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LESSON1NUTRITION
Whatweeataswellashowmuchweeatdetermineournutritionstatustoanimportantextent,
andinfluencedbyadiversityofexternalandinternalfactors.
Thepersonwhowantstofinetheanswertothequestion"whatshouldIeatforgood
nutrition?”,mighteasilybecomelostinthemazeofinformationalcorridors,confusedbythe
wealthoftechnicalinformationprovidedbyscientistsormisleadbysimplisticanswersprovided
bythosewithproductstosell.Somewhereinbetweenissomereasonable,commonsense
informationthatwecanusetoguideusourquestforsoundnutritionknowledgeo
Tobegin,weneedtolearnsomedefinitionsofcommonlyusednutritiontermsandfindout
whatsortsofguidelinesareavailabletohelpusmeasurethequalityofourdietsandtodevelop
healthfuleatingpatterns.
NUTRITIONANDFOOD:DEFINITIONS
Thewordnutritionisoftenpairedwiththewordfoodbecausethetwogotogether.Theyare
interdependent,butnotinterchangeable.
Foodmightbedefinedasanyediblesubstancethatprovidesnourishmentwhenconsumed.Itis
madeupofmanynaturalingredientsallchemicalsthathavedifferentfunctionssuchasproviding
odor,flavor,color,andnourishment.Theingredientsthatgiveusnourishmentarecallednutrients.
Thesenutrientsarecategorizedasfats,proteinscarbohydrates(sugarsandstarches),minerals,
vitamins,andwater.Theyarecalledessentialnutrientsbecausewecannotgetalongwithoutthem.
Weneedthemforenergy,forbuildingandmaintainingbodytissue;andforregulatingbody
processesthethreeessentialfunctionsoffoodsinthebody.
Nutritionmightbedefinedastheprocesswherebyweobtaintheessentialnutrientsandusethem
tomakemanyothersubstancesourbodiesneed,thisprocesswouldincludeeatinganddigesting
foodandabsorbingandusing,ormetabolizing,thenutrientsitcontains.
Wecanobtainalloftheessentialnutrientsfromfood.However,itispossibletoobtain
nourishmentwithouteatinganddigestingfbod-if,forexample,thenutrientsareinjecteddirectly
toourveinsasinintravenousfeeding.
Thus,itisthenutrientsthatareessentialandthefoodthatnormallyprovidesthem.Since
foodisvital,weneedtoknowthenutritivecontentoffoods,whichonesarethebestsourcesof
thevariousnutrientsandhowtocombinethemintoahealthfuldiet.
Thetermgoodnutritionimpliesthatweareobtainingfromourfoodalloftheessential
nutrientsintheamountsneededtokeepourbodiesfunctioningandtomaintainoptimumhealth.A
verysimplifieddefinitionofgoodnutritionmightbe"eatingtherightfoodsintherightamounts.”
Theworkofnutritionscientistsinvolvesfindinginthebody,theamountofeachthatweneed,
whathappeningswhenwereceivetoomuchortoolittleandaboutfoodanddied-whatfoodswe
shouldeatandinwhatamount.
Yetnutritionscienceinitsbroadestsensehasmanymorefacets:theinfluenceofsensory
factorsofflavor,color,andtextureoffoodoneatingbehavior;thepsychological,cultural,
emotional,andsocialaspectsoffoodintake;andeventheeconomicsoffoodavailabilityand
consumerbehaviorinthepurchaseoffood
THENUTRIENTS
Todate,nutritionscientistshaveidentifiedsome40to45substancesasessentialnutrients.
Butthelistisgrowingasnewnutrientscontinuetobeidentified;thehistoryofnutritionscience
containsfascinatingstoriesaboutthewaysfoodsubstanceshavebeenidentifiedasessential
nutrients.Insomeinstances,medicalresearchersseekingthecauseofaparticulardiseasefound
thatproblemwasduetoasinglesubstance,andthatwhenthissubstancewasaddedtothediet,the
symptomsofthediseasedisappeared.Anumberofvitaminswerediscoveredinthisway.
Nutrientsmightbedividedintotwogenialcategoriesbasedontheamountthatweneed.
