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1.Whenafluidflowsthroughaductoroverasurface,thevelocityoveraplaceat
rightanglestothestreamisnotnormallyuniform.Thevariationofvelocitycanbeshov/nby
theuseofstreamlineswhicharelinessodrawnthatthevelocityvectorisalwaystangential
tothem.Theflowratebetweenanytwostreamlinesisalwaysthesame.Constantvelocity
overacross-sectionisshownbyequidistantstreamlinesandincreaseinvelocitybycloser
spacingofstreamlines.
2.Itisfoundtheheattransferrateperunitareaqisdependentonthosephysical
propertieswhichaffectflowpattern.Thethermalpropertiesofthefluidandthevelocityof
flowthefluidoverthesurface,thetemperaturedifferencetandafactordeternmingthe
naturalcirculationeffectcausebyexpansionofthefluidonheating.
3.Theoildistilledinaverylargesteeltower,thetechnicalnamesofwhichisthe
fractionatingtower.Thetoweristhirtytofiftymeterstallanditsdiameterisonetothree
meters.Itisdividedintochambers,eachofwhichcontainsalayeroftrays.Thereareholesin
thetrays.Thechanbersareatdifferentheights,andtemperatureateachheightisdifferent.
4.Agroupofoperationforseparatingthecomponentsofmixtureisbasedonthe
transferofmaterialfromonehomogeneousphasetoanther.Unlikepurelymechanical
separation,thesemethodsutilizedifferencesinvaporpressureorsolubility,notdensityor
particlesize.Thedrivingforcefortransferisaconoantrationdiffercetooraconcentration
gradient,muchasatemperaturedifferenceoratemperaturegradientprovidesthedriving
forceheattransfer.
5.Thethreemostimportantcharacteristicsofanindividualparticleareits
composition,itssizeanditsshape.Compositiondeterminesuchpropertiesasdensityand
conductivity,providedthattheparticleiscompletelyuniform.Aparticleshapemaybe
regularsuchassphericalorcubic,oritmaybeirregularas,forexample,withapieceof
brokenglass.
6.homogeneouscatalysisistheindustricaloxoprocessformanufacturingnormal
iosobuty(异丁醛)。Ahomogeneouscatalysispressinvolvemorethanonephase,usually
thecatalystisasolidandthereactantsandproductsareinliquidorgaseousform.
7.Whenthevaporsriseintothecoolerpartofthefractionatingtower;theylose
heat,thevaporsriseuntiltheyarejustbelowtheirownboilingtemperature.thenthey
condenseonatrayandturnintoaliquidagain.Theliquidoneachtrayflowsintoaseparate
smalltowerwheretheliquidbreaksdownintosmallerfractions.Theseparationofthe
hydrocarbonsismoreaccurate.
8.Thefunctionofdistillationistoseparate,byvaporization,aliquidmixtureof
miscible,andvolaulesubstancesintoindividualcomponentsor,insomecases,intogroups
ofcomponents,theseparationofamixtureofalcoholandwaterintoitscomponentofliquid
nitrogen,oxygenandargon,andofcrudepetroleumintogasoline,kerosence,fueloil,and
lubricationstockareexamplesofdistillation.
9.Forthepumpingofliquidsorgasesfromonevesseltoanotherorthroughlong
pipes,somefromofmechanicalpumpisusuallyemployed.Theenergyrequirebythepump
willcependontheheightthroughwhichtheliquidsraised,thepressurerequiredatdelivery
point,thelengthanddiameterofthepipe,therateofflow,togetherwiththephysical
propertiesoftheliquid,particularlyitsviscosityanddensity.
10.Inthemajorityofchemicalprocesses,heatiseithergivenoutorabsorbed,and
fluidsmustoftenbeheatedorcooleinawiderangeofplant,suchasfurnaces,evaporates,
distillationunits,dryers,andreactionvesselswhereoneofthemajorproblemsisthatof
transferringheatatthedesiredrate.Inaddition,itmaybenecessarytopreventthelossof
heatatthedesiresrateformsoneofthemostimportantareasofchemicalengineering.
11.membranesciencehasreachedmaturity,andtheseparationprocesses,whichare
basedonthetechnologiesthatithasspawned,arenowcommonplace.Theycoversuch
widerangingapplicationasmicrofiltration,reserveosmosis,gasseparation,theartificial
kidneyandcontrolled-releasepharmaceuticals,andtheyareusedextensivelyinindustry,
medicineandtoprotecttheenvironment
12.Theremovalofoneormoreselectedcomponentsfromamixtureofgasesby
absorptionintoasuitableliquidisthesecondmajoroperationofchemicalengineeringthat
isbasedoninterphasemasstransfercontrolledlargelybyratesofdiffusion.Thus,acetone
canberecoverdfromanacetone-airmixturebtpassingthegasstreamintowaterinwhich
theacetonedissolveswhiletheairpassesout.
13.Evaporationisachievedbyaddingheattothesolutiontovaporisethesolvent.
Theheatissuppliedprincipallytoprovidethelatentheatcfvaporization,and,byadopting
methodsforrecoveryofheatfrcmthevepor,ithasbeenpossibletoachievegreateconomy
inheatutilization.Whilstthenormalheatingmediumisgenerallylowpressureexhaust
steamfromturbines,specialheattransferfluidsorfluegasesarealsoused.
14.Manyorganicliquidarepurifiedbycrystallizationratherthanbydistillationsince
enthapiesofcrystallizationaregenerallymuchlowerthanenthalpiesofvaporizationand
caystallizationmaybecarrieoutclosertoambienttemperaturetherebyreducingenergy
requirements.Againstthis,crasrallizationisrarelythelaststageinaprocessandsolvent
separation,washinganddryingstagesareusuallyrequired.
15.Theseparationofliquidmixtureintotheirvariouscomponentisoneofthemajor
operationsintheprocessindustries,anddistillation,themostwidelyusedmethodof
achievingthisend,isthekeyoperatinginandoilrefinery.Inprocessing,thedemandfor
purerproduct,coupledwiththeneedforgreatereffiency,haspromotedcontinuedresearch
intothetechniquesofdistillation.
16.Thisistheclassicreatorusedbyorganicchemists.Thetypicalvolumein
glasswareisafewhundredmilliliters.Reactantsarechargestothesystem,rapidlymixed,and
repidlybroughtuptotemperaturesothatreactionconditionsarewelldefined.Heatingis
carriedoutwithanoilbathoranelectricheatingmantle.Mixingiscarriedoutwitha
magneticstirrerorasmallmechanicalagitator.Temperatureiscontrolledbyregulationthe
temperatureorbyallowingasolventtoreflux.
17.Inabatchreatorallmoleculesenterandleavetogether.ifthesystemsis
omermal,reactionyieldsdependonlyontheelapsedtimeandontheinitialcomposition,the
situationinflowsystemismorecomplicatebutnotimpossiblyso.Thecounterpartcfthe
batchreactiontimeistheageofamolecule.Agingbeginswhenamoleculeentersthe
reactorandceseswhenitleaves,thetotaltimespentwithintheboundariesofthereactionis
knownastheexitage,orresidencetime.
18.Severalpossiblemechanismshavebeensuggestedasthecauseofcrystal
nucleationfromasupersaturatedsolution.Threerecognizednucleationprocesses
are(l)homogeneousnucleation,whichoccursspontaneouslyanddoesnotrequirethe
presenceofsurfacesofanykind;(2)heterogeneousnuclestion,usuallypromptedbythe
presenceofacrystallinephaseofthesolutematerial.
19.Enzymesarenature1scatalysts.Forthemomentitissufficienttoconsideran
enzymeasalargeprotein,thestructureofwhichresultsinaveryshape-specificactivesite.
Havingshapethatareoptimallysuitedtoguidereactantmolecules(usuallyreferredtoas
substrates)intheoptimumconfigurationforreaction,enzymesarehighltspecialand
efficientcatalysts.
20.Environmentalcatalysisisprojectedtogrowfasterthananyothersegmentofthe
catalystmarketinthenext20years.Thisgrowthwillcomebothfromtraditionalareas,such
asemissionstreatment,andfromnewareasthatrangefromtheautomotiveindustryto
pharmaceuticals.Tosustainthisgrowthandtomeetmorestringentenvironmentdemands,
researcherswillrequireever-increasingcontrolandunderstandingofcatalyticmaterialand
processesatthemolecularlevel.
21.Processengineeringdesignistheappllicationofchemical,mechanical,petroleum,
gasandotherengineeringtalentstotheprocess-relateddevelopment,planning,designs
anddecisionsrequiresforeconomicalandeffectivecompletionofaprocessproject.
Although!processdesignengineersareorganizationallylocatedinresearch,technical
service,wconomicevaluation,theusualarrangementistohavethemavailabletothe
engineeringgroupsconcernedwithdevelopingtheengineeringdetailsofaproject.
22.Compressorsareusedforprovidinggaspressurerequiredtotransortgaswith
pipelinesandtoliftoilingas-liftoperations.Thecompressorsusedintoday'snaturalgas
productionindustyfallintotwodistincttypes:reciprocatingandrotarycompressors.
Reciprocatingcompressorsaremostcommonlyusedinthenaturalgasindustry.Theyare
builtforpracticallyallpressuresandvolumetriccapacities.
23.Hydrocarbonsconstitutetheessentialcomponentsofpetroleum,theirmolecules
containonlycarbonandhydrogen;theyaregroupedintomanychemicalfamiliesaccoringto
theirstructure.Allstruct
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