leung,ChristopherK.Y.</author></authors></contributors><titles><title>Effectofgrapheneoxideonthemechanicalbehaviorofstrainhardeningcementitiouscomposites</title><secondary-title>ConstructionandBuildingMaterials</secondary-title></titles><periodical><full-title>ConstructionandBuildingMaterials</full-title></periodical><pages>457-464</pages><volume>120</volume><keywords><keyword>Grapheneoxide</keyword><keyword>Strainhardeningcementitiouscomposites</keyword><keyword>Mechanicalproperties</keyword></keywords><dates><year>2016</year><pub-dates><date>2016/09/01/</date></pub-dates></dates><isbn>0950-0618</isbn><urls><related-urls><url>/science/article/pii/S0950061816308583</url></related-urls></urls><electronic-resource-num>/10.1016/j.conbuildmat.2016.05.122</electronic-resource-num></record></Cite></EndNote>[71]等研究发现GO和PVA纤维复掺使得水泥砂浆的强度得到改善，与单掺2%PVA纤维的水泥砂浆相比，2%PVA和0.08%的GO复掺使得强度进一步提高，抗压、抗拉和抗弯强度分别提高了24.8%、37.7%和80.6%。陈亚兵ADDINEN.CITE<EndNote><Cite><Author>陈亚兵</Author><Year>2017</Year><RecNum>217</RecNum><DisplayText><styleface="superscript">[72]</style></DisplayText><record><rec-number>217</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647832762">217</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>陈亚兵</author><author>严泽稷</author><author>鲁娅</author><author>林康</author><author>李月星</author><author>张芳</author></authors></contributors><auth-address>武汉工程大学材料科学与工程学院;中国地质大学工程学院;武汉源锦商品混凝土有限公司;</auth-address><titles><title>硅灰与氧化石墨烯对硬化水泥浆体的复合增强效应</title><secondary-title>武汉工程大学学报</secondary-title></titles><periodical><full-title>武汉工程大学学报</full-title></periodical><pages>471-476</pages><volume>39</volume><number>05</number><keywords><keyword>氧化石墨烯复合聚羧酸减水剂</keyword><keyword>硅灰</keyword><keyword>复合增强</keyword></keywords><dates><year>2017</year></dates><isbn>1674-2869</isbn><call-num>42-1779/TQ</call-num><urls></urls><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[72]研究了10%硅灰（内掺）和0.08%GO（外掺）两者分别单掺和复掺对水泥净浆力学性能的影响，研究结果表明，二者复掺改性浆体的孔隙率最低，抗折、抗压强度分别提高了38.6%和22.7%，且均高于分别单掺时的增幅。GO对水泥基材料起到增强增韧、提高力学性能的同时，通常伴随着对耐久性能的改善效果，包括抗渗、抗冻和抗腐蚀等性能。MohammedA等ADDINEN.CITE<EndNote><Cite><Author>Mohammed</Author><Year>2015</Year><RecNum>219</RecNum><DisplayText><styleface="superscript">[73]</style></DisplayText><record><rec-number>219</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647842775">219</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Mohammed,A.</author><author>Sanjayan,J.G.</author><author>Duan,W.H.</author><author>Nazari,A.</author></authors></contributors><titles><title>Incorporatinggrapheneoxideincementcomposites:Astudyoftransportproperties</title><secondary-title>ConstructionandBuildingMaterials</secondary-title></titles><periodical><full-title>ConstructionandBuildingMaterials</full-title></periodical><pages>341-347</pages><volume>84</volume><keywords><keyword>Grapheneoxide</keyword><keyword>Cementmatrix</keyword><keyword>Transportproperties</keyword><keyword>Watersorptivity</keyword><keyword>Waterabsorption</keyword><keyword>Chloridepenetration</keyword></keywords><dates><year>2015</year><pub-dates><date>2015/06/01/</date></pub-dates></dates><isbn>0950-0618</isbn><urls><related-urls><url>/science/article/pii/S0950061815001531</url></related-urls></urls><electronic-resource-num>/10.1016/j.conbuildmat.2015.01.083</electronic-resource-num></record></Cite></EndNote>[73]研究GO对水泥砂浆传输特性的影响，结果发现，砂浆在GO掺量为0.01%时孔隙率最高，其吸水性也最高，与对照组相比氯离子渗透深度下降了81%，这归因于GO使微观结构更为致密，能够捕获氯离子并阻碍其侵入。