Thesearethemacronutrients(carbohydrates,fats,proteins,andwater),whichweneedin
relativelylargeamountsandthemicronutrients)mineralelementsandvitamins),whichweneed
inrelativelysmallamounts.Allofthenutrientsexceptformineralelementsandwaterare
classifiedasorganicchemicalsbecausetheycontaintheelementcarbon.Mineralelementsand
waterareinorganicchemicalsbecausetheydonotcontaincarbon.
Thevitaminsaredividedintotwogeneralcategorizesbasedontheirsolubilityineitherwater
orfat.thefat-solublevitaminsarevitaminsA,D,E,andK;thewater-solublevitaminsinclude
vitaminsC(ascorbicacid),niacin,thiamin,riboflavin,flacon(alsocalledfolicacid)antitheticacid,
pyridoxine,vitaminB12andbiotin.
Themineralelementsaredividedintotwocategoriesbasedonthequantityofthemthatwe
need.Microelementsarethoseneededinrelativelylargeamounts,whilemicroelementsarethose
neededinverysmallamounts,someexampleofmicroelementsaresodium,calcium,and
phosphorus.Someexampleofmicroelementsisiron,iodine,manganese,zinc,andfluorine.
RECOMMENDEDDIETARYALLOWANCES
Onceanutrientisidentified,oneoftheprincipalresearcheffortsofnutritionscientististo
determinehowmuchofitisneededbypeopleatvariousagesandstagesoflife.Initialstudies
usuallyareconductedwithlaboratoryanimals,buttheinformationdevelopedinthesestudies
cannotbeapplieddirectlytohumanssincepeople*sneedsoftenarequitedifferentfromanimals'
needs.Humannutritionstudiesontheotherhand,aretime-consuming,costly,anddifficultto
conduct,especiallybecauseoftheproblemsofcontrollingvariablesandpossiblycausingharmto
theindividualsinvolved.Becauseoftheobstaclestocollecting,accuratedata,ourpresent
knowledgeofnutrientneedsisincomplete,andtherequirementsofhumansformanynutrients
havenotbeenestablished.
However,thedataonhumanandanimalneedscurrentlyavailableareusedbynutrition
scientiststoestablishestimatesoftheamountsofessentialnutrientsperdaythatwillmeetthe
needsofmosthealthpersons.IntheUnitedStates,themostwidelyusednutrientguidelinesare
therecommendeddietaryallowance(RDA),whichareissuedbythenationalacademyofsciences,
nationalresearchcouncil,andfoodandnutritionboard.
TheRDAservesasdietaryofnutritionalstandardsforawiderangeofage-weight-sex
groupssuchasinfants,children,adolescents,pregnantandlactatingwomen,andyoungerand
olderadults.Theyarerecommendations,notaveragerequirements,forsatisfactorylevelsofintake
ofessentialnutrientsofpopulationgroupsofaverage,healthypeople.Theydonottakeaccountof
specialneedscertainindividualsmayhaveduetogeneticmakeup,metabolicdisorders,chronic
infections,andotherabnormalities,whichmayresultintheirneedingdifferentlevelsofnutrients.
MARGINofSAFETYALLOWSforINDIVIDUALDIFFERENCES
Toallowforindividualdifference,theusuallyaresetwithagenerousmarginofsafety.Thus,
theyarethoughttomeettheneedsof95to97percentofthepeoplewithineachage-sexgroup.In
otherwords,theRDAexceedtherequirementsofmostindividualstoensurethattheneedsof
nearlyallaremeet.Forthisreason,apersonwhoconsumesadietthatprovideslessthantheRDA
foroneormoreessentialnutrientsisnotnecessarilygettingadietthatisnutritionallyinadequate.
Whatcanbeconcluded,however,isthatthefarthertheintakeofanessentialnutrientfallsbelow
theRDA,thegreatertheprobabilityofnutritionalinadequacy,ontheotherhand,ifanindividual
isgettingalltheessentialnutrientsatorabovetheRDAlevelofhisorherage,chancesaregood
thatdietisnationallyadequate.
AnexceptionistheRDAfbrenergyorcalories,whicharenotdesigned,asguidesfbr
individualcaloricneeds.OthervariablesnotincludedintheRDA,suchasbodysizeandphysical
activity,areinvolvedinanindividualJscaloricrequirements
DIFFERENCESINNUTRIENTUTILIZATIONCONSIDERED
AnotherfactorconsideredwhentheRDAareestablishedistheavailabilityofthenutrient
andfactorsthataffecthowefficientlyitisusedinthebodyforsomenutrients,suchasiron,
absorptionoruseinthebodymaybeincomplete;sotheRDAneedstobesethighenoughtoallow
forthis.Andbecauseinthecaseofcertainothernutrients,substancefoundincarrotsandother
vegetablesandfruits,whichourbodiesconverttovitaminA.
Ontheothersideofthecoin,receivingtoomuchofcertainnutrients,amounts
significantlyabovetheRDA,canbejustharmfulasnotobtainingenoughcertain
vitamins(suchasAandD)andmineralscanbehighlytoxicifhighforoptimal
nutrientintakefromthestandpointofbothmaximumandminimumlevels.
LESSON2CARBOHYDRATES
Thefoodscientisthasamany-sidedinterestincarbohydrates.Heisconcernedwiththeir
amountsinvariousfoods,availability(nutritionalandeconomic),methodsofextractionand
analysis,commercialformsandpurity,nutritionalvalve,physiologicaleffects,andfunctional
propertiesinfoods.Understandingtheirfunctionalpropertiesinprocessedfoodsrequiresnotonly
knowledgeofthephysicalandchemicalpropertiesofisolatedcarbohydrates,butalsoknowledge
ofthereactionsandinteractionsthatoccurinsitusbetweencarbohydratesandotherfood
constituentsandtheeffectsofthesechangesuponfoodqualityandacceptance.Thisisatallorder
forknowledge.Becauseprocessingaffectsbothnutritionalandestheticvaluesoffood,knowledge
ofthechangesthatcarbohydratesundergoduringmilling,cooking,dehydration,freezing,and
storageisespeciallyimportant.
Studentsareadvisedtostudythefundamentalchemistryunderlyingusefulcarbohydrates
propertiesOfservicewillbeanunderstandingoftheassociationofpolarmoleculesthrough
hydrogenbonding,ioniceffects,substituenteffects,chelationwithinorganicions,complexing
withlipidsandproteins,anddecompositionreaction.Thisbackgroundwillprovidean
understandingofpropertiesthataffectthetextureandacceptanceofprocessedfoods(e.g.,
solubility,hygroscopicity,diffusion,osmosis,viscosity,plastity,andflavorproduction),properties
thatenabletheformationorhighqualitypastries,gels,coatings,confections,andreconstitutable
dehydratedandfrozenfoods.
Abilitytopredictwhatchangesinfunctionalpropertiesarelikelytoensuefrom
incorporatingvarioustypesofcarbohydratesintoprocessedfoodsisapracticalgoalofthefood
scientist.Suchforecastingrequireseitherawealthofexperiencewithtrial-and-errormethodsora
deepknowledgeofcarbohydratepropertiesasrelatedtostructure-perhapsboth.However,
scientificknowledgeofcauseandeffectishighlyrespectedwhenitshortensindustrial
developmenttime
Source,Types,andTerminology
Thelayman'sconceptionofcarbohydratesgenerallyinvolvesonlythesugarsandstarchesof
foods一thosethatgeneratecaloriesandfat.Thefoodchemistknowsmanyothertypesthatare
ingested.
Becausemostpeopleenjoythesweetnessofsugarsandthemouthfeelofcookedstarches,
theybecomefamiliarbyassociationwithtablesugar(sucrose),invertsugar'shydrolyzedsucrose,
cornsyrupsugars(D-glucoseandmaltose),milksugar(lactose),andthemorestarchyfoods.
Thesecarbohydratesarenutritionallyavailable;ie,theyaredigested(hydrolyzedtocomponent
monosaccharides)andutilizedbythehumanbody。Carbohydratesofdietaryfiber(cellulose,
hemicelluse,pentosans,andpecticsubstances),incontrast,tendtobeoverlookedbecausethey
arelargelyunavailable.Digestiveenzymesdonothydrolyzethemsignificantly;nevertheless,they
maybequiteimportantforhumanhealth.
Thecarbohydratesofnaturalandprocessedfoodsaredividedintoavailableand
unavailabletypes.Theavailablecarbohydratesvaryindegreesofabsorptionandutilization
dependinguponquantitiesingested,accompanyingfoodtypes,andhumandifferencesin
complementsofdefectiveenzymesandintestinaltransportmechanisms.Malabsorption
difficultiesandadversephysiologicaleffectsareknownforalltheavailablecarbohydratesbut
gelatinizedstarchesgivelittleornotrouble.
Itisimportanttorealizethatinruminantstheunavailableandmostabundant
polysaccharidecelluloseispartiallyhydrolyzedtothesamehighlyavailablesugarthatstarch
providesupondigestion;i.e.D-glucose.Grazinganimalsdoitthroughthecellulosesgeneratedby
themicroorganismsoftheirrumen.Celluloseis,therefore,acontributingsourceofvolubleanimal
protein.Foodchemistsprobablycanimproveupontheefficiencyandeconomicsoftheruminant'
sconversionofcellulosetonutrients.Developmentofcellulosesthatarestableoutsidethecellsof
microorganismsenablestheculturingoffungiandwithyeastsoncellulosehydrolyzates.Fungi
(e.g.,mushrooms)canproduceproteinwiththebiologicalvalueofanimalprotein.Theconversion
ofcellulosewastestoanimalfeedandhumanfoodisanintriguingprospectforlimiting
environmentalpollutionandforfeedingtheworld'expendingpopulation.
Carbohydrateswerefirstnamedaccordingtotheirnaturalsources;e.g.,beetsugar,cane
sugar,grapesugar,maltsugar,milksugar,cornstarch,liverglycogen,andsweetcornglycogen.
Trivialnameswerethenformed,inEnglishterminology,oftenfromaprefixrelatedtothesource
followedbythesuffix"-ose”todenotecarbohydrate.Namesarisinginthisway,forexample,are
fructose,maltose,lactose,xylose,andcellulose.Theseshort,well-establishednamesarestill
commonlyused.Theyfurnishnoinformationonthechemicalstructureshowever,soadefinitive
carbohydratenomenclaturehasbeendeveloped.Fromthedefinitivenames,structuralformulas
canbewritten.Someofthetermsinvolvedinthedefinitivenomenclatureareexplainedinthe
followingparagraphs.
Thesimplesugars(monosaccharidesOarebasicallyaliphaticpolyhydroxyaldehydesand
ketones:HOCH2-(CHOH)n-CHOandH0CH2-(CHOOH)n-1-C-O-Ch2OH,called“aldoses”
and“ketoses,“respectively.However,itmustbeunderstoodthatcyclichemiacetalsofthose
open-chainformsprevailIsolidsandatequilibriuminsolutions.Inthedefinitivenomenclature,
thesuffix"ose"isappendedtoprefixesdenotingthenumberofcarbonatomsinthe
nomosaccaride;e.g.trioses(n=l),tetroses(n=2),pentoses(n=3),hexoses(n=4)todistinguish
aldosesfromketoses,ketosesaredesignatedas”-uloses.wThus,thesimplestketose,
HOCH2-C:O-CH2OH,isatriulose;themostcommonketose,D-fructose(levulose),isahexlose.
Todesignatetheconfigurationsofhydroxylgroupsontheasymmetriccarbonatomsof
monosaccharides,theprefixesDandLareusedtogetherwithprefixesderivedfromthetrivial
sugarnames(e.g.,D-glycero-,L-arabino-,D-xylo-)followedbypentose,hexosehexulose,etc.
Asopen-chainhydroxyaldehydesandhydroxylketenes,themonosaccharidesarevery
reactive.TheyreadlyenolizeinalkalinesoluionstoreduceionssuchasCu2+andFe(CN)63".
Therefore,theyarecalledureducingsugars”.Plantsprotectthereactivemonosaccharidesfor
transportandstoragebycondensingthemwithlossofwater,intolessreactivesugars,e.g.,
D-glucoseandD-fructose,arecondensinginsuchawaythattheirreactivefunctionsarelostto
formthedisaccharidenoreducingsugar,sucrose.Thelessreactivesucroseisthentransportedto
allpartsoftheplantforenzyminsynthesesofoligo-andpolysaccharides.Fromthousandsormore
D-glucosemoietiesofsucrosetheglucans,starchandcellulose,arebuilt.FromtheD-fructose
moietyofsucrose,fructanssuchasinulinareassembled.Otherpolysaccharidesareformedfrom
othersugar,whichrosebyenzymictransformationsofphosphorylatedhexoesandsugar
nucleotides.
Theprefix"glyc,“isusedinagenericsensetodesignatesugarsandtheirderivatives;e.g.,
glycoses,glycosides,glycosans,glyconicglyceric,andglycuronicacids.Thegenericnamefor
polysaccharidesis“glycan“homoglycansarecomposedofsinglemonosaccharide;forexample,
theD-glucans,celluloseandstarch,releaseonlyD-glucosebyhydrolysis.Otherhomoglycans
(e.g.,thehexcsans,D-galactanandD-manan,andthepentosans,L-arabinanandD-xy-lan)are
uncommoninnature.Heteroglycans,composedoftwoormoredifferentmonosaccharides,are
widelydistributedthanthehomoglycansthatarenotglucans.Galactomnnans,glucomammans,
arabinogalactans,andarabinoxylansarecommondiheteroglycans(composedoftwosugars).the
glycantvailoverfreeglycosesinnaturalfoods.
Thereducingsugarsarereadilyoxidized,mildoxidationofaldosesyieldsaldonicacids,
HOCH2-(CHOH)n-COOH;e.g.,gluconicacid(n=4).oxidationofbothendsofthealdosemolecule
yieldsaldaricacids,HOOC-(CHOH)n-COOH;e.g,,tartaricacid(n=2).Oxidationoftheterminal
CH2OHgroupofhexoseswithoutoxidationofthereducingfunction(protected)produces
hexuronicacids,HOOC-(CHOH)-CHO.Thehexuronicacidsarecommonmonosaccharide
constituentsofmanyheteroglycans.forexample,theyarefoundinacidichemicelluloses,pectic
substances,alginplandexudategumes,andthemucopolysaccharidesofmammaliantissues.
Penluronicacidshavenotbeenfoundinnature.
Reductionofaldosesorketosesyieldsugaralcohols,properlycalled'alditols,“
HOCH2-(CHOH)n-CH2OH.thesuffix”-itol“isappliedtothetrivialprefixestodenote
differentalditols;e.g.,D-glucitol,D-manniitol,xylitol.Thetriitol,gllyceritol(bycommonusage,
glycerol,n=l),isthealditolmoietyoffats.GlycerolandD-glucitol(sorbitol)areacceptableand
usefulfoodaddiaffinityforwater.Pentitols(n=3)andhexutols(n=4)arefoundinsmallamountin
manyfruits,vegetablesandhexitohperseitol(n=5),andanoctitolhavebeenisolatedfrom
avocados.Someaditolsarenutritionallyavailable;othersarenot.
OthertypesofcarbohydratesfoundinfbodarethecondensedN-acetylatedaminosugarsof
mucopolysaccharides,glycoproteins,andchitin;thecondensedeoxysugarsofgum,mucilages,
andnucleotides;glcosides(sugarscondensedwithnonsugars);glucosinolates(toxic
thioglycosides);cyclitols(myoinositol,phyticacid);andreductone,L-ascorbicacid.Complex
carbohydrates,suchascelluloseandhemicellulose,arelargelyindigestible,asareanumberof
origins
CarbohydrateCompositionofFoods
Detainsneedmoreexactinformationonthecarbohydratecompassionoffoods.Food
pressersalsomakepracticaluseofcarbohydratecompositiondata.Forexample,thereducing
sugarcontentoffruitsandvegetablesthataretobedehydratedorprocessedwithheatis
frequentlyanindicatoroftheextentofnonenzymicbrowingthatcanexpectedduringprocessing
andstorage.Thepossiblehydrolysisofsucrosetoreducingsugarsduringprocessingalsoistobe
considered.thenaturalchangesincarbohydratecompositionthatoccurduringmaturationandpost
harvestripeningofplantfoodsisthereforeofparticularinteresttofoodchemists.
Citrusfruits,whichnormallyripenonthetreeandcontainnostarch,undergolittlechange
incarbohydratecompositionfollowingharvest.However,infruitthatarepickedbeforecomplete
ripening(e.g.,apples,bananas,pears),muchofthestoredstarchisconvertedtosugarsasripening
process.Thereducingsugarcontentofpotatoesalsoincreaseduringthesundryingofgrapesand
dates,sucroseisconvertedtoD-glucoseandD-fructose;accordingly,thecolorofthedried
productsisdeepenedbynonenzymicbrowningreactions.
Greenpeas,greenbeans,andsweetcomarepickedbeforematuritytoobtainsucculent
texturesandsweetness.Laterthesugarswouldbeconvertedtopolysaccharides,waterwouldbe
lost,andtoughtextureswoulddevelop.Insoybean,whichisallowedtomaturecompletelybefore
harvest,thestarchreserveisdepletedassucroseandgalactosyIsucroses(raffinose,stachyose,
verbascose,etc.)areforminthemaltingofcerealgrains,rapidconversionsofreserve
carbohydratetosugarsoccurasenzymesarestronglyactivated.
Infoodsofanimalorigin,postmortemactivityofenzymesmustbeconsideredwhen
carbohydratecompositiondataisobtained.Theglycogenofanimaltissues,especiallyliveris
rapidlydepolymerizedtoD-glucoseafterslaughter,andimmediatedeepfreezingisrequiredto
preservetheglycogen.Mammalianinternalorgans,suchasliver,kidney,andbrainsalsoeggsand
shellfish,providesmallamountofD-glucoseinthediet.Redfreshmeatscontainonlytracesof
availablecarbohydrate(D-glucose,D-fructose,andD-ribose)andtheseareextractedinto
bouillonsandbroths.Dairyproductsprovidethemainsourceofmammaliancarbohydrate.Whole
cow'smilkcontainsabout4.9%carbohydratesanddriedskimmilkcontainsover50%lactose.
Examinationoffoodcompositiontablesshowsthatingeneral,cerealsarehighestinstarch
contentandlowestinsugars.Fruitarehighestinfreesugarsandlowestinstarch.onadrybasis,
theedibleportionsoffruitusuallycontain80-90%carbohydrate.Legumesoccupyintermediate
portionwithregardtostarchandarehighinunavailablecarbohydrate.
Glycosidesofmanytypesarewidelydistributedinplants.Certainbiologicallyactive
thioglucosides,properlycalled“glucosinolates”,arefoundinsignificantamountincrucifers.
Mustardoils,nitriles,andgoitrinsarereleasedbyenzymichydrolysis.Theirsuspectedgoitrogenic
inhumanshavebeeninvestigated,buttheamountofglucosnolatesnormallyconsumedinfood
suchasfreshcabbage(300-1000ppm),cauliflower,Brusselssprouts,turning,rutabagas,and
radishesarenotnowbelievedtocauseadversephysiologicaleffects.Cyangeneticglycosides,
whichreleasehydrogencyanidebyenzymichydrolysisundercertainconditionofvegetable
maceration,areknowntobesourcesofacutetoxicityincertainanimalfeeds;howevertheyare
notactiveinthecustomaryfoodsofdevelopedcountries.Certainforeignvarietiesoflimabeans
andmanicroot(cassava)mayyieldupto0.3%hydrogencyanidebyweight,butlimabeans
distributedintheUnitedStatesyieldlessthan0.02%.Saponins,thesurface-activeglycosidesof
steroidsandtriterpenoids,arefoundinlowconcentrationsintealeaves,spinach,asparagus,beets
sugarbeet(0.3%),yams,soybeans(0.5%),alfalfa(2-3%),andpeanutsandotherlegumes.
LESSON3LIPIDSANDTHEIRUSESINFOODS
Thechemistryoffoodlipidsiscomplicatedbecausetheyarediversetypesofcompoundsthat
undergomanyinteractionswithothercomponentsofafood.Manyimportantandwell-understood
chemicalchangesthatoccurinanisolatedlipidmaybemodifiedbysuchfactorsaslocationofthe
lipidinatissuesystem,thepresenceorabsenceofwater,andtheimpositionofsuchstressesas
heatorradiation.Metals,bothinthefreestateasironsandascomponentsoforganmetallic
compounds,affectthechemistryoflipids,especiallyinoxidationreactions.Non-lipidcomponents
ofafoodmayinteractwithlipidsandthiscanproducechangeinfoodquality.
DEFINITIONANDCLASSIFICATIONOFLIPIDS
Theconsumerandtheprocessoroffoodsutilizesubstancesfromthenutrientsgroupknownas
fatsandoils.Fatsandoilsrepresentthemostprevalentsinglecategoryofaseriesofcompounds
knownaslipids.Theword"lipid1'isdefinedinWebster*sunabridgeddictionaryas“anyofa
groupsubstancethatsparinglysolubleinether,chloroform,orothersolventsforfatsbutareonly
sparinglysolubleinwater,thatwithproteinsandcarbohydratesconstitutetheandprincipal
structuralcomponentsoflivingcells,andrelatedandderivedcompounds,andsometimessteroids
andcarotenoids,“Thisdefinitiondescribesabroadgroupofsubstancesthathavesome
propertiesincommonandhavesomecompositionalsimilarities.
AclassificationoflipidsproposedbyBloorcontainsthefollowingelements,whichareuseful
indistinguishingthemanylipidsubstances:
1.Simplelipids(neutrallipids)-estersoffattyacidswithalcohols.
a.Fats:estersoffattyacidswithglycerol.
b.Waxes;estersoffattyacidswithalcoholsotherthanglycerol.
2.Compoundlipids-compoundscontainingothergroupsinadditionesterofafattyacidwithan
alcohol.
a.Phospholipids(phosphatides):esterscontainingfattyacids,phosphoricacidandother
groupsusuallycontainingnitrogen.
b.Cerebrosides(phosphatides);compoundscontainingfattyacids,acarbohydrateanda
nitrogenmoiety,butnophosphoricacid
c.Othercompoundlipids:sphingolipids:sphingolipidsandsulfolipids
3.Derivedlipids-substancesderivedfromneutrallipidsorcompoundlipidsandhaving
generalpropertiesoflipids.
a.Fattyacids
b.Alcohols:usuallynormalchainhigheralcoholsandsterols
c.Hydrocarbons
Foodsmaycontainanyorallofthesesubstancesbutthoseofgreatestconcernarethefatsor
glycosidesandthephosphatides.Theterm“fatis“applicabletoalltriglyceridesregardlessof
whethertheyarenormallynonliquidorliquidatambienttemperatures.Liquidfatsarecommonly
referredtoasoils.Suchoilsassoybeanoil,cottonseedoil,andoliveoilareofplantorigin,lard
andtallowareexamplesofnonliquidfatsfromanimals,yetfatfromthehorseisliquidatambient
temperaturesandisreferredtoashorseoil.
Fatsandoilsalsocanbeclassedaccordingto“groupcharacteristics.vFive
well-recognizedgroupsarethemilkfatgroup,thelauricacidgroup,theoleiclinoleicacidgroup,
thelinolenicacidgroup,andtheanimaldepot-fatsgroup.
Themilkfatgrouppertainsessentiallytothemilkofruminantsandespeciallytothatofthe
cow,althoughincertainareasmilkofthewaterbuffaloofsheepandgoatsmaybeprominent.,
Milkfatsarecharacterizedby30-40%oleic,25-32%palmitic,and10-15%stearicacids.They
generallyhavesubstantialamountsofc4-cl2acidsandaretheonlycommonlyusedfatsto
containbutyricacid,whichcompositionisparticularlysusceptibletovariationasaconsequence
oftheanimal'sdiet.
Thelauricacidgroupischaracterizedbyahighproportion(40-50%)oflauricacid(cl2)
andlesseramountsofc8,clO,cl4,c!6,andc!8acids,theunsaturatedacidcont
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