保存到的文件有机习题

1、第十二章 含氮和含磷有机化合物习题解答1. （1）乙基异丙基胺 （2）1,4苯二胺 （3）1,5 戊二胺 （4）N 甲基N 乙基苯胺 （5）2 甲基3氨基戊烷 （6）1硝基丙烷 （7）氢氧化三甲基丙基铵 （8）碘化三乙基异丙基铵 （9）氯化对甲基重氮苯 （10）对羟基偶氮苯2. (1) CH3CH2NH2(2) H2N(CH2)6NH2(5) CH3NHCOO(6)NNN(CH3)2(3) HOCH2CH2NCH3)3OH(4) HOCH2CH2NH2+(7) CH3CH2POHOHO(8) CH3POHOCH3O(9)PSCH2CNHCH3CH3OCH3OOO(10)POCH3CH2OSCH

2、3CH2ONO2O3. (1)CH3NCC2H5C2H5 (2)CH3NNO（3）C12H25N(CH3)3Br+（4）H2N NH2(5)NNN(CH3)2OH2NCNCNH2 OH(6)4. (1) CH3CH2NH2NH3 NHCH3NH2NH5. (1) CH3NH2 (a)(CH3)2NH (b)(CH3)3N (c)NaNO2HCl有气泡冒出者为 (a)黄色油状物者为 (b)余 者为 (c) (3) (CH3CH2)2NH CH3CH2NH2 NH3 CH3CONH2 CH3COOH (2) 氢氧化四乙铵 苯甲胺对硝基苄胺苯胺邻苯二甲酰亚胺(2)NH2 (a)CH3 (b)NHCH

3、3COOHCOOH (d)OH (c)NaHCO3溶液气泡者 (c) (d)FeCl3溶液显紫色者为(d)余 者为(c)余 者 (a) (b)HNO2有气泡者为(a)黄色油状物为(b)6. 苯酚 (a)苯胺 (b) 对氯苯甲酸 (c) 苯酚 ( 有机层(a)(c)(分液)NaHCO3有机层:(a)水层:ClCOONa(c)H+HCl(分液)水层:NH2HClNaOH(b)7. 此化合物的构造式：NO2CH3，反应式如下：NO2CH3Fe+HClNH2CH3HNO205N2ClCH3Cu2(CN)2NaCNH+CNCH3 H+H2OCOOHCH3KMnO4COHCOHOOCCOOO8. (1)浓

4、HNO3浓H2SO4NO2发烟HNO3浓H2SO4NO2NO2Fe+HClNH2NH2HNO205N2ClN2ClKCNCu2(CN)2CNCNH2OH+COOHCOOH(2)CH3HNO3H2SO4CH3NO2Fe+HClCH3NH2CH3CClOCH3NHCCH3OHNO3H2SO4CH3O2NNHCOCH3NaOHH2OCH3NO2NH2HNO205CH3NO2H2ClH3PO2H2OCH3NO2Fe + HClCH3NH2(3)CH3HNO3H2SO4NO2CH3Fe + HClNH2CH3Br2BrBrCH3NH2HNO205BrBrCH3N2ClH3PO2H2OBrBrCH3 (4)HNO3H2SO4NO2Fe+HClNH2Br2BrBrNH2BrHNO205BrBrN2ClH3PO2H2OBrBrBrBr9. 此化合物的构造式为:CH3CNHCH3，名称为N甲基乙酰胺。OCH3CNHCH3NaOHCH3COONa + CH3NH2O水解反应式：10.