DuH等ADDINEN.CITE<EndNote><Cite><Author>Du</Author><Year>2015</Year><RecNum>218</RecNum><DisplayText><styleface="superscript">[74]</style></DisplayText><record><rec-number>218</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647842695">218</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Du,Hongjian</author><author>Pang,SzeDai</author></authors></contributors><titles><title>Enhancementofbarrierpropertiesofcementmortarwithgraphenenanoplatelet</title><secondary-title>CementandConcreteResearch</secondary-title></titles><periodical><full-title>CementandConcreteResearch</full-title></periodical><pages>10-19</pages><volume>76</volume><keywords><keyword>Diffusion(C)</keyword><keyword>Dispersion(A)</keyword><keyword>Durability(C)</keyword><keyword>Permeability(C)</keyword><keyword>Poresizedistribution(B)</keyword></keywords><dates><year>2015</year><pub-dates><date>2015/10/01/</date></pub-dates></dates><isbn>0008-8846</isbn><urls><related-urls><url>/science/article/pii/S0008884615001386</url></related-urls></urls><electronic-resource-num>/10.1016/j.cemconres.2015.05.007</electronic-resource-num></record></Cite></EndNote>[74]研究发现，掺入2.5%的GO后，砂浆的抗水渗透性能和抗氯离子渗透性能提高了64%和70%。TongT等人ADDINEN.CITE<EndNote><Cite><Author>Tong</Author><Year>2016</Year><RecNum>234</RecNum><DisplayText><styleface="superscript">[75]</style></DisplayText><record><rec-number>234</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1649125999">234</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>Tong,Teng</author><author>Fan,Zhou</author><author>Liu,Qiong</author><author>Wang,Sen</author><author>Tan,Susheng</author><author>Yu,Qiang</author></authors></contributors><titles><title>Investigationoftheeffectsofgrapheneandgrapheneoxidenanoplateletsonthemicro-andmacro-propertiesofcementitiousmaterials</title><secondary-title>ConstructionandBuildingMaterials</secondary-title></titles><periodical><full-title>ConstructionandBuildingMaterials</full-title></periodical><pages>102-114</pages><volume>106</volume><keywords><keyword>Graphenenanoplatelets</keyword><keyword>Grapheneoxidenanoplatelets</keyword><keyword>Portlandcement</keyword><keyword>Durability</keyword><keyword>Micro-scalecharacterization</keyword><keyword>Atomisticsimulation</keyword></keywords><dates><year>2016</year><pub-dates><date>2016/03/01/</date></pub-dates></dates><isbn>0950-0618</isbn><urls><related-urls><url>/science/article/pii/S0950061815307649</url></related-urls></urls><electronic-resource-num>/10.1016/j.conbuildmat.2015.12.092</electronic-resource-num></record></Cite></EndNote>[75]研究了GO对水泥砂浆抗腐蚀性能和抗冻性能的影响，结果表明，GO促进了高密度的C-S-H凝胶的生长，并且与周围C-S-H凝胶形成了更紧密的结合界面，水泥砂浆产生了更为致密的微观结构，从而改善了GO水泥砂浆的抗腐蚀性和抗冻性能，此外，在冻融循环过程中水分子的脱附和吸附机理可以解释GO对砂浆抗冻性能的增强作用。杨亚玲等人ADDINEN.CITE<EndNote><Cite><Author>杨雅玲</Author><Year>2017</Year><RecNum>220</RecNum><DisplayText><styleface="superscript">[76]</style></DisplayText><record><rec-number>220</rec-number><foreign-keys><keyapp="EN"db-id="vxzd0wpdefeza7e2sf6x5pvsefezas5axsfw"timestamp="1647842847">220</key></foreign-keys><ref-typename="JournalArticle">17</ref-type><contributors><authors><author>杨雅玲</author><author>袁小亚</author><author>沈旭</author><author>殷璐</author></authors></contributors><auth-address>重庆交通大学材料科学与工程学院;</auth-address><titles><title>氧化石墨烯改性水泥砂浆耐腐蚀性能的研究</title><secondary-title>功能材料</secondary-title></titles><periodical><full-title>功能材料</full-title></periodical><pages>5144-5148</pages><volume>48</volume><number>05</number><keywords><keyword>氧化石墨烯</keyword><keyword>水泥砂浆</keyword><keyword>耐腐蚀性能</keyword><keyword>微观结构</keyword></keywords><dates><year>2017</year></dates><isbn>1001-9731</isbn><call-num>50-1099/TH</call-num><urls></urls><remote-database-provider>Cnki</remote-database-provider></record></Cite></EndNote>[76]研究了水泥砂浆浸泡在复合盐溶液中，在经过长期干湿循环和盐腐蚀的耦合作用下，GO掺量变化对其耐腐蚀性能的影响，发现砂浆在GO掺量为0.03%时耐腐蚀性能最好，归因于水泥砂浆的微观结构更为致密，因此对复合形式腐蚀具有极佳的抗性。1.3对微观结构的影响大量研究发现，GO对水泥砂浆的水化有着显著影响，可以调节水化晶体的成核和生长情况，改善水泥砂浆的微观结构，进而大大改善硬化水泥砂浆的宏观性能。LvSH等人ADDINEN.CITEADDINEN.CI