物料衡算、能量衡算

河南科技大学鼎鼎鼎化工队洛阳吉利区年产6万吨甲基丙烯酸甲酯项目环境影响报告书洛阳吉利区年产6万吨甲基丙烯酸甲酯的项目河南科技大学鼎鼎鼎化工队小组成员：张卫生郭相江赵紫君王海岩朱新月衡算说明书本项目的设备材料平衡计算分为MAL合成和MMA合成两个工序进行详细的计算说明。1.1 MAL合成工序MAL合成工序主要包括反应精馏塔T201、合成MAL原料混合器M201、MAL合成反应器R201、骤冷淋浴塔T202、脱水塔T203 . 经过Aspen Plus 8.4模拟，其结果详见表1-1至表1-5。(1)反应精馏塔(T201 )表1-1反应精馏塔(T201 )模拟结果串流id15161718暂时性c59.159.249.363压缩栏。776.56.5Vapor Frac110Vapor Frac1110质量v frac1110Mole Flow kmol/hr161.674.96194.3572.28质量流公斤/HR90301050304010质量流公斤/秒2.5080.0031.3971.114质量流公斤/秒2.5080.0031.397质量流公斤/秒1.114质量流质量流体积流计数/HR549.831342.4537.332企业PS/PS-0.972-0.417-0.916Density gm/cc0.0160.0010.0150.547质量流公斤/HRH21010跟踪公司C3H60.8010.801跟踪公司C3H82.6212.621跟踪公司N-C4H10761.5512.371759.181I-C4H10163.409163.3590.051-C4618.082跟踪公司跟踪公司CIS-C4战斗机1487.5480.3592723.817TRANS-C4923.1570.161304.451PS PR 45031.1664845.229185.9371，3-c 47.7235.12.622C4H4跟踪公司跟踪公司跟踪公司C4H6跟踪公司H2O33.9130.00133.913JR0.029跟踪公司0.029PS美联社MALPS二氧化碳二氧化碳N2O2C8H6O4C2H4O2C3H6OCH4OMass FracH210.002跟踪公司C3H689 PPM159 PPM跟踪公司C3H8290 PPM521 PPM跟踪公司N-C4H100.084471 PPM0.189I-C4H100.0180.03213 PPM1-C40.068跟踪公司跟踪公司CIS-C4战斗机0.16571 PPM0.679TRANS-C40.10232 PPM0.076PS PR 40.5570.9630.0461，3-c 4855 PPM0.001654 PPMC4H4跟踪公司跟踪公司跟踪公司C4H6跟踪公司H2O0.0042 PPB0.008JR3 PPM跟踪公司7 PPMPS美联社MALPS二氧化碳二氧化碳N2O2C8H6O4C2H4O2C3H6OCH4O(2)合成mal原料混合器(M201 )表1-2合成MAL原料混合器(M201 )的模拟结果串流id1920211722暂时性c239.3202049.346.7压缩栏。1.0131.0131.0136.51.013Vapor Frac11110.998Vapor Frac11110.998质量v frac11110.999Mole Flow kmol/hr141.524188.6981132.18894.351556.76质量流千克/小时2549.5856038.11317716.53503045334.22质量流公斤/秒0.7081.6778.811.39712.593质量流公斤/秒0.7081.6778.811.39712.576质量流0.017质量流质量流体积流计数/HR5931.0364536.1927231.9342.453407929.6企业PS/PS-7.927-0.007-0.041-0.417-8.391Density gm/cc0.0010.0010.0010.0150.001质量流公斤/HRH21010C3H60.8010.801C3H82.6212.621N-C4H102.3712.371I-C4H10163.359163.3591-C4跟踪公司跟踪公司CIS-C4战斗机0.3590.359TRANS-C40.1610.161PS PR 44845.2294845.2291，3-c 45.15.1C4H4跟踪公司跟踪公司C4H6H2O2549.5850.0012549.585JR跟踪公司跟踪公司PS美联社MALPS二氧化碳二氧化碳N2317716.53317716.53O26038.116038.11C8H6O4C2H4O2C3H6OCH4OMass FracH20.002221 PPMC3H6159 PPM18 PPMC3H8521 PPM58 PPMN-C4H10471 PPM52 PPMI-C4H100.0320.0041-C4跟踪公司跟踪公司CIS-C4战斗机71 PPM8 PPMTRANS-C432 PPM4 PPMPS PR 40.9630.1071，3-c 40.001113 PPMC4H4跟踪公司跟踪公司C4H6H2O12 PPB0.056JR跟踪公司跟踪公司PS美联社MALPS二氧化碳二氧化碳N210.7O210.133C8H6O4C2H4O2C3H6OCH4O(3) MAL合成反应器表1-3合成MAL反应器(R201 )的模拟结果串流id2324暂时性c350350压缩栏。1.0131.013Vapor Frac11Vapor Frac11质量v frac11摩尔流kmol/HR1556.761563.02质量流公斤/HR45334.2245334.22质量流公斤/秒12.59312.593质量流公斤/秒12.59312.593质量流质量流质量流体积流计数/HR79796330.1679940.82企业PS/PS-4.335-12.889Density gm/cc0.0010.001质量流公斤/HRH21010C3H60.8010.801C3H82.6212.621N-C4H102.3712.371I-C4H10163.359163.3591-C4跟踪公司CIS-C4战斗机0.3590.359TRANS-C40.1610.161PS PR 44845.22992.0591，3-c 45.15.1C4H4跟踪公司C4H6H2O2549.5854309.116PS跟踪公司PS美联社MAL5459.618PS二氧化碳215.279二氧化碳304.041N2317716.53317716.53O26038.112773.279C8H6O4172.159C2H4O262.231C3H6O45.14CH4OMass FracH2221 PPM221 PPMC3H618 PPM18 PPMC3H858 PPM58 PPMN-C4H1052 PPM52 PPMI-C4H100.0040.0041-C4跟踪公司CIS-C4战斗机8 PPM8 PPMTRANS-C44 PPM4 PPMPR PR 40.1070.0021，3-c 4113 PPM113 PPMC4H4跟踪公司C4H6H2O0.0560.095JR跟踪公司PS美联社MAL0.12PS二氧化碳0.005二氧化碳0.007N20.70.7O20.1330.061C8H6O40.004C2H4O20.001C3H6O996 PPMCH4O(4)急冷淋浴塔(T202 )表1-4急冷淋浴塔(T202 )的模拟结果串流id29303141暂时性c161.56360.497.2压缩栏。331.23Vapor Frac1010Vapor Frac1010质量v frac1010摩尔流kmol/HR1777